Qi, Xinxin published the artcilePalladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters, Application of ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, the publication is Organic Chemistry Frontiers (2020), 7(6), 885-889, database is CAplus.
A palladium-catalyzed carbonylative transformation of aryl iodides RI (R = Ph, naphthalen-2-yl, thiophen-3-yl, etc.) and sulfonyl chlorides R1S(O)2Cl (R1 = 4-methylphenyl, i-Pr, cyclohexyl, etc.) has been studied. Both aryl and alkyl sulfonyl chlorides were all successfully transformed into the desired thioesters RC(O)SR1 with sulfonyl chlorides as the sulfur source. Mo(CO)6 played a dual role as both CO surrogate and reductant in this reaction.
Organic Chemistry Frontiers published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Application of ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride.
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