Tag: M.W=150-200

Khanam, R; Kumar, R; Hejazi, II; Shahabuddin, S; Meena, R; Rajamani, P; Yadav, N; Bhat, AI; Athar, F in [Khanam, Rashmin; Hejazi, Iram Iqbal; Athar, Fareeda] Jamia Millia Islamia, Ctr Interdisciplinary Res Basic Sci, New Delhi 110025, India; [Kumar, Raj; Meena, Ramovatar; Rajamani, Paulraj] Jawaharlal Nehru Univ, Sch Environm Sci, New Delhi, India; [Shahabuddin, Syed] Sunway Univ, RCNMET, Sch Sci & Technol, Selangor, Malaysia; [Yadav, Nitin] Indian Inst Technol, Dept Chem, New Delhi, India; [Bhat, Asif Iqbal] Cluster Univ, Dept Chem, Sri Pratap Coll, Srinagar, Jammu & Kashmir, India published New N-benzhydrylpiperazine/1,3,4-oxadiazoles conjugates inhibit the proliferation, migration, and induce apoptosis in HeLa cancer cells via oxidative stress-mediated mitochondrial pathway in 2019, Cited 43. COA of Formula: C7H4Cl2O2. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0.

N-benzhydrylpiperazine and 1,3,4-oxadiazoles are pharmacologically active scaffolds which exhibits significant inhibitory growth effects against various cancer cells, however, antiproliferation effects and the underlying mechanism for inducing apoptosis for aforementioned scaffolds addressing HeLa cancer cells remains uncertain. In this study, N-benzhydrylpiperazine clubbed with 1,3,4-oxadiazoles (4a-4h) were synthesized, subsequently characterized using high resolution spectroscopic techniques and eventually evaluated for their antiproliferation potential by inducing apoptosis in HeLa cancer cells. The MTT assay screening results revealed that among all, compound 4d (N-benzhydryl-4-((5-(4-aminophenyl)-1,3,4-oxadiazol-2-yl)methyl)piperazine) in particular, exhibited IC (50) value of 28.13 +/- 0.21g/mL and significantly inhibited the proliferation of HeLa cancer cells in concentration-dependent manner. The in vitro anticancer assays for treated HeLa cells resulted in alterations in the cell morphology, reduction in colony formation, and inhibition of cell migration in concentration-dependent treatment. Furthermore, G2/M phase arrest, variations in the nuclear morphology, degradation of chromosomal DNA confirmed the ongoing apoptosis in treated HeLa cells. Increase in the expression of cytochrome C and caspase-3 confirmed the involvement of intrinsic mitochondrial pathway regulating the cell death. Also, elevation in reactive oxygen species level and loss of mitochondrial membrane potential signified that compound 4d induced apoptosis in HeLa cells by generating the oxidative stress. Therefore, compound 4d may act as a potent chemotherapeutic agent against human cervical cancer.

COA of Formula: C7H4Cl2O2. Bye, fridends, I hope you can learn more about C7H4Cl2O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Computed Properties of C7H4Cl2O2. Sun, ML; Li, JC; Liang, CM; Shan, C; Shen, XY; Cheng, RH; Ma, YY; Ye, JX in [Sun, Maolin; Li, Jianchang; Liang, Chaoming; Shan, Chao; Shen, Xinyuan; Ma, Yueyue; Ye, Jinxing] East China Univ Sci & Technol, Minist Educ, Sch Pharm, Engn Res Ctr Pharmaceut Proc Chem, Shanghai 200237, Peoples R China; [Cheng, Ruihua] East China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China published Practical and rapid construction of 2-pyridyl ketone library in continuous flow in 2021, Cited 59. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0.

2-Pyridyl ketones widely appear in bioactive molecules, natural products, and are employed as precursors of chiral 2-pyridine alky/aryl alcohols or 2-aminoalkyl pyridine ligands for asymmetric catalysis. Herein, a practical method for the rapid synthesis of 2-pyridyl ketone library in continuous flow is reported, in which the 2-lithiopyridine formed by Br/Li exchange reacts with commercially available esters to obtain 2-pyridyl ketones in a good yield at short reaction time. This protocol functions broadly on a variety of esters and has been applied to the synthesis of TGF-beta type 1 receptor inhibitor LY580276 intermediate in an environmentally friendly method. It is rapid, reliable, and cost-efficient to afford diverse kinds of 2-pyridyl ketones in the compound library.

Welcome to talk about 50-84-0, If you have any questions, you can contact Sun, ML; Li, JC; Liang, CM; Shan, C; Shen, XY; Cheng, RH; Ma, YY; Ye, JX or send Email.. Computed Properties of C7H4Cl2O2

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

COA of Formula: C7H4Cl2O2. Li, N; Song, XZ; Wang, H in [Li, Ning; Song, Xiaozhe; Wang, Hui] Beijing Forestry Univ, Coll Environm Sci & Engn, Beijing 100083, Peoples R China published Degradation of 2,4-Dichlorobenzoic Acid by Coupled Electrocatalytic Reduction and Anodic Oxidation in 2020, Cited 35. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0.

Dual effects of cathodic dechlorination and oxidative decomposition of 2,4-dichlorobenzoic acid (2,4-DCBA) can be achieved using electrochemical reduction-oxidation technology. The removal efficiency was improved by optimizing the experimental conditions affecting electrode activity and contaminant degradation. The 2,4-DCBA removal efficiency reached 90.8% at a current density at 50 mA.cm(-2), initial pH of 5, and sodium sulfate concentration of 0.05 mol.L-1, with a 2,4-DCBA concentration of 20 mg.L-1. Furthermore, a good total organic carbon removal efficiency of 81.6% was achieved in the electrocatalytic reduction and oxidation process, with the present system retaining high stability after many experiment cycles. The reaction mechanism under different conditions is discussed, which provides new approaches to the degradation of chlorinated organic compounds.

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Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

In 2019 J MED CHEM published article about 20S PROTEASOMES; CRYSTAL-STRUCTURE; IMMUNOPROTEASOME; SITES; YEAST; GENERATION; BORTEZOMIB; MECHANISM; SUBSTRATE; KNOWLEDGE in [Xin, Bo-Tao; de Bruin, Gerjan; Maurits, Elmer; Espinal, Christofer; Du, Yimeng; Janssens, Marissa; Florea, Bogdan I.; van der Marel, Gijsbert A.; Overkleeft, Herman S.] Leiden Inst Chem, Gorlaeus Labs, Einsteinweg 55, NL-2333 CC Leiden, Netherlands; [Xin, Bo-Tao; de Bruin, Gerjan; Maurits, Elmer; Espinal, Christofer; Du, Yimeng; Janssens, Marissa; Florea, Bogdan I.; van der Marel, Gijsbert A.; Overkleeft, Herman S.] Netherlands Prote Ctr, Einsteinweg 55, NL-2333 CC Leiden, Netherlands; [Huber, Eva M.; Heinemeyer, Wolfgang; Groll, Michael] Tech Univ Munich, Lehrstuhl Biochem, Dept Chem, Ctr Integrated Prot Sci, D-85748 Garching, Germany; [Driessen, Christoph] Kantonsspital St Gallen, Dept Hematol & Oncol, CH-9007 St Gallen, Switzerland; [Weyburne, Emily S.; Kisselev, Alexei F.] Geisel Sch Med Dartmouth, Dept Mol & Syst Biol, 1 Med Ctr Dr HB7936, Lebanon, NH 03756 USA; [Weyburne, Emily S.; Kisselev, Alexei F.] Geisel Sch Med Dartmouth, Norris Cotton Canc Ctr, 1 Med Ctr Dr HB7936, Lebanon, NH 03756 USA; [Kisselev, Alexei F.] Auburn Univ, Harrison Sch Pharm, Dept Drug Discovery & Dev, Auburn, AL 36849 USA in 2019, Cited 43. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0. Category: chlorides-buliding-blocks

Subunit-selective proteasome inhibitors are valuable tools to assess the biological and medicinal relevance of individual proteasome active sites. Whereas the inhibitors for the beta 1c, beta 1i, beta 5c, and beta 5i subunits exploit the differences in the substrate-binding channels identified by X-ray crystallography, compounds selectively targeting beta 2c or beta 2i could not yet be rationally designed because of the high structural similarity of these two subunits. Here, we report the development, chemical synthesis, and biological screening of a compound library that led to the identification of the beta 2c- and beta 2i-selective-compounds LU-002c (4; IC50 beta 2c: 8 nM, IC50 beta 2i/beta 2c: 40-fold) and LU-002i (5; IC50 beta 2i: 220 nM, IC50 beta 2c/beta 2i: 45-fold), respectively. Co-crystal structures with beta 2 humanized yeast proteasomes visualize protein-ligand interactions crucial for subunit specificity. Altogether, organic syntheses, activity-based protein profiling, yeast mutagenesis, and structural biology allowed us to decipher significant differences of beta 2 substrate-binding channels and to complete the set of subunit-selective proteasome inhibitors.

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Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Authors Zhang, JW; Wang, CR; Liu, WH; Xu, S; Liu, BQ in ELSEVIER SCIENCE SA published article about THERMAL-DECOMPOSITION KINETICS; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; BUILDING UNITS; COMPLEXES; IONS; ACID; 3D; EUROPIUM(III); TERBIUM(III) in [Zhang, Ju-Wen; Wang, Cen-Ru; Liu, Wen-Hua; Xu, Shuang; Liu, Bin-Qiu] Bohai Univ, Dept Chem, Jinzhou 121013, Peoples R China; [Zhang, Ju-Wen] Bohai Univ, Coll Chem & Chem Engn, Profess Technol Innovat Ctr Liaoning Prov Convers, Jinzhou 121013, Peoples R China in 2020, Cited 57. COA of Formula: C7H4Cl2O2. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0

Ln(NO3)(3)center dot nH(2)O reacted with 2,4-dichlorobenzoic acid (2,4-HDCB) and NaOH under solvothermal conditions of water and ethanol to yield four lanthanide-organic coordination polymers (CPs) [Eu(2,4-DCB)(3)(CH3CH2OH)(2)] (1) and [Ln(2,4-DCB)(3)(H2O)] [Ln = Gd (2), Tb (3), Dy (4)]. The second ligand 4,4′-bipyridine (4,4′-bpy) was introduced into the above reaction systems to provide four new lanthanide-organic CPs [Ln(2)(2,4-DCB)(6)(4,4′-bpy)(H2O)(2)] [Ln = Eu (5), Gd (6), Tb (7), Dy (8)]. Single-crystal and powder X-ray diffraction analyses reveal that CPs 1 and 2 possess similar one-dimensional (1D) structures, and CPs 2-4 and 5-8 are isostructural, respectively. In 1-4, the 2,4-DCB anions bridge the Ln(III) ions to form a 1D chain. In 5-8, six 2,4-DCB anions link two Ln(III) ions into a binuclear Ln(2)(2,4-DCB)(6) unit, and the Ln(2)(2,4-DCB)(6) units are further connected by the 4,4′-bpy co-ligands to generate a 1D chain. The photoluminescent and magnetic properties of 1-8 were investigated.

COA of Formula: C7H4Cl2O2. Welcome to talk about 50-84-0, If you have any questions, you can contact Zhang, JW; Wang, CR; Liu, WH; Xu, S; Liu, BQ or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

An article Synthesis and pharmacological evaluation of 3-[5-(aryl-[1,3,4]oxadiazole-2-yl]-piperidine derivatives as anticonvulsant and antidepressant agents WOS:000531825800011 published article about NIPECOTIC ACID-DERIVATIVES; ANTIEPILEPTIC DRUGS; DESIGN; MODEL; 1,3,4-OXADIAZOLE; TRANSPORTER; MECHANISMS; EPILEPSY in [Singh, Ravi Bhushan; Zaman, Kamaruz] Dibrugarh Univ, Dept Pharmaceut Sci, Dibrugarh 786004, Assam, India; [Das, Nirupam] Assam Univ, Dept Pharmaceut Sci, SSMPS, Silchar 788151, Assam, India; [Singh, Gireesh Kumar] Rajendra Inst Med Sci, Ranchi 834009, Jharkhand, India; [Singh, Sushil Kumar] Banaras Hindu Univ, Indian Inst Technol, Dept Pharmaceut Engn & Technol, Pharmaceut Chem Res Lab, Varanasi 221005, Uttar Pradesh, India in 2020, Cited 43. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0. Computed Properties of C7H4Cl2O2

In the present study, we have synthesized a series of fifteen nipecotic acid 1,3,4-oxadiazole based hybrids with significant (60-78%) yields. All the compounds were characterized by using different spectroanalytical techniques such as FT-IR, H-1 NMR, C-13 NMR, and elemental analysis. This design strategy was validated by using in vivo anti-epileptic and anti-depressant bioassay models. Anti-convulsant activity was evaluated using subcutaneous pentylenetetrazol (scPTZ) in mice and MES induced seizure. Among a spectrum of activities, three compounds (4i, 4m, and 4n) displayed significant activity against pentylenetetrazole (scPTZ) induced seizures. No disruptions in motor co-ordination were observed in mice pretreated with the test compounds in the rotarod test. Their influence on the safety profile of elevated serum levels of biochemical markers such as hepatic and renal toxicity has been found to be safe. The derivatives also show marked anti-depressant activity, devoid of serotonergic augmentation as assessed using the despair swim test, 5-hydroxytryptophan (5-HTP)-induced head twitch test and learned helplessness test. In silico docking studies targeted on homology modelled GABA transporter 1 (GAT1) protein shows the critical enzyme-ligand interactions leading to the inhibition of the GAT1 transporter. The compound 4m was found to be the most active compound among all the synthesized compounds. (C) 2020 Published by Elsevier B.V. on behalf of King Saud University.

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Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Product Details of 50-30-6. In 2019.0 ENVIRON SCI TECHNOL published article about SP STRAIN HBP1; HYDROLYTIC DEHALOGENATION; DEGRADATION; BAM; DICHLOBENIL; GENES; ACID; 4-CHLOROBENZOATE; 3-CHLOROBENZOATE; 2,3-DIOXYGENASE in [Raes, Bart; Horemans, Benjamin; T’Syen, Jeroen; Springael, Dirk] Katholieke Univ Leuven, Div Soil & Water Management, B-3000 Leuven, Belgium; [Ghequire, Maarten G. K.; De Mot, Rene] Katholieke Univ Leuven, Ctr Microbial & Plant Genet, B-3000 Leuven, Belgium; [Rentsch, Daniel] Swiss Fed Labs Mat Sci & Technol, Lab Funct Polymers, Empa, CH-8600 Dubendorf, Switzerland; [Wattiez, Ruddy] Univ Mons, Dept Prote & Microbiol, B-7000 Mons, Belgium; [Kohler, Hans-Peter E.] Swiss Fed Inst Aquat Sci & Technol, Dept Environm Microbiol, Eawag, CH-8600 Dubendorf, Switzerland in 2019.0, Cited 52.0. The Name is 2,6-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-30-6.

2,6-Dichlorobenzamide (BAM) is a major groundwater micropollutant posing problems for drinking water treatment plants (DWTPs) that depend on groundwater intake. Aminobacter sp. MSH1 uses BAM as the sole source of carbon, nitrogen, and energy and is considered a prime biocatalyst for groundwater bioremediation in DWTPs. Its use in bioremediation requires knowledge of its BAM-catabolic pathway, which is currently restricted to the amidase BbdA converting BAM into 2,6-dichlorobenzoic acid (2,6-DCBA) and the monooxygenase BbdD transforming 2,6-DCBA into 2,6-dichloro-3-hydroxybenzoic acid. Here, we show that the 2,6-DCBA catabolic pathway is unique and differs substantially from catabolism of other chlorobenzoates. BbdD catalyzes a second hydroxylation, forming 2,6-dichloro-3,5-dihydroxybenzoic acid. Subsequently, glutathione-dependent dehalogenases (BbdI and BbdE) catalyze the thiolytic removal of the first chlorine. The remaining chlorine is then removed hydrolytically by a dehalogenase of the alpha/beta hydrolase superfamily (BbdC). BbdC is the first enzyme in that superfamily associated with dehalogenation of chlorinated aromatics and appears to represent a new subtype within the alpha/beta hydrolase dehalogenases. The activity of BbdC yields a unique trihydroxylated aromatic intermediate for ring cleavage that is performed by an extradiol dioxygenase (BbdF) producing 2,4,6-trioxoheptanedioic acid, which is likely converted to Krebs cycle intermediates by BbdG.

Product Details of 50-30-6. Welcome to talk about 50-30-6, If you have any questions, you can contact Raes, B; Horemans, B; Rentsch, D; T’Syen, J; Ghequire, MGK; De Mot, R; Wattiez, R; Kohler, HPE; Springael, D or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

An article Phosphine-Catalyzed Chemoselective [4+3] Cycloaddition of Alminine Esters and beta ‘-acetoxy Allenoates for Divergent Synthesis of Azepines WOS:000500053200001 published article about FORMAL 3+2+2 CYCLOADDITION; RING-CLOSING METATHESIS; FACILE SYNTHESIS; ANNULATION; ALKYNES; IMINES; GENERATION; ALLENES; ACCESS; 1,2,3-TRIAZOLES in [Dai, Zonghao; Zhu, Jin; Wang, Jiahua; Su, Wenbo; Yang, Fulai; Zhou, Qingfa] China Pharmaceut Univ, Dept Organ Chem, State Key Lab Nat Med, Nanjing 210009, Jiangsu, Peoples R China in 2020.0, Cited 96.0. HPLC of Formula: C7H4Cl2O2. The Name is 2,6-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-30-6

Text. A general method for the synthesis of structural diversity and complexity of azepines from aldimine esters and beta ‘-acetoxy allenoates is reported. Under phosphine catalysis, a [4+3] cycloaddition for the formation of 1,3-dihydro-2H-azepine-2,2,4-tricarboxylates was achieved with broad substrate scope under mild reactions. A switchable process was given and a variety of important 2,3-dihydrochromeno[4,3-b]azepin-6(1H)-ones were selectively formed when the reaction was performed in the presence of Cs2CO3 and PPh3, which involved an intramolecular ester group migration and subsequent lactonization of 1,3-dihydro-2H-azepine-2,2,4-tricarboxylates. Besides easy handle process, high synthetic value of resulting products, it is worth to note that this work showed the novel example of 1,5-ethoxycarbonyl migration.

About 2,6-Dichlorobenzoic acid, If you have any questions, you can contact Dai, ZH; Zhu, J; Wang, JH; Su, WB; Yang, FL; Zhou, QF or concate me.. HPLC of Formula: C7H4Cl2O2

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Recently I am researching about SOLUBLE MICROBIAL PRODUCTS; POLYCYCLIC AROMATIC-HYDROCARBONS; MOLECULAR-WEIGHT; EXCITATION; SMP; IDENTIFICATION; SPECTROSCOPY; FRACTIONS; SPECTRA; FENTON, Saw an article supported by the Natural Science of Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51608350, 51478291]; Mega-Projects of Science Research for Water Environment improvement [2015ZX07203]. Published in HARD in OLSZTYN 5 ,Authors: Wang, D; Wang, C; Ji, M; Sun, LP; Qiu, CS; Lo, SL. The CAS is 50-84-0. Through research, I have a further understanding and discovery of 2,4-Dichlorobenzoic acid. Name: 2,4-Dichlorobenzoic acid

In this study, the transformation characteristics of fluorescent dissolved organic matter (FDOM) were investigated to characterize the removal of dissolved organic matter (DOM) during biological treatment of commingled chemical industrial wastewater. The results of fluorescence excitation and emission spectroscopy and parallel factor analysis revealed three components (C1, C2, and C3) of FDOM, which were related not only to surface and sewage sources but also chemical industrial wastewater sources. Resin fractionation results showed that the removal of DOM was affected not only by substrate biodegradability but also by DOM generation, such as intermediates, end products, and soluble microbial products, during biological treatment. However, the same variation tendency between DOM and FDOM, based on molecular weight (MW) distribution, was observed during MW fractionation. The changes in DOM in MW>10 kDa fraction apparently corresponded with C2 variation; the tendency of DOM removal in MW of 0.5-10 kDa fraction was possibly related to the evolutions of all three components; and lastly, the removal of DOM in MW<0.5 kDa fraction was found in accordance with C1 and C3 transformations. The removal and transformation of DOM and FDOM were investigated using gas chromatography-mass spectrometer and Fourier transform infrared spectroscopy. Welcome to talk about 50-84-0, If you have any questions, you can contact Wang, D; Wang, C; Ji, M; Sun, LP; Qiu, CS; Lo, SL or send Email.. Name: 2,4-Dichlorobenzoic acid

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

An article Glycosyl triazoles as novel insect beta-N-acetylhexosaminidase OfHex1 inhibitors: Design, synthesis, molecular docking and MD simulations WOS:000468879400006 published article about ACETYL-D-HEXOSAMINIDASE; NAG-THIAZOLINE; DERIVATIVES; DYNAMICS; INSIGHTS in [Dong, Lili; Shen, Shengqiang; Lu, Huizhe; Xu, Dongdong; Jin, Shuhui; Zhang, Jianjun] China Agr Univ, Coll Sci, Dept Appl Chem, Beijing, Peoples R China; [Chen, Wei; Yang, Qing] Dalian Univ Technol, Sch Life Sci & Biotechnol, Dalian, Peoples R China; [Yang, Qing] Chinese Acad Agr Sci, Inst Plant Protect, Beijing 100193, Peoples R China in 2019.0, Cited 36.0. Formula: C7H4Cl2O2. The Name is 2,6-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-30-6

The insect enzyme GH20 beta-N-acetyl-D-hexosaminidase OfHex1 represents an important chitinolytic enzyme found in the agricultural pest Ostrinia furnacalis (Guenee) and inhibition of this enzyme has been considered a promising strategy for the development of eco-friendly pesticides. In this article, based on the structure of the catalytic domains of OfHex1, a series of novel glycosyl triazoles were designed and synthesized via Cu-catalyzed azide-alkyne [3+ 2] cycloaddition reaction. To investigate the potency and selectivity of these glycosyl triazoles, the inhibition activities towards OfHex1 and HsHexB (human beta-N-acetylhexosaminidase B) were studied. Particularly compound 17c (OfHex1, K-i= 28.68 mu M; HsHexB, K-i > 100 mu M) exhibited a suitable activity and selectivity against OfHex1. Furthermore, the possible inhibitory mechanisms of 17c with OfHex1 were studied using molecular docking and MD simulations. The structure-activity relationship results as well as the formed binding patterns may provide promising insights into the further development of novel OfHex1 inhibitors.

Formula: C7H4Cl2O2. Welcome to talk about 50-30-6, If you have any questions, you can contact Dong, LL; Shen, SQ; Chen, W; Lu, HZ; Xu, DD; Jin, SH; Yang, Q; Zhang, JJ or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics