Tag: 100-200

Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)₃]^– was written by Proehm, Patrick;Schwarze, Nico;Mueller, Carsten;Steinhauer, Simon;Beckers, Helmut;Rupf, Susanne M.;Riedel, Sebastian. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Reference of 75-57-0 The following contents are mentioned in the article:

The authors present the synthesis and characterization of the first non-classical Cl(I) polyinterhalide [NMe₄][F(ClF)₃] as well as the homologous polychloride [NPr₃Me][Cl₇]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl₂, resp. Quantum-chem. studies predict an unexpected planar structure for the [F(ClF)₃]^– anion. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Reference of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Reference of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The Combination of Benzaldehyde and Nickel-Catalyzed Photoredox C(sp³)-H Alkylation/Arylation was written by Zhang, Lumin;Si, Xiaojia;Yang, Yangyang;Zimmer, Marc;Witzel, Sina;Sekine, Kohei;Rudolph, Matthias;Hashmi, A. Stephen K.. And the article was included in Angewandte Chemie, International Edition in 2019.Application of 6294-17-3 The following contents are mentioned in the article:

Herein the authors report a highly selective photoredox C(sp³)-H alkylation/arylation of ethers through the combination of a photoorganocatalyst (benzaldehyde) and a transition-metal catalyst (nickel). This method provides a simple and general strategy for the C(sp³)-H alkylation/arylation of ethers. A selective late-stage modification of (-)-ambroxide also was conducted to demonstrate the applicability of the method. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Application of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Carbohydrate Microarrays Containing Glycosylated Fluorescent Probes for Assessment of Glycosidase Activities was written by Hyun, Ji Young;Kang, Na Rae;Shin, Injae. And the article was included in Organic Letters in 2018.SDS of cas: 95-88-5 The following contents are mentioned in the article:

Carbohydrate microarrays, containing glycosylated fluorescent probes, have been constructed using N-hydroxysuccinimide (NHS) ester-conjugated BSA modified surfaces. When the carbohydrate moieties were cleaved from the fluorescent probes in the conjugates by glycosidases, the fluorescence signals of the probes were enhanced. In this study, we have applied these microarrays to profile glycosidase activities and have employed them to determine IC₅₀ values of glycosidase inhibitors. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5SDS of cas: 95-88-5).

4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).SDS of cas: 95-88-5

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nickel-Catalyzed Cross-Coupling of Potassium Aryl- and Heteroaryltrifluoroborates with Unactivated Alkyl Halides was written by Molander, Gary A.;Argintaru, O. Andreea;Aron, Ioana;Dreher, Spencer D.. And the article was included in Organic Letters in 2010.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

A method for the cross-coupling of alkyl electrophiles with various potassium aryl- and heteroaryltrifluoroborates has been developed. Nearly stoichiometric amounts of organoboron species could be employed to cross-couple a large variety of challenging heteroaryl nucleophiles. Several functional groups were tolerated on both the electrophilic and the nucleophilic partners. Chemoselective reactivity of C(sp³)-Br bonds in the presence of C(sp²)-Br bonds was achieved. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Category: chlorides-buliding-blocks).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Diatomite incorporation in zeolite Fu-1 was written by Vinaches, Paloma;da Silva Filho, Severino H.;Souza, Iane M. S.;Pergher, Sibele B. C.. And the article was included in Materials Letters in 2021.HPLC of Formula: 75-57-0 The following contents are mentioned in the article:

The effect is studied of an alternative raw source for the synthesis of zeolite Fu-1. The reference material with com. raw sources are available since 1980s and have been studied intermittently along 1990s. The decision to continue its study drove to the acquisition of a hierarchical material with a lower Si/Al ratio that the reference material. The results are discussed from the characterization techniques (e.g. X-ray diffraction, microscopy) and comparing with the reference material. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0HPLC of Formula: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.HPLC of Formula: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nucleophilic Cyclization/Electrophilic Substitution of (2,2-Dialkoxyethyl)ureas: Highly Regioselective Access to Novel 4-(Het)arylimidazolidinones and Benzo[d][1,3]diazepinones was written by Smolobochkin, Andrey V.;Gazizov, Almir S.;Otegen, Nazerke K.;Voronina, Julia K.;Strelnik, Anna G.;Samigullina, Aida I.;Burilov, Alexander R.;Pudovik, Michail A.. And the article was included in Synthesis in 2020.Recommanded Product: 4-Chlororesorcinol The following contents are mentioned in the article:

Herein, a highly regioselective acid-catalyzed intramol. nucleophilic cyclization/intermol. electrophilic substitution reaction sequence of (2,2-dialkoxyethyl)ureas was reported. The reaction benefits from readily available starting materials, a simple workup procedure, moderate to high yields of target compounds and provided a convenient entry to previously unknown 4-(het)arylimidazolidinones and 5-(het)arylbenzodiazepinones. The proposed mechanism of the reaction was also discussed. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5Recommanded Product: 4-Chlororesorcinol).

4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: 4-Chlororesorcinol

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

EPR and optical absorption of VO²⁺ doped tetramethylammonium tetrachloro-zincate was written by Kumar Yadav, Awadhesh;Govind, Har;Kripal, Ram. And the article was included in Inorganic Chemistry Communications in 2022.Recommanded Product: Tetramethylammonium chloride The following contents are mentioned in the article:

EPR studies of VO²⁺ ions in [NMe₄]₂ZnCl₄ (TMZ) single crystals are done at room temperature Four magnetically equivalent VO²⁺ sites are observed from EPR anal. VO²⁺ ion substitutes at Zn²⁺ site. The principal g and A tensors are determined from angular variation of the EPR spectra. The optical absorption study is also performed. Using EPR and optical data the nature of bonding in the crystal is discussed. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Recommanded Product: Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Efficient synthesis of alkylboronic esters via magnetically recoverable copper nanoparticle-catalyzed borylation of alkyl chlorides and bromides was written by Shegavi, Mahadev L.;Agarwal, Abhishek;Bose, Shubhankar Kumar. And the article was included in Green Chemistry in 2020.Electric Literature of C6H12BrCl The following contents are mentioned in the article:

We report a magnetically separable Cu nanocatalyst (Fe-DOPA-Cu) for the borylation of alkyl halides with alkoxy diboron reagents, providing alkylboronic esters in high yields, with broad functional group tolerance under mild reaction conditions. The procedure is also applicable to the borylation of benzyl chlorides and bromides. Radical clock experiments support a radical-mediated process. Easy recycling of the catalyst resulted in no significant loss of activity up to ten runs. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Electric Literature of C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Electric Literature of C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Multicomponent One-pot Synthesis of Oxadiazole Included Pyranopyrazoles as Promising Antioxidant Agents was written by Reddy, Guda Mallikarjuna;Yun Chen, Di;Venkata Subbaiah, Munagapati;Jianyou, Long;Wen, Jet-Chau. And the article was included in Journal of Heterocyclic Chemistry in 2019.Related Products of 638-07-3 The following contents are mentioned in the article:

In this context, a series of oxadiazole included pyranopyrazoles were prepared under eco-friendly synthetic way by using montmorillonite k10 as a catalyst. The final compounds were obtained in good yields. Further, compounds were screened for their antioxidant activity and most of the compounds revealed promising activity. Among all, electron rich-substituted compounds at para position demonstrated higher antioxidant activity than their corresponding ortho-substituted compounds This study involved multiple reactions and reactants, such as Ethyl 4-chloro-3-oxobutanoate (cas: 638-07-3Related Products of 638-07-3).

Ethyl 4-chloro-3-oxobutanoate (cas: 638-07-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Related Products of 638-07-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis of 1-sulfonyl-2-arylpyrrolidines via intramolecular cyclization/Mannich-type reaction cascade of N-(4,4-diethoxybutyl)sulfonamides was written by Anikina, Ekaterina A.;Smolobochkin, Andrey V.;Gazizov, Almir S.;Burilov, Alexander R.;Pudovik, Michail A.. And the article was included in Phosphorus, Sulfur and Silicon and the Related Elements in 2018.Safety of 4-Chlororesorcinol The following contents are mentioned in the article:

Herein, we report the successful application of a novel approach to 2-substituted pyrrolidines based on intramol. cyclization/intermol. Mannich-type cascade reaction of N-(4,4-diethoxybutyl)sulfonamides to the synthesis of pyrrolidines possessing heterocyclic and polyaromatic moieties. The proposed approach benefits from mild reaction conditions, moderate to high yields of target compounds and provides a convenient route to the previously unknown 1-sulfonyl-2-arylpyrrolidines. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5Safety of 4-Chlororesorcinol).

4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of 4-Chlororesorcinol

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics