Chlorides-buliding-blocks

Sokolova, A. S. published the artcileSynthesis of (1S)-(+)-camphor-10-sulfonic acid derivatives and investigations in vitro and in silico of their antiviral activity as the inhibitors of filovirus infections, Safety of ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, the publication is Russian Chemical Bulletin (2019), 68(5), 1041-1046, database is CAplus.

N-Heterocycle-containing (1S)-(+)-camphor-10-sulfonamide derivatives were synthesized. Their antiviral activity against the Ebola and Marburg viruses was estimated using a pseudovirus system based on the vesicular stomatitis virus. The derivatives bearing morpholine and triazole moieties demonstrated the highest inhibitory activity towards the Ebola virus glycoprotein. A moderate activity against the Marburg virus was found for a compound containing the piperidine moiety. A mol. modeling of the interaction between the synthesized derivatives and the binding site of glycoprotein of the Ebola virus was performed.

Russian Chemical Bulletin published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C18H24N6O6S4, Safety of ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Wang, Wei published the artcileNickel-Catalyzed One-Pot Carbonylative Synthesis of 2-Mono- and 2,3-Disubstituted Thiochromenones from 2-Bromobenzenesulfonyl Chlorides and Alkynes, Application In Synthesis of 21286-54-4, the publication is Organic Letters (2021), 23(16), 6589-6593, database is CAplus and MEDLINE.

A nickel-catalyzed one-pot carbonylation reaction of 2-bromobenzenesulfonyl chlorides I (R = H, Me, OMe; R¹ = H, OMe; RR¹ = -OCH₂O-, -O(CH₂)₂O-) with alkynes R²CCR³ (R² = Me, Ph, 2-thienyl, etc.; R³ = Ph, 3-thienyl, 2-naphthyl, etc.) for the synthesis of thiochromenones II has been established. The alkynes were suitable substrates in this carbonylative transformation, and a broad range of 2-mono- and 2,3-disubstituted thiochromenone products II were obtained in moderate to good yields with quite high functional group compatibility. Notably, this procedure presents the first example of nickel-catalyzed carbonylative synthesis of thiochromenones II with 2-bromobenzenesulfonyl chlorides as a promising sulfur precursor.

Organic Letters published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C7H9BO3, Application In Synthesis of 21286-54-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Qi, Xinxin published the artcileNickel-Catalyzed Thiocarbonylation of Arylboronic Acids with Sulfonyl Chlorides for the Synthesis of Thioesters, Computed Properties of 21286-54-4, the publication is Organic Letters (2020), 22(16), 6671-6676, database is CAplus and MEDLINE.

An interesting procedure for thioesters synthesis via nickel-catalyzed thiocarbonylation of arylboronic acids with sulfonyl chlorides as the sulfur source has been explored. Using Mo(CO)₆ as a solid CO surrogate and reductant, a broad range of thioesters ArC(O)SR (Ar = Ph, naphthalen-2-yl, furan-2-yl, etc., R = Et, cyclohexyl, naphthalen-1-yl, etc.) were obtained in moderate to good yields with good functional group tolerance.

Organic Letters published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Computed Properties of 21286-54-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Qi, Xinxin published the artcilePalladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters, Application of ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, the publication is Organic Chemistry Frontiers (2020), 7(6), 885-889, database is CAplus.

A palladium-catalyzed carbonylative transformation of aryl iodides RI (R = Ph, naphthalen-2-yl, thiophen-3-yl, etc.) and sulfonyl chlorides R¹S(O)₂Cl (R¹ = 4-methylphenyl, i-Pr, cyclohexyl, etc.) has been studied. Both aryl and alkyl sulfonyl chlorides were all successfully transformed into the desired thioesters RC(O)SR¹ with sulfonyl chlorides as the sulfur source. Mo(CO)₆ played a dual role as both CO surrogate and reductant in this reaction.

Organic Chemistry Frontiers published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Application of ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Liu, Yongzhu published the artcilePalladium-catalyzed reductive desulfonative aminocarbonylation of benzylsulfonyl chlorides with nitroarenes towards arylacetamides, Computed Properties of 939-99-1, the publication is Organic Chemistry Frontiers (2022), 9(8), 2079-2083, database is CAplus.

A new palladium-catalyzed reductive desulfonative aminocarbonylation reaction with benzylsulfonyl chlorides RCH₂S(O)₂Cl (R = Ph, 3,4-dimethylphenyl, 2,4-dichlorophenyl, etc.) as C(sp³) electrophiles has been developed. Using nitroarenes R¹NO₂ (R¹ = Ph, quinolin-8-yl, 2H-1,3-benzodioxol-5-yl, etc.) as readily accessible and stable nitrogen surrogates, a wide range of arylacetamides RCH₂C(O)NHR¹ were easily prepared in high yields with very good functional group compatibility. Mo(CO)₆ plays a dual role as both a CO source and reductant. Moreover, a late-stage modification of natural products was also achieved via this aminocarbonylation strategy.

Organic Chemistry Frontiers published new progress about 939-99-1. 939-99-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Benzyl chloride,Benzene, name is 1-(Chloromethyl)-4-(trifluoromethyl)benzene, and the molecular formula is C8H6ClF3, Computed Properties of 939-99-1.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Liu, Yongzhu published the artcilePalladium-catalyzed reductive desulfonative aminocarbonylation of benzylsulfonyl chlorides with nitroarenes towards arylacetamides, Product Details of C7H6Cl2, the publication is Organic Chemistry Frontiers (2022), 9(8), 2079-2083, database is CAplus.

A new palladium-catalyzed reductive desulfonative aminocarbonylation reaction with benzylsulfonyl chlorides RCH₂S(O)₂Cl (R = Ph, 3,4-dimethylphenyl, 2,4-dichlorophenyl, etc.) as C(sp³) electrophiles has been developed. Using nitroarenes R¹NO₂ (R¹ = Ph, quinolin-8-yl, 2H-1,3-benzodioxol-5-yl, etc.) as readily accessible and stable nitrogen surrogates, a wide range of arylacetamides RCH₂C(O)NHR¹ were easily prepared in high yields with very good functional group compatibility. Mo(CO)₆ plays a dual role as both a CO source and reductant. Moreover, a late-stage modification of natural products was also achieved via this aminocarbonylation strategy.

Organic Chemistry Frontiers published new progress about 620-20-2. 620-20-2 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Benzyl chloride,Benzene, name is 3-Chlorobenzylchloride, and the molecular formula is C7H6Cl2, Product Details of C7H6Cl2.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Liu, Yongzhu published the artcilePalladium-catalyzed reductive desulfonative aminocarbonylation of benzylsulfonyl chlorides with nitroarenes towards arylacetamides, Name: 3-Chloro-4-fluoronitrobenzene, the publication is Organic Chemistry Frontiers (2022), 9(8), 2079-2083, database is CAplus.

A new palladium-catalyzed reductive desulfonative aminocarbonylation reaction with benzylsulfonyl chlorides RCH₂S(O)₂Cl (R = Ph, 3,4-dimethylphenyl, 2,4-dichlorophenyl, etc.) as C(sp³) electrophiles has been developed. Using nitroarenes R¹NO₂ (R¹ = Ph, quinolin-8-yl, 2H-1,3-benzodioxol-5-yl, etc.) as readily accessible and stable nitrogen surrogates, a wide range of arylacetamides RCH₂C(O)NHR¹ were easily prepared in high yields with very good functional group compatibility. Mo(CO)₆ plays a dual role as both a CO source and reductant. Moreover, a late-stage modification of natural products was also achieved via this aminocarbonylation strategy.

Organic Chemistry Frontiers published new progress about 350-30-1. 350-30-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Nitro Compound,Benzene, name is 3-Chloro-4-fluoronitrobenzene, and the molecular formula is C6H3ClFNO2, Name: 3-Chloro-4-fluoronitrobenzene.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Liu, Yongzhu published the artcilePalladium-catalyzed reductive desulfonative aminocarbonylation of benzylsulfonyl chlorides with nitroarenes towards arylacetamides, HPLC of Formula: 21286-54-4, the publication is Organic Chemistry Frontiers (2022), 9(8), 2079-2083, database is CAplus.

A new palladium-catalyzed reductive desulfonative aminocarbonylation reaction with benzylsulfonyl chlorides RCH₂S(O)₂Cl (R = Ph, 3,4-dimethylphenyl, 2,4-dichlorophenyl, etc.) as C(sp³) electrophiles has been developed. Using nitroarenes R¹NO₂ (R¹ = Ph, quinolin-8-yl, 2H-1,3-benzodioxol-5-yl, etc.) as readily accessible and stable nitrogen surrogates, a wide range of arylacetamides RCH₂C(O)NHR¹ were easily prepared in high yields with very good functional group compatibility. Mo(CO)₆ plays a dual role as both a CO source and reductant. Moreover, a late-stage modification of natural products was also achieved via this aminocarbonylation strategy.

Organic Chemistry Frontiers published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, HPLC of Formula: 21286-54-4.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Yuan, Jingjing published the artcileSubstituent position effect on photochromic properties of aldehyde-functionalized dithienylethenes, SDS of cas: 219537-97-0, the publication is Molecular Crystals and Liquid Crystals (2020), 712(1), 24-30, database is CAplus.

Three sym. dithienylethenes bearing two electron-withdrawing aldehyde groups have been synthesized. And their structures were confirmed by ¹H NMR, ¹³C NMR and HRMS (ESI). Investigation on photochromic properties indicated that they had good photochromic behavior with excellent fatigue resistance upon irradiation with UV or visible light. And it was found that the aldehyde substituent position had a significant effect on their photochromic properties. The DFT calculations further validated those exptl. results for their photochromic behavior. Furthermore, they may be used as versatile building blocks to construct novel photochromic materials.

Molecular Crystals and Liquid Crystals published new progress about 219537-97-0. 219537-97-0 belongs to chlorides-buliding-blocks, auxiliary class Fused/Partially Saturated Cycles,Cyclopentenes, name is 5-Chloro-3-[2-(5-chloro-2-methylthien-3-yl)cyclopent-1-en-1-yl]-2-methylthiophene, and the molecular formula is C37H30ClIrOP2, SDS of cas: 219537-97-0.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Luo, Qianfu published the artcilePreparation and solvent-dependent photochromism of triptycene-bonded dithienylethenes, HPLC of Formula: 219537-97-0, the publication is Chemistry Letters (2014), 43(10), 1584-1586, database is CAplus.

Two new, stable photochromic dithienylethenes DTE-1 and DTE-2 based on triptycene were conveniently synthesized in one pot. Their spectral properties and photochromism in different solvents were studied extensively. It was revealed that the two DTE-triptycene conjugates undergo special UV-vis absorption and color change in chloride solvents when irradiated by UV light.

Chemistry Letters published new progress about 219537-97-0. 219537-97-0 belongs to chlorides-buliding-blocks, auxiliary class Fused/Partially Saturated Cycles,Cyclopentenes, name is 5-Chloro-3-[2-(5-chloro-2-methylthien-3-yl)cyclopent-1-en-1-yl]-2-methylthiophene, and the molecular formula is C15H14Cl2S2, HPLC of Formula: 219537-97-0.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics