Charlesworth, E. H.’s team published research in Canadian Journal of Research, Section B: Chemical Sciences in 28B | CAS: 18791-02-1

Canadian Journal of Research, Section B: Chemical Sciences published new progress about 18791-02-1. 18791-02-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 2,3-Dibromopropionylchloride, and the molecular formula is C3H3Br2ClO, Formula: C3H3Br2ClO.

Charlesworth, E. H. published the artcileAction of zinc on α,β-dibromopropionyl halides, Formula: C3H3Br2ClO, the publication is Canadian Journal of Research, Section B: Chemical Sciences (1950), 1-4, database is CAplus.

BrCH2CHBrCOBr (I) reacts vigorously with Zn in absolute Et2O to give CH2:CHCO2Et (II) (55%), EtBr (6-8%), and HBr (42%). Steps for the reaction have been suggested. I was prepared by treating BrCH2CHBrCO2H with P and Br. The Hell-Volhard-Zelinskii reaction on BrCH2CH2CO2H (anilide, m. 119-20°; Pr β-bromopropionate, b. 76-8°, nD20 1.467), gave only BrCH2CH2COBr (III). Zn with BrCH2CHBrCOCl gave II also. Zn and III yielded 60% BrCH2CH2CO2Et.

Canadian Journal of Research, Section B: Chemical Sciences published new progress about 18791-02-1. 18791-02-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 2,3-Dibromopropionylchloride, and the molecular formula is C3H3Br2ClO, Formula: C3H3Br2ClO.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics