Tag: 100-200

Controlled Generation of 3-Triflyloxyarynes was written by Uchida, Keisuke;Yoshida, Suguru;Hosoya, Takamitsu. And the article was included in Synthesis in 2016.Application of 95-88-5 The following contents are mentioned in the article:

3-Triflyloxyarynes such as 3-triflyloxybenzyne, including those bearing a transformable group, were prepared by iodine-magnesium exchange reactions of 1,3-bis(triflyloxy)-2-iodoarenes such as I using conditions that efficiently suppressed the competing thia-Fries rearrangement. The method enabled the facile synthesis of a wide range of multisubstituted arenes such as II. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5Application of 95-88-5).

4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application of 95-88-5

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Cross-coupling reaction of alkyl halides with alkyl Grignard reagents catalyzed by Cp-iron complexes in the presence of 1,3-butadiene was written by Iwasaki, Takanori;Shimizu, Ryohei;Imanishi, Reiko;Kuniyasu, Hitoshi;Kambe, Nobuaki. And the article was included in Chemistry Letters in 2018.Formula: C6H12BrCl The following contents are mentioned in the article:

Iron-catalyzed cross-coupling reaction of alkyl halides with alkyl Grignard reagents by the combined use of cyclopentadienyl ligand and 1,3-butadiene additive was described. The reaction smoothly proceeded at room temperature using unactivated alkyl bromides and fluorides via non-radical mechanism, which was in sharp contrast with hitherto known Fe-catalyzed cross-coupling reactions of alkyl halides. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Bis-calix[4]arene-based podants using the bridge position as a constructive mode of subunit connection was written by Fischer, Conrad;Weber, Edwin. And the article was included in Journal of Inclusion Phenomena and Macrocyclic Chemistry in 2014.HPLC of Formula: 6294-17-3 The following contents are mentioned in the article:

A set of bridged calixarenes were synthesized where the bridges were formed by a flexible alkylene chain or a more rigid bistriazole modified connection element of different lengths. NMR measurements as well as MM calculations pointed to rather flexible conjugates showing suitable requirements for a potential formation of inclusion complexes with neutral and anionic guests of appropriate size. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3HPLC of Formula: 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).HPLC of Formula: 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Palladium-catalyzed coupling of α-halo vinylphosphonate and α-phosphonovinyl sulfonate with alkylzincs: straightforward and versatile synthesis of α-alkyl vinylphosphonates was written by Zhang, Li;Fang, Yewen;Jin, Xiaoping;Guo, Ting;Li, Ruifeng;Li, Yan;Li, Xie;Ye, Qilin;Luo, Xiang. And the article was included in Organic Chemistry Frontiers in 2018.Application of 6294-17-3 The following contents are mentioned in the article:

With α-(pseudo)halo vinylphosphonate as the electrophilic coupling partner, a variety of alkyl- and benzylic zinc reagents underwent vinylation reactions to produce α-alkyl vinylphosphonates. This unprecedented Pd-catalyzed Negishi coupling features mild reaction conditions, high functional group tolerance, broad substrate scope, retention of the olefin geometry, and easy gram-scale synthesis. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Application of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Photoinduced Radical Borylation of Alkyl Bromides Catalyzed by 4-Phenylpyridine was written by Zhang, Li;Wu, Zhong-Qian;Jiao, Lei. And the article was included in Angewandte Chemie, International Edition in 2020.Formula: C6H12BrCl The following contents are mentioned in the article:

Utilizing 4-phenylpyridine catalysis, we developed a visible-light-induced transition-metal-free radical borylation reaction of unactivated alkyl bromides that features a broad substrate scope and mild reaction conditions. Mechanistic studies revealed a novel nucleophilic substitution/photoinduced radical formation pathway, which could be utilized to trigger a variety of radical processes. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis of isomer of clopidogrel was written by Li, Dong-xing;Pu, Tong;Zhong, Wei-hui. And the article was included in Zhejiang Huagong in 2010.Related Products of 141109-14-0 The following contents are mentioned in the article:

The Me 2-(2-chlorophenyl)-2-(4,5-dihydrothieno [2,3-c]-pyridin-6 (7H)-yl)acetate, an isomer of clopidogrel, was achieved from 2-chlorophenylglycine Me ester and 2-(3-thiophenyl)ethyl para-toluenesulfonate via amino substitution, Mannich reaction and formation of sulfate salt in 56%. The advantages of our method are com. available starting materials, mild reaction condition and high yield. This study involved multiple reactions and reactants, such as (S)-Methyl 2-amino-2-(2-chlorophenyl)acetate (cas: 141109-14-0Related Products of 141109-14-0).

(S)-Methyl 2-amino-2-(2-chlorophenyl)acetate (cas: 141109-14-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Related Products of 141109-14-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Photoswitching Using Visible Light: A New Class of Organic Photochromic Molecules was written by Helmy, Sameh;Leibfarth, Frank A.;Oh, Saemi;Poelma, Justin E.;Hawker, Craig J.;Read de Alaniz, Javier. And the article was included in Journal of the American Chemical Society in 2014.Related Products of 6294-17-3 The following contents are mentioned in the article:

A versatile new class of organic photochromic mols. that offers an unprecedented combination of phys. properties including tunable photoswitching using visible light, excellent fatigue resistance, and large polarity changes is described. These unique features offer significant opportunities in diverse fields ranging from biosensors to targeted delivery systems while also allowing non-experts ready synthetic access to these materials. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Related Products of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Related Products of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Acid-catalyzed reaction of phenols with N-(4,4-diethoxybutyl)sulfonamides – a new method for the synthesis of 2-aryl-1-sulfonylpyrrolidines was written by Smolobochkin, Andrey V.;Gazizov, Almir S.;Anikina, Ekaterina A.;Burilov, Alexander R.;Pudovik, Michael A.. And the article was included in Chemistry of Heterocyclic Compounds in 2017.Name: 4-Chlororesorcinol The following contents are mentioned in the article:

A new method for the synthesis of 2-aryl-1-sulfonylpyrrolidines I (R = Me, Et, Ph, p-tolyl; R¹ = 5-chloro-2,4-dihydroxyphenyl, 2-hydroxynaphthalen-1-yl, 2,7-dihydroxynaphthalen-1-yl) on the basis of reactions between various phenols ArH and N-(4,4-diethoxybutyl)sulfonamides RS(O)₂NH(CH₂)₃CH(OEt)₂ in the presence of trifluoroacetic acid has been developed. This study involved multiple reactions and reactants, such as 4-Chlororesorcinol (cas: 95-88-5Name: 4-Chlororesorcinol).

4-Chlororesorcinol (cas: 95-88-5) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Name: 4-Chlororesorcinol

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Palladium and copper-supported on charcoal: A heterogeneous multi-task catalyst for sequential Sonogashira-Click and Click-Heck reactions was written by Rossy, Cybille;Majimel, Jerome;Delapierre, Mona Treguer;Fouquet, Eric;Felpin, Francois-Xavier. And the article was included in Journal of Organometallic Chemistry in 2014.Electric Literature of C6H12BrCl The following contents are mentioned in the article:

This paper describes the development of one-pot sequential Sonogashira-Click and Click-Heck reactions by using Pd-Cu/C as a heterogeneous multi-task catalyst for the synthesis of heterocyclic structures e. g., I. Details of the optimization studies and the substrate scope are discussed. These methodologies allow the preparation of functionalized triazoles in simple exptl. conditions with inexpensive reagents. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Electric Literature of C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nucleophilic Fluorination of Heteroaryl Chlorides and Aryl Triflates Enabled by Cooperative Catalysis was written by Hong, Cynthia M.;Whittaker, Aaron M.;Schultz, Danielle M.. And the article was included in Journal of Organic Chemistry in 2021.SDS of cas: 75-57-0 The following contents are mentioned in the article:

A new approach that leverages the cooperative action of 18-crown-6 ether and tetramethylammonium chloride to catalytically access the reactivity of tetramethylammonium fluoride and achieve halex fluorinations under mild conditions with operational ease was reported. The described methodol. readily converts both heteroaryl chlorides and aryl triflates to their corresponding (hetero)aryl fluorides in high yields and purities. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0SDS of cas: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics