Tag: 300-400

On February 3, 2022, Wang, Xiaomei; Zhu, Lin; Ju, Xiaolei; Wang, Kai; Ye, Changqing; Liang, Zuoqin; Chen, Shuoran published a patent.COA of Formula: C22H23ClN4 The title of the patent was Azaanthracene derivative upconversion system, preparation method therefor and use thereof. And the patent contained the following:

The present invention relates to an azaanthracene derivative upconversion system, a preparation method therefor and use thereof. The azaanthracene derivative free of noble metals and heavy atoms used as a photosensitizer material of TTA-UC can be effectively compounded with a 9,10-diphenylanthracene (DPA) light emitting agent to obtain TTA-UC, and a green-turn-blue upconversion efficiency of up to 9.69% can be obtained. Using the azaanthracene derivative as a light emitting agent material of single photon absorption upconversion, red light of 655 nm excitation can be achieved, a red-turn-yellow single photon absorption upconversion fluorescence color-changing effect of orange-yellow light at about 610 nm can be obtained, and upconversion color changes can be obtained without requiring oxygen removal, thereby enriching the types of light emitting agent materials in the field of single photon absorption upconversion. The azaanthracene derivative has a formula of I, wherein R1 and R2 are selected from NH2 and N(CH2CH3)2, R3 and R4 are selected from H and CH3. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).COA of Formula: C22H23ClN4

The Article related to azaanthracene derivative fluorescence upconversion system preparation, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Luminescence and other aspects.COA of Formula: C22H23ClN4

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On September 24, 1987, Bentz, Bryan L.; Gale, P. Jane published an article.COA of Formula: C22H23ClN4 The title of the article was Characterization of organic dyes aided by hydrogen-deuterium exchange in liquid secondary ion mass spectrometry (liquid SIMS). And the article contained the following:

The SIMS of several cationic dyes dissolved in glycerol and glycerol-d8 were presented. Dyes containing active hydrogens exhibited mass shifts in the spectra obtained from labeled and unlabeled glycerol, allowing inferences about mol. structure to be made. The exchange methodol. is useful in the study of reductive processes occurring in the liquid matrix and in distinguishing isomeric forms of dye compounds The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).COA of Formula: C22H23ClN4

The Article related to dye hydrogen exchange sims, mass spectra dye hydrogen exchange, Physical Organic Chemistry: Degradation Reactions, Including Mass Spectral Fragmentation and other aspects.COA of Formula: C22H23ClN4

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On August 19, 2009, Baeyens-Cabrera, Jose Manuel; Buschmann, Helmut H.; Vela Hernandez, Jose Miguel; Zamanillo-Castanedo, Daniel; Nieto-Lopez, Francisco Rafael published a patent.Quality Control of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the patent was Use of compounds binding to the sigma receptor for the treatment of neuropathic pain developing as a consequence of chemotherapy. And the patent contained the following:

The invention discloses the use of compounds binding to the sigma receptor for the treatment or prevention of neuropathic pain resulting from chemotherapy. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Quality Control of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to chemotherapy neuropathic pain treatment sigma receptor ligand analgesic, Pharmacology: Effects Of Nervous System- and Behavior-Affecting Drugs and Neuromuscular Agents and other aspects.Quality Control of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On August 27, 2009, Baeyens-Cabrera, Jose Manuel; Buschmann, Helmut H.; Vela-Hernandez, Jose-Miguel; Zamanillo-Castanedo, Daniel; Nieto-Lopez, Francisco Rafael published a patent.Product Details of 4569-86-2 The title of the patent was Use of compounds binding to the sigma receptor for the treatment of neuropathic pain developing as a consequence of chemotherapy. And the patent contained the following:

The present invention refers to the use of compounds binding to the sigma receptor for the treatment or prevention of neuropathic pain resulting from chemotherapy. The invention discloses the use of compounds binding to the sigma receptor for the treatment or prevention of neuropathic pain resulting from chemotherapy. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Product Details of 4569-86-2

The Article related to chemotherapy neuropathic pain treatment sigma receptor ligand analgesic, Pharmacology: Effects Of Nervous System- and Behavior-Affecting Drugs and Neuromuscular Agents and other aspects.Product Details of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On March 8, 2007, Buschmann, Helmut H. published a patent.Application of 4569-86-2 The title of the patent was Use of compounds binding to the sigma receptor for the treatment of diabetes-associated pain. And the patent contained the following:

The invention discloses the use of compounds active on the sigma receptor for the production of a medicament for the treatment of diabetes-associated pain. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Application of 4569-86-2

The Article related to diabetes pain analgesic sigma receptor binding compound, Pharmacology: Effects Of Nervous System- and Behavior-Affecting Drugs and Neuromuscular Agents and other aspects.Application of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On February 2, 2006, Baeyens Cabrera, Jose Manuel published a patent.Synthetic Route of 4569-86-2 The title of the patent was Use of compounds active on the sigma receptor for the treatment of mechanical allodynia. And the patent contained the following:

The invention discloses the use of compounds active on the sigma receptor for the treatment of mech. allodynia. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Synthetic Route of 4569-86-2

The Article related to mech allodynia treatment sigma receptor modulator, Pharmacology: Effects Of Nervous System- and Behavior-Affecting Drugs and Neuromuscular Agents and other aspects.Synthetic Route of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On May 23, 2007, Buschman, Helmut Heinrich published a patent.Electric Literature of 4569-86-2 The title of the patent was Use of compounds binding to the sigma receptor for the treatment of diabetes-associated pain. And the patent contained the following:

The invention discloses the use of compounds active on the sigma receptor for the production of a medicament for the treatment of diabetes-associated pain. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Electric Literature of 4569-86-2

The Article related to diabetes pain analgesic sigma receptor ligand, Pharmacology: Effects Of Nervous System- and Behavior-Affecting Drugs and Neuromuscular Agents and other aspects.Electric Literature of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On March 12, 2021, Wang, Kai; Jia, Fang; Song, Shihao; Zhao, Fang; Pan, Jie; Zhao, Yimei; Jiang, Jun; Ye, Wenjing published a patent.Reference of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the patent was Preparation of methylene violet derivatives as fluorescent probes for sulfide ion detection. And the patent contained the following:

The title compounds with general formula I•Cl- [wherein R1 = -NHCOCH2-R3, -NH(CH2O)n-R3, –NH(CH2NH)n-R3, -NH(CH2)n-R3, -N=N-(p-phenyl)-R3 or R3, where R3 is 7-nitro-4-(1-piperazinyl-4-yl)-2,1,3-benzoxadiazole; R2 = NH2 or N(Et)2; n = independently 1-12] were prepared as fluorescent probes. For example, compound II•Cl- was prepared in a multi-step synthesis. The fluorescent probe can be used for sulfide ion detection or preparing photodynamic therapy probe. The invention has good water solubility, high detection sensitivity, simple synthesis, mild condition, and low cost. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Reference of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to preparation methylene violet derivative fluorescent probes sulfide ion detection, Heterocyclic Compounds (More Than One Hetero Atom): Pyridazines, Cinnolines, and Phthalazines and other aspects.Reference of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On February 28, 1998, Proevska, L. I.; Pojarlieff, I. G. published an article.Computed Properties of 4569-86-2 The title of the article was 1H NMR spectra and structure of safranines. Hindered rotation of the 3-dialkylamino group in 7-azo derivatives. And the article contained the following:

The 1H NMR spectra of safranine derivatives are reported. Semiempirical calculations indicate that the high shielding of the 4- and 6-proton adjacent to an amino or hydroxyl group (resonating between 5.5 and 6.0 ppm) is due to accumulation of neg. charge on the 4-and 6-C atoms, augmented by the magnetic anisotropy effect of the orthogonal 5-Ph ring. The ortho protons of the latter resonate up field to the meta and para protons. Hindered rotation of dialkylamino groups, altogether unexpected in view of the rather low barriers in similar anilines, is observed only in the azo derivatives AM1 suggests that this is due to destabilization of the transition state when an amino group is substituted for an azo group. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Computed Properties of 4569-86-2

The Article related to azo derivative safranine hindered rotation, alkylamino hindered rotation safranine derivative, Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers: Heterocyclics and other aspects.Computed Properties of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On July 31, 2003, Jonnalagadda, S. B.; Shezi, M.; Pare, B. published an article.Synthetic Route of 4569-86-2 The title of the article was Uncatalyzed and ruthenium(III)-catalyzed reaction of acidic chlorite with methylene violet. And the article contained the following:

The kinetics and mechanism of the uncatalyzed and Ru(III)-catalyzed oxidation of methylene violet [3-amino-7-(diethylamino)-5-phenylphenazinium chloride] (MV) by acidic chlorite is reported. With excess concentrations of other reactants, both uncatalyzed and catalyzed reactions had pseudo-first-order kinetics with respect to MV. The uncatalyzed reaction had first-order dependence on chlorite and H+ concentrations, but the catalyzed reaction had first-order dependence on both chlorite and catalyst, and a fractional order with respect to [H+]. The rate coefficient of the uncatalyzed reaction is (5.72 ± 0.19) M-2 s-1, while the catalytic constant for the catalyzed reaction is (22.4 ± 0.3) × 103 M-1 s-1. Stoichiometry is dependent on the initial concentration of chlorite present. Consistent with the exptl. results, pertinent mechanisms are proposed. The proposed 15-step mechanism is simulated using literature; exptl. and estimated rate coefficients and the simulated plots agreed well with the exptl. curves. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Synthetic Route of 4569-86-2

The Article related to chlorite oxidation kinetics methylene violet dye ruthenium catalyst, Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers: Heterocyclics and other aspects.Synthetic Route of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics