Fawzy, A. published the artcileMechanistic and thermodynamic aspects of oxidative removal of flucloxacillin by different oxidants in an acidic medium, Category: chlorides-buliding-blocks, the publication is Journal of Molecular Liquids (2021), 115160, database is CAplus.
The mechanism of oxidative removal of flucloxacillin antibiotic (Flx) by two different oxidants (Ox), potassium bromate (KBrO3) and potassium iodate (KIO3), were studied using a spectrophotometric technique in sulfuric acid medium. The stoichiometry of the oxidation reactions of flucloxacillin by both oxidants was set to be a 2: 3 (Ox: Flx). The oxidation products of flucloxacillin were identified utilizing spot tests and FT-IR spectroscopy. The reactions followed a first order credence in [Flx] and lesser than unit order kinetics regarding to both [Ox] and [H+]. Negligible impacts of both ionic strength and dielec. constant of the reactions medium on the rates of reactions were observed The dependence of the oxidation rates on mercuric acetate concentration which works as a scavenger for any bromide or iodide ion composed during the reactions was investigated. Credence of reaction rates on temperature was studied, and the activation parameters were assessed and discussed. Tests for free radicals involvement throughout the oxidation reactions were neg. The reactions mechanism was elucidated and the rate law expressions were derived.
Journal of Molecular Liquids published new progress about 3919-74-2. 3919-74-2 belongs to chlorides-buliding-blocks, auxiliary class Isoxazole,Fluoride,Chloride,Carboxylic acid,Benzene, name is 3-(2-Chloro-6-fluorophenyl)-5-methylisoxazole-4-carboxylic acid, and the molecular formula is C11H7ClFNO3, Category: chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics