Skvortsov, N. K. published the artcileMolecular Structure and Spectral Characteristics of the Complex [Ni(Bu3P)2(NCS)2], and Its Catalytic Properties in Hydrosilylation Reaction, Safety of Dichloro(hexyl)(methyl)silane, the publication is Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii) (2003), 73(1), 66-69, database is CAplus.
According to X-ray diffraction data, the nickel complex [Ni(Bu3P)2(NCS)2] has a square-planar structure with the two phosphine ligands trans to each other and the thiocyanate ligand coordinated by the nitrogen atom. The IR and 1H, 13C, and 31P NMR data show that the same structure is preserved in solutions The catalytic activity of the complex in hydrosilylation of 1-hexene with chlorohydrosilanes HSiMe3-nCln varies in the series HSiCl3 > HSiMeCl2 > HSiMe2Cl. The reactions of the complex with hydrosilanes involve substitution of the anionic ligand and formation of silyl complexes.
Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii) published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C9H9BrO2, Safety of Dichloro(hexyl)(methyl)silane.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics