Tag: 100-200

Enantioselective one-pot synthesis of 4H-chromene derivatives catalyzed by a chiral Ni(II) complex was written by Yu, Xuan;Lan, Wenjie;Li, Jiaqi;Bai, Hui;Qin, Zhaohai;Fu, Bin. And the article was included in RSC Advances in 2020.Synthetic Route of C6H9ClO3 The following contents are mentioned in the article:

A Ni(II)-bis(oxazoline) complex and p-TSOH are used to form enantioenriched 4H-chromenes from ortho-quinone methides (o-QMs) and dicarbonyls, providing the desired products in up to 95% ee. The method is compatible with various β-ketoester substrates, and the products obtained could be converted into biol. active 4H-chromene derivatives This study involved multiple reactions and reactants, such as Ethyl 4-chloro-3-oxobutanoate (cas: 638-07-3Synthetic Route of C6H9ClO3).

Ethyl 4-chloro-3-oxobutanoate (cas: 638-07-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Synthetic Route of C6H9ClO3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Synthesis of novel analogs 3,4-dihydro-1H-quinolin-2-one derivatives as typical Antidepressant, Sedative and anti-Parkinson agents was written by Pai, Nandini R.;Pusalkar, Deeptaunshu Atul;Khandekar, Dileep. And the article was included in Heterocyclic Letters in 2012.COA of Formula: C6H12BrCl The following contents are mentioned in the article:

This study aimed at synthesis of the potential Antidepressant and Sedative, anti-Parkinson’s activity of structurally diverse derivatives of lead compound 3,4-dihydro-1H-quinolin-2-one; synthesized via straightforward and efficient synthetic process. The structures of the compounds were characterized by spectral data (IR and 1H-NMR). This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3COA of Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).COA of Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration was written by Jiang, Jing;Hu, Ying;Cai, Xin;Wang, Liudi;Hu, Yanwei;Chen, Shaohua;Zhang, Shilei;Zhang, Yinan. And the article was included in Organic & Biomolecular Chemistry in 2018.Safety of 1-Bromo-6-chlorohexane The following contents are mentioned in the article:

An effective dehydrochlorination of bis(phenylsulfonyl)alkanes to prepare alkene building blocks was developed. The elimination together with double bond migration resulted in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chem. diversification represented an easy and straightforward access to a series of alkene building blocks. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Safety of 1-Bromo-6-chlorohexane).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Safety of 1-Bromo-6-chlorohexane

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Nickel-Catalyzed Reductive Amidation of Unactivated Alkyl Bromides was written by Serrano, Eloisa;Martin, Ruben. And the article was included in Angewandte Chemie, International Edition in 2016.Recommanded Product: 6294-17-3 The following contents are mentioned in the article:

A user-friendly, nickel-catalyzed reductive amidation of unactivated primary, secondary, and tertiary alkyl bromides with isocyanates is described. This catalytic strategy offers an efficient synthesis of a wide range of aliphatic amides under mild conditions and with an excellent chemoselectivity profile while avoiding the use of stoichiometric and sensitive organometallic reagents. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Recommanded Product: 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl₂ and LiCl was written by Bluemke, Tobias D.;Piller, Fabian M.;Knochel, Paul. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2010.COA of Formula: C6H12BrCl The following contents are mentioned in the article:

Alkyl bromides bearing various functional groups are smoothly converted to functionalized alkylzinc reagents by the direct insertion of magnesium in the presence of LiCl and ZnCl₂. These organozinc derivatives are used in situ for palladium-catalyzed cross-coupling reactions and additions to electrophiles such as aroyl chlorides, allyl bromides, and sulfonothioates. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3COA of Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.COA of Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Methylene chain ruler for evaluating the regioselectivity of a substrate-recognizing oxidation catalyst was written by Teramae, Shota;Kito, Akane;Shingaki, Tomoteru;Hamaguchi, Yu;Yano, Yuuki;Nakayama, Takamori;Kobayashi, Yuko;Kato, Nobuki;Umezawa, Naoki;Hisamatsu, Yosuke;Nagano, Tetsuo;Higuchi, Tsunehiko. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.SDS of cas: 6294-17-3 The following contents are mentioned in the article:

Regioselective C-H oxidation of aliphatic mols. with synthetic catalysts is challenging. The authors incorporated substrate-recognition sites into a Ru porphyrin-heteroaromatic N-oxide catalytic system to characterize its regioselectivity for the oxidation of alkanes. This substrate-recognition catalytic reaction exhibits high regioselectivity and high reaction efficiency. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3SDS of cas: 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.SDS of cas: 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

MnCl₂-Catalyzed C-H Alkylations with Alkyl Halides was written by Liu, Weiping;Cera, Gianpiero;Oliveira, Joao C. A.;Shen, Zhigao;Ackermann, Lutz. And the article was included in Chemistry – A European Journal in 2017.Formula: C6H12BrCl The following contents are mentioned in the article:

C-H alkylations with challenging β-hydrogen-containing alkyl halides were accomplished with sustainable MnCl₂ as the catalyst under phosphine-ligand-free conditions. The proximity-induced benzamide C-H activation occurred with ample substrate scope through rate-determining C-H metalation, also setting the stage for manganese-catalyzed oxidative C-H methylations. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Formula: C6H12BrCl).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Formula: C6H12BrCl

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents was written by Iwasaki, Takanori;Yamashita, Koji;Kuniyasu, Hitoshi;Kambe, Nobuaki. And the article was included in Organic Letters in 2017.Related Products of 6294-17-3 The following contents are mentioned in the article:

The cross-coupling reaction of unactivated alkyl fluorides with alkyl Grignard reagents (alkylmagnesium chlorides) by a CoCl₂/LiI/1,3-pentadiene catalytic system is described. The present reaction smoothly cleaved C-F bonds under mild conditions and achieved alkyl-alkyl cross-coupling even when sterically hindered tertiary alkyl Grignard reagents were employed. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Related Products of 6294-17-3).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Related Products of 6294-17-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Iridium and bis(4-nitrophenyl)phosphoric acid catalysed amination of diol by hydrogen-borrowing methodology for the synthesis of cyclic amine: Synthesis of clopidogrel was written by Swain, Sharada Prasanna;Shri, Om;Ravichandiran, V.. And the article was included in Molecular Catalysis in 2021.HPLC of Formula: 141109-14-0 The following contents are mentioned in the article:

The borrowing hydrogen method is an environmentally benign process for the synthesis of amines, as H₂O is the side product. A new green process for the amination of diol by [Ir] catalyst and bis(4-nitrophenyl)phosphoric acid for the synthesis of cyclic amine is reported. This method was successfully applied for the synthesis of antiplatelet drug clopidogrel. This study involved multiple reactions and reactants, such as (S)-Methyl 2-amino-2-(2-chlorophenyl)acetate (cas: 141109-14-0HPLC of Formula: 141109-14-0).

(S)-Methyl 2-amino-2-(2-chlorophenyl)acetate (cas: 141109-14-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.HPLC of Formula: 141109-14-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

PROTAC-mediated crosstalk between E3 ligases was written by Steinebach, Christian;Kehm, Hannes;Lindner, Stefanie;Vu, Lan Phuong;Koepff, Simon;Lopez Marmol, Alvaro;Weiler, Corinna;Wagner, Karl G.;Reichenzeller, Michaela;Kroenke, Jan;Guetschow, Michael. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.Recommanded Product: 1-Bromo-6-chlorohexane The following contents are mentioned in the article:

Small-mol. heterobifunctional degraders can effectively control protein levels and are useful research tools. We assembled proteolysis targeting chimeras (PROTACs) from a cereblon (CRBN) and a von-Hippel-Lindau (VHL) ligase ligand and demonstrated a PROTAC-induced heterodimerization of the two E3 ligases leading to unidirectional and efficient degradation of CRBN. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Recommanded Product: 1-Bromo-6-chlorohexane).

1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 1-Bromo-6-chlorohexane

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics