Tag: 200-300

NMR studies of the dynamic behavior of 2-anilino-6-chloro-4-methoxy-1,3,5-triazine in solution was written by Belyakov, P. A.;Shastin, A. V.;Strelenko, Yu. A.. And the article was included in Russian Chemical Bulletin in 2001.Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine The following contents are mentioned in the article:

2-Anilino-6-chloro-4-methoxy-1,3,5-triazine was synthesized and studied by dynamic NMR. The activation parameters of hindered internal rotation in unsym. substituted arylamino-sym-triazine were determined for the first time. It was found that a sterically more hindered rotational isomer is thermodynamically more stable in this compound (slow-exchange NOE data). This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine).

4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis of chalcones, pyrazolines, amino pyrimidines and pyrimidinethiones as antibacterial agents was written by Solankee, Anjani;Patel, Jayesh. And the article was included in Indian Journal of Chemistry in 2004.Electric Literature of C9H6Cl2N4 The following contents are mentioned in the article:

2-Phenylamino-4-(3′-fluorophenylamino)-6-(4′-acetylphenyl-amino)-s-triazine on treatment with aromatic aldehydes yields chalcones, which on cyclization with hydrazine hydrate, guanidine nitrate and thiourea give the corresponding pyrazolines, amino pyrimidines and pyrimidinethiones, resp. The synthesized compounds are screened for their antibacterial activity. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Electric Literature of C9H6Cl2N4).

4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of C9H6Cl2N4

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Iodine-catalyzed synthesis of 5-benzoyl-8H-phthalazino[1,2-b]quinazolin-8-one derivatives via a domino reaction involving a benzyl automatic oxidation by oxygen was written by Liu, Jian-Quan;Feng, Bin-Bin;Wang, Xiang-Shan. And the article was included in Tetrahedron in 2018.Quality Control of 5-Chloro-2-(phenylethynyl)benzaldehyde The following contents are mentioned in the article:

A one-pot procedure for the synthesis of 5-benzoyl-8H-phthalazino[1,2-b]quinazolin-8-ones was achieved by an iodine-catalyzed reaction of 2-aminobenzohydrazides and 2-alkynylbenzaldehydes in good yields. The salient feature of this strategy is a domino type process including a condensation, addition, hydroamination, and a noteworthy benzyl automatic oxidation by oxygen under metal-catalyst-free conditions. This study involved multiple reactions and reactants, such as 5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3Quality Control of 5-Chloro-2-(phenylethynyl)benzaldehyde).

5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Quality Control of 5-Chloro-2-(phenylethynyl)benzaldehyde

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Study of the dependence of the reactivity of substituted dichloro-s-triazines on the nature of the substituent was written by Smirnova, O. V.;Bolmosova, V. P.;Kutepov, D. F.;Eryshev, B. Ya.. And the article was included in Zhurnal Prikladnoi Khimii in 1979.Synthetic Route of C9H6Cl2N4 The following contents are mentioned in the article:

Substituents having π-π, π-p, or π-p-π conjugation with the triazine ring increase its basicity and decrease its rate of nucleophilic substitution in polycondensation with bisphenol A [80-05-7]. Rate constants for the polymerization of 2-substituted 4,6-dichloro-1,3,5-triazines with bisphenol A increase in the substituent order: Ph < piperidyl < NHPh < NPh₂. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Synthetic Route of C9H6Cl2N4).

4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Synthetic Route of C9H6Cl2N4

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Isoquinolone synthesis via Zn(OTf)₂-catalyzed aerobic cyclocondensation of 2-(1-alkynyl)-benzaldehydes with arylamines was written by Khan, Dost Muhammad;Hua, Ruimao. And the article was included in Catalysts in 2020.Application In Synthesis of 5-Chloro-2-(phenylethynyl)benzaldehyde The following contents are mentioned in the article:

A zinc(II) triflate-catalyzed cyclocondensation of ortho-alkynylbenzaldehydes with arylamines was developed in the presence of base under an oxygen atm. and afforded isoquinolones in good to high yields. The advantages of the present catalyst system include the use of an air-stable and cheap com. available Lewis acid as the catalyst, high atom utilization and easily available starting materials. This study involved multiple reactions and reactants, such as 5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3Application In Synthesis of 5-Chloro-2-(phenylethynyl)benzaldehyde).

5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Application In Synthesis of 5-Chloro-2-(phenylethynyl)benzaldehyde

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Study on the iodine-catalyzed reaction of 3-aminopyrazine-2-carbohydrazide and 2-(arylethynyl)benzaldehydes was written by Pan, Wan-Chen;Liu, Jian-Quan;Wang, Xiang-Shan. And the article was included in Tetrahedron in 2018.Reference of 1186603-47-3 The following contents are mentioned in the article:

At 60°C in DMSO, the iodine-catalyzed reaction of 3-aminopyrazine-2-carbohydrazide and 2-(arylethynyl)benzaldehydes led hydrazones. Increasing the reaction temperature to 100°C, the amino and amido still indicated inactive, only the imine took part in the addition of acetylene bond to give 2-arylisoquinolines in high yields with the cleavage of N-N bond unexpectedly under metal-free conditions. This study involved multiple reactions and reactants, such as 5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3Reference of 1186603-47-3).

5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Reference of 1186603-47-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

CuI/I₂-promoted electrophilic tandem cyclization of 2-ethynylbenzaldehydes with ortho-benzenediamines: Synthesis of Iodoisoquinoline-Fused Benzimidazoles was written by Ouyang, Huang-Che;Tang, Ri-Yuan;Zhong, Ping;Zhang, Xing-Guo;Li, Jin-Heng. And the article was included in Journal of Organic Chemistry in 2011.Formula: C15H9ClO The following contents are mentioned in the article:

An efficient tandem route to the synthesis of iodo isoquinoline-fused benzimidazole derivatives, e.g., I including an iodocyclization strategy has been developed. In the presence of CuI, a variety of 2-ethynylbenzaldehydes underwent the tandem reaction with benzenediamines and iodine to afford the corresponding iodo isoquinoline-fused benzimidazoles in moderate to good yields. This study involved multiple reactions and reactants, such as 5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3Formula: C15H9ClO).

5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Formula: C15H9ClO

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis of H-Pyrazolo[5,1-a]isoquinolines via Copper(II)-Catalyzed Oxidation of an Aliphatic C-H Bond of Tertiary Amine in Air was written by Li, Shaoyu;Wu, Jie. And the article was included in Organic Letters in 2011.Formula: C15H9ClO The following contents are mentioned in the article:

A multicomponent reaction of 2-alkynylbenzaldehyde, sulfonohydrazide, and tertiary amine is discovered, which generates the unexpected H-pyrazolo[5,1-a]isoquinolines, e.g., I in good yields under mild conditions. In the reaction process, silver(I)-catalyzed intramol. cyclization and copper(II)-catalyzed oxidation of an aliphatic C-H bond of tertiary amine in air are involved. This study involved multiple reactions and reactants, such as 5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3Formula: C15H9ClO).

5-Chloro-2-(phenylethynyl)benzaldehyde (cas: 1186603-47-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Formula: C15H9ClO

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis and studies of chalcones and its cyanopyridine and acetyl pyrazoline derivatives was written by Solankee, Anjani;Patel, Ghanshyam;Solankee, Sejal. And the article was included in Rasayan Journal of Chemistry in 2008.Name: 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine The following contents are mentioned in the article:

Chalcones were achieved upon refluxing of ketone and different substituted aromatic and heterocyclic aldehydes in suitable solvent. Chalcones on cyclization with malononitrile in presence of ammonium acetate and hydrazine hydrate in presence of acetic acid give cyanopyridines and acetyl pyrazoline, resp. All the synthesized compounds were characterized by their phys. data and spectral data. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Name: 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine).

4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Name: 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Quantitative structure-activity relationship studies of selected heterocyclic nitrogen compounds was written by Chen, J.;Wang, L.;Lu, G.;Zhao, T.. And the article was included in Bulletin of Environmental Contamination and Toxicology in 1997.Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine The following contents are mentioned in the article:

Quant. structure-activity relationship studies were performed on seven 1,3,5-triazine derivatives , five pyrimidine derivatives and one pyridine derivative, used as intermediates in pesticide synthesis. Octanol/water partition coefficients and quantum chem. descriptors were used. Acute toxicity to Daphnia magna was compared to toxicity predicted by the equation of Y.H. Zhao, et al. (1979). This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine).

4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application In Synthesis of 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics