Joshiba, G. Janet et al. published their research in Environmental Research in 2022 | CAS: 61-73-4

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride

Iron doped activated carbon for effective removal of tartrazine and methylene blue dye from the aquatic systems: Kinetics, isotherms, thermodynamics and desorption studies was written by Joshiba, G. Janet;Kumar, P. Senthil;Rangasamy, Gayathri;Ngueagni, P. Tsopbou;Pooja, G.;Balji, G. Bharat;Alagumalai, Krishnapandi;El-Serehy, Hamed A.. And the article was included in Environmental Research in 2022.Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride This article mentions the following:

In the current research work, the activated carbon synthesized from the plant species Delonix regia is doped with iron oxide nanoparticles and enforced as a nanosorbent for the effective extermination of Tartrazine (TAR) and Methylene blue (MB) dyes. This nanosorbent is prepared from the bark powder of the Delonix regia and subjected to chem. activation; Furthermore, the synthesized biosorbent were characterized using FTIR, SEM, TGA, and XRD to understand their functional properties and structural morphol. The optimum effectiveness adsorption of Tartrazine and Methylene blue has been investigated by using different key parameters. The conclusions have shown the highest removal percentage at a pH of 3 and 6 for Tartrazine and Methylene blue, resp. For the various initial concentrations, the adsorption percentage reached equilibrium after 60 min and 90 min for TAR and MB. The adsorption equilibrium values were applied to various isotherms models. The adsorbent showed a higher removal capacity of 357.142 mg g-1 and 147.058 mg g-1 and for MB and TAR resp. The kinetic data were best fits to pseudo second order model. The thermodn. parameters indicated that this adsorption process was found to be spontaneous, exothermic and feasible at different temperatures These results have shown that the prepared adsorbent is an environmentally friendly and suitable material for the elimination of TAR and MB from water systems. In the experiment, the researchers used many compounds, for example, 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride).

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Huang, Shiyang et al. published their research in Water Research in 2021 | CAS: 101-20-2

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Electric Literature of C13H9Cl3N2O

Surface modification of nanofiltration membranes to improve the removal of organic micropollutants: Linking membrane characteristics to solute transmission was written by Huang, Shiyang;McDonald, James A.;Kuchel, Rhiannon P.;Khan, Stuart J.;Leslie, Greg;Tang, Chuyang Y.;Mansouri, Jaleh;Fane, Anthony G.. And the article was included in Water Research in 2021.Electric Literature of C13H9Cl3N2O This article mentions the following:

Surface modification of nanofiltration (NF) membranes has great potential to improve the removal of organic micropollutants (OMs) by NF membranes. This study used polydopamine (PDA) as a model coating to comprehensively link the changes in membrane properties with the changes in transmission of 34 OMs. The membrane characterization demonstrated that a thicker, denser, and more hydrophilic PDA coating can be achieved by increasing the PDA deposition time from 0.5 to 4 h. Overall, the transmissions of target OMs were reduced by PDA-coated NF membranes compared to unmodified NF membranes. The neutral hydrophobic compounds showed lower transmissions for longer PDA coating (PDA4), while the neutral hydrophilic compounds tended to show lower transmissions for shorter PDA coating (PDA0.5). To explain this, competing effects provided by the PDA coatings are proposed including sealing defects, inducing cake-enhanced concentration polarization in the coating layer for neutral hydrophilic compounds, and weakened hydrophobic adsorption for neutral hydrophobic compounds For charged compounds, PDA4 with the greatest neg. charge among the PDA-coated membranes showed the lowest transmission. Depending on the mol. size and hydrophilicity of the compounds, the transmission of OMs by the PDA4 coating could be reduced by 70% with only a 26.4% decline in water permeance. The correlations and mechanistic insights provided by this work are highly useful for designing membranes with sp. surface properties via surface modification to improve the removal of OMs without compromising water production In the experiment, the researchers used many compounds, for example, 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2Electric Literature of C13H9Cl3N2O).

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Electric Literature of C13H9Cl3N2O

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Sayed, Marwa M. et al. published their research in Scientific Reports in 2022 | CAS: 61-73-4

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Computed Properties of C16H18ClN3S

Synthesis, physico-chemical characterization, and environmental applications of meso porous crosslinked poly (azomethine-sulfone)s was written by Sayed, Marwa M.;Abdel-Hakim, Mohamed;Mahross, Mahmoud H.;Aly, Kamal I.. And the article was included in Scientific Reports in 2022.Computed Properties of C16H18ClN3S This article mentions the following:

To develop innovative mesoporous crosslinked poly(azomethine- sulfone)s with environmental applications, a simple Schiff base condensation technique based on barbituric acid BA or condensed terephthaldehyde barbituric acid TBA in their structures as monomeric units are applied. Different anal. methodologies and viscosity measurements identify them as having stronger heat stability and an amorphous structure. The photophys. features of the multi stimuli response MSR phenomenon are observable, with white light emission at higher concentrations and blue light emission at lower concentrations Their emission characteristics make them an excellent metal ions sensor through diverse charge transfer methods. They can have a better inhibition efficiency and be employed as both mixed-type and active corrosion inhibitors according to their fluorescence emission with metals, demonstrating their capacity to bind with diverse metals. The adsorption of two distinct dye mols., Methylene blue MB cationic and sunset yellow SY anionic, on the mesoporous structures of the polymers is investigated, revealing their selectivity for MB dye adsorption. Quantum studies support these amazing discoveries, demonstrating a crab-like monomeric unit structure for the one that is heavily crosslinked. In the experiment, the researchers used many compounds, for example, 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4Computed Properties of C16H18ClN3S).

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Computed Properties of C16H18ClN3S

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Qu, Ting et al. published their research in Scientific Reports in 2022 | CAS: 61-73-4

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride

A sustainable natural clam shell derived photocatalyst for the effective adsorption and photodegradation of organic dyes was written by Qu, Ting;Yao, Xinxin;Owens, Gary;Gao, Liangjun;Zhang, Hailong. And the article was included in Scientific Reports in 2022.Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride This article mentions the following:

In response to an increasing desire for modern industries to be both green and sustainable, there has been increasing research focus on the reutilization of natural waste materials to effectively remove and degrade toxic wastewater effluents. One interesting food industry waste product is clam shell. Here a new photocatalytic nanomaterial derived from marine clam shells was successfully prepared and characterized. Thereafter the material was applied for the removal of two target dyes from aqueous solution, where the effect of both catalyst dose and initial dye concentration on adsorption and photocatalysis was investigated. The maximum adsorption capacities of methylene blue (100 mg/L) and Congo red (500 mg/L) were 123.45 mg/g and 679.91 mg/g, resp., where adsorption followed pseudo second order kinetics predominantly via a chem. adsorption process. The photodegradation removal efficiencies of the two dye solutions under visible light irradiation were 99.6% and 83.3% for MB and CR, resp. The excellent degradation performance in a mixed dye solution, with strong degradation capability and low cost, demonstrated that the clam shell catalyst material was a good candidate for practical field remediation of dye contaminated wastewater. In the experiment, the researchers used many compounds, for example, 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride).

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Fouda, Amr et al. published their research in Scientific Reports in 2022 | CAS: 61-73-4

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Category: chlorides-buliding-blocks

Light enhanced the antimicrobial, anticancer, and catalytic activities of selenium nanoparticles fabricated by endophytic fungal strain, Penicillium crustosum EP-1 was written by Fouda, Amr;Hassan, Saad El-Din;Eid, Ahmed M.;Abdel-Rahman, Mohamed Ali;Hamza, Mohammed F.. And the article was included in Scientific Reports in 2022.Category: chlorides-buliding-blocks This article mentions the following:

Selenium nanoparticles (Se-NPs) has recently received great attention over owing to their superior optical properties and wide biol. and biomedical applications. Herein, crystallog. and dispersed spherical Se-NPs were green synthesized using endophytic fungal strain, Penicillium crustosum EP-1. The antimicrobial, anticancer, and catalytic activities of biosynthesized Se-NPs were investigated under dark and light (using Halogen tungsten lamp, 100 W, λ > 420 nm, and light intensity of 2.87 W m-2) conditions. The effect of Se-NPs was dose dependent and higher activities against Gram-pos. and Gram-neg. bacteria as well different Candida spp. were attained in the presence of light than obtained under dark conditions. Moreover, the viabilities of two cancer cells (T47D and HepG2) were highly decreased from 95.8 ± 2.9% and 93.4 ± 3.2% in dark than those of 84.8 ± 2.9% and 46.4 ± 3.3% under light-irradiation conditions, resp. Significant decreases in IC50 values of Se-NPs against T47D and HepG2 were obtained at 109.1 ± 3.8 and 70.4 ± 2.5μg mL-1, resp. in dark conditions than 19.7 ± 7.2 and 4.8 ± 4.2μg mL-1, resp. after exposure to light-irradiation The photoluminescence activity of Se-NPs revealed methylene blue degradation efficiency of 89.1 ± 2.1% after 210 min under UV-irradiation compared to 59.7 ± 0.2% and 68.1 ± 1.03% in dark and light conditions, resp. Moreover, superior stability and efficient MB degradation efficiency were successfully achieved for at least five cycles. In the experiment, the researchers used many compounds, for example, 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4Category: chlorides-buliding-blocks).

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ji, Shengxiang et al. published their research in Reactive & Functional Polymers in 2001 | CAS: 12083-92-0

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: C10H10Cl2Pt

Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group was written by Ji, Shengxiang;Xu, Hui;Zhou, Xiaoshu;Dai, Daorong;Zhang, Rongben. And the article was included in Reactive & Functional Polymers in 2001.Formula: C10H10Cl2Pt This article mentions the following:

A new soluble ladder-like polysilsesquioxane with polar lateral aryl ester group, which has good adhesion properties and could be potential precursors of advanced functional materials such as catalyst carriers, polymeric solid electrolytes and microelectronic packaging materials etc., was successfully synthesized by stepwise coupling polymerization (SCP) method. The monomer used, Me 4-trichlorosilylpropoxybenzoate, was synthesized by hydrosilylation reaction catalyzed by dicyclopentadienylplatinum(II) dichloride (Cp2PtCl2). The titled polymer was characterized by 1H NMR, 29Si NMR, FTIR, X-ray diffraction (XRD) and gel permeation chromatog. (GPC). The characterization data demonstrate that the polymer possesses a typical ladder-like structure. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Formula: C10H10Cl2Pt).

Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: C10H10Cl2Pt

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Li, Siwen et al. published their research in Fish & Shellfish Immunology in 2022 | CAS: 101-20-2

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.COA of Formula: C13H9Cl3N2O

Triclocarban evoked neutrophil extracellular trap formation in common carp (Cyprinus carpio L.) by modulating SIRT3-mediated ROS crosstalk with ERK1/2/p38 signaling was written by Li, Siwen;Wang, Yanling;Yu, Dongke;Zhang, Yuan;Wang, Xiali;Shi, Mei;Xiao, Yanxin;Li, Xinlian;Xiao, Hongtao;Chen, Lu;Xiong, Xuan. And the article was included in Fish & Shellfish Immunology in 2022.COA of Formula: C13H9Cl3N2O This article mentions the following:

Triclocarban (TCC), an antimicrobial ingredient in personal care products, is associated with immunosuppression and physiol. dysfunctions of aquatic organisms. The aim of this study was to investigate whether TCC can induce common carp NETosis (neutrophil death by neutrophil extracellular trap (NET) release) and then to attempt to identify the potential mol. mechanisms. Herein, SEM and flow cytometric assays showed that revealed that TCC triggers DNA-containing web-like structures and increases extracellular DNA content. In the proteomic anal., we observed that NET-related proteins, extracellular regulated protein kinase (Mapk1, Mapk14, Jak2) and apoptotic protein (caspase3) were significantly increased, and defender against cell death 1 (Dad1) was significantly decreased after TCC treatments. Meanwhile, we confirmed that TCC stress can trigger NETosis in common carp by activating the reactive oxygen species (ROS)/ERK1/2/p38 signaling. We think that the upregulated NDUFS1 expression is closely related to oxidative stress induced by TCC. Importantly, we discovered that SIRT3 expression was significantly decreased in the process of TCC-induced NETs. Importantly, pretreatment with the SIRT3 agonist honokiol (HKL) effectively suppressed TCC-induced NET release. In contrast, the SIRT3 antagonist 3-TYP escalated TCC-induced NET formation. Mechanistically, SIRT3 degradation serves as a potential mediator for regulating oxidative stress crosstalk between ERK1/2/p38 signals in the process of TCC-induced NET formation. These findings unveil new insights into the TCC-evoked health risk of fish and other aquatic organisms and suggest that SIRT3 is a potential pharmacol. intervention target to alleviate TCC-induced common carp NETosis. In the experiment, the researchers used many compounds, for example, 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2COA of Formula: C13H9Cl3N2O).

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.COA of Formula: C13H9Cl3N2O

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Kebede, Mekonnen Tefera et al. published their research in Materials Science in Semiconductor Processing in 2022 | CAS: 61-73-4

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Reference of 61-73-4

Structural transition and enhanced magnetic, optical and photocatalytic properties of novel Ce-Ni co-doped BiFeO3 nanoparticles was written by Kebede, Mekonnen Tefera;Devi, Sheela;Tripathi, Babita;Chauhan, Sunil;Dillu, Venus. And the article was included in Materials Science in Semiconductor Processing in 2022.Reference of 61-73-4 This article mentions the following:

Bi1-xCexFe1-xNixO3 (x = 0%, 4%, 6% and 8%) samples were synthesized using sol-gel method to study strategically the influence of Ce-Ni co-doping on structural, vibrational, magnetic, optical and photocatalytic properties utilizing various techniques. XRD showed that whole samples crystallized in single-phase as well as revealed a huge lattice distortion with rising Ce-Ni co-substitution content. A structural phase change from rhombohedral to orthorhombic occurred at the co-substitution sample with x = 8%, confirmed by XRD and the Rietveld refinement as well as Raman anal. EDS anal. evidenced the existence of Bi, Fe, Ce as well as Ni concentrations in the co-substitution samples with stoichiometric proportion. Crystallinity is noted to be raised when Ce-Ni is co-substitution in BiFeO3 (BFO). Ce-Ni co-doped in BiFeO3 significantly induced improvement of ferromagnetic property, which was shown by the drastic rising with a maximum saturation (Ms) magnetization values of 2.741 emu/g. The optical energy bandgap was sharply reduced with the Ce-Ni co-substitution concentration It was found that Ce3+ and Ni2+ co-substitution enormously impacted the photocatalytic efficiency of undoped BFO. Furthermore, with the increase of Ce-Ni co-doping into BFO up to 6%, the photocatalytic efficiency was maximized. The photocatalytic feasibility mechanism of Ce-Ni co-substitution BFO was discussed in detail. We have noted in this work that the fascinating properties in co-substituted BiFeO3 give the feasibility of producing a novel functional device. In the experiment, the researchers used many compounds, for example, 3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4Reference of 61-73-4).

3,7-Bis(dimethylamino)phenothiazin-5-ium chloride (cas: 61-73-4) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Reference of 61-73-4

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Rueda-Marquez, Juan Jose et al. published their research in Water Research in 2021 | CAS: 101-20-2

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Reference of 101-20-2

Post-treatment of real municipal wastewater effluents by means of granular activated carbon (GAC) based catalytic processes: A focus on abatement of pharmaceutically active compounds was written by Rueda-Marquez, Juan Jose;Moreno-Andres, Javier;Rey, Ana;Corada-Fernandez, Carmen;Mikola, Anna;Manzano, Manuel A.;Levchuk, Irina. And the article was included in Water Research in 2021.Reference of 101-20-2 This article mentions the following:

Pharmaceutically active compounds (PhACs) widely present in urban wastewater effluents pose a threat to ecosystems in the receiving aquatic environment. In this work, efficiency of granular activated carbon (GAC) – based catalytic processes, namely catalytic wet peroxide oxidation (CWPO), peroxymonosulfate oxidation (PMS/GAC) and peroxydisulfate oxidation (PDS/GAC) at ambient temperature and pressure were studied for removal of 22 PhACs (ng L-1 level) that were present in secondary effluents of real urban wastewater. Concentrations of PhACs were measured using Ultra Performance Liquid Chromatog. – Triple Quadrupole Mass Spectrometry (UPLC-QqQ-MS/MS). Catalytic experiments were conducted in discontinuous mode using up-flow fixed bed reactors with granular activated carbon (GAC) as a catalyst. The catalyst was characterized by means of N2 adsorption-desorption isotherm, mercury intrusion porosimetry (MIP), elemental anal., X-ray fluorescence spectroscopy (WDXRF), X-ray diffraction (XRD), thermal gravimetry and differential temperature analyses coupled mass spectrometry (TGA-DTA-MS). Results indicate that the highest efficiency in terms of TOC removal was achieved during CWPO performed at optimal operational conditions (stoichiometric dose of H2O2; TOC removal ~82%) followed by PMS/GAC (initial PMS concentration 100 mg L-1; TOC removal ~73.7%) and PDS/GAC (initial PDS concentration 100 mg L-1; TOC removal ~67.9%) after 5 min of contact time. Full consumption of oxidants was observed in all cases for CWPO and PDS/GAC at contact times of 2.5 min, while for PMS/GAC it was 1.5 min. In general, for 18 out of 22 target PhACs, very high removal efficiencies (> 92%) were achieved in all tested processes (including adsorption) performed at optimal operational conditions during 5 min of contact time. However, moderate (40 – 70%) and poor (< 40%) removal efficiencies were achieved for salicylic acid, ofloxacin, norfloxacin and ciprofloxacin, which can be possibly attributed to insufficient contact time. Despite high efficiency of all studied processes for PhACs elimination from urban wastewater effluent, CWPO seems to be more promising for continuous operation. In the experiment, the researchers used many compounds, for example, 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2Reference of 101-20-2).

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Reference of 101-20-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Khan, Hudda Khaleeq et al. published their research in Science of the Total Environment in 2022 | CAS: 101-20-2

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Application In Synthesis of 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea

Occurrence, source apportionment and potential risks of selected PPCPs in groundwater used as a source of drinking water from key urban-rural settings of Pakistan was written by Khan, Hudda Khaleeq;Rehman, Muhammad Yasir Abdur;Junaid, Muhammad;Lv, Ming;Yue, Linxia;Haq, Ihsan-ul;Xu, Nan;Malik, Riffat Naseem. And the article was included in Science of the Total Environment in 2022.Application In Synthesis of 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea This article mentions the following:

Pharmaceuticals and personal care products (PPCPs) are emerging contaminants that have been extensively used in present time to improve the living standards Their persistence in water resources due to various anthropogenic sources such as wastewater treatment plants, pharmaceutical industries, and runoff from agricultural and livestock farms has not only threaten aquatic life but their occurrence in groundwater has also raised concerns related to humans�wellbeing. Considering this as a neglected area of research in Pakistan, a systematic monitoring study was designed to investigate their occurrence, sources, and potential environmental and human health risks in groundwater from urban-rural areas of six cities. Ultra-High-Performance Liquid Chromatog.-Tandem Mass Spectrometry (UHPLC-MS/MS) was used to analyze the collected samples preceded by solid-phase extraction Overall, 8 out of 11 selected PPCPs were detected in groundwater samples with detection frequency ranging from 5.5-65%. Their concentrations ranged from below limit of detection (<LOD) to 1961 ng/L. The overall mean concentrations of detected PPCPs were found below 100 ng/L. The highest mean concentration was reported for Ibuprofen (154 ng/L) in Rawalpindi/Islamabad. Results of PCA-MLR revealed that domestic wastewater discharge (76.4%) was the dominant source contributing to PPCPs contamination in groundwater. Followed by mixed source (pharmaceutical & hospital waste) 17.8%, and rural discharge/animal husbandry 5.8%. No appreciable risk to human health upon exposure to detected PPCPs via drinking water was anticipated. However, environmental risk assessment indicated moderate risk posed to P. subcapitata (RQ = 0.98) and D. magna (RQ = 0.2) by ibuprofen. The current study reports the first evidence of PPCPs occurrence in groundwater in Pakistan. Reporting their occurrence in groundwater is a fundamental initial step to inform public-health decisions concerning sewage systems and drinking water quality. Hence, comprehensive monitoring programs are required to further investigate contamination of emerging contaminants in groundwater and their associated risks. In the experiment, the researchers used many compounds, for example, 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2Application In Synthesis of 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea).

1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea (cas: 101-20-2) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Application In Synthesis of 1-(4-Chlorophenyl)-3-(3,4-dichlorophenyl)urea

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics