Category: 95-49-8

An article Nickel-Catalyzed N-Arylation of Fluoroalkylamines WOS:000601055800001 published article about (HETERO)ARYL CHLORIDES; CROSS-COUPLINGS; AMINATION; FLUORINE; PHARMACEUTICALS; BISPHOSPHINES; PRECATALYST; AMIDES; SALTS in [McGuire, Ryan T.; Stradiotto, Mark] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4R2, Canada; [Yadav, Arun A.] Paraza Pharma Inc, 2525 Ave Marie Curie, Montreal, PQ H4S 2E1, Canada in 2021.0, Cited 51.0. SDS of cas: 95-49-8. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8

The Ni-catalyzed N-arylation of beta-fluoroalkylamines with broad scope is reported for the first time. Use of the air-stable pre-catalyst (PAd2-DalPhos)Ni(o-tol)Cl allows for reactions to be conducted at room temperature (25 degrees C, NaOtBu), or by use of a commercially available dual-base system (100 degrees C, DBU/NaOTf), to circumvent decomposition of the N-(beta-fluoroalkyl)aniline product. The mild protocols disclosed herein feature broad (hetero)aryl (pseudo)halide scope (X=Cl, Br, I, and for the first time phenol-derived electrophiles), encompassing base-sensitive substrates and enantioretentive transformations, in a manner that is unmatched by any previously reported catalyst system.

About 1-Chloro-2-methylbenzene, If you have any questions, you can contact McGuire, RT; Yadav, AA; Stradiotto, M or concate me.. SDS of cas: 95-49-8

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

In 2020.0 RSC ADV published article about REVERSE-OSMOSIS MEMBRANE; IONIZATION BEHAVIOR; DENSITY FUNCTIONALS; ACTIVE LAYER; WATER; DYNAMICS; PHARMACEUTICALS; STOICHIOMETRY; ACCESSIBILITY; CONTAMINANTS in [Zhang, Muxue; Minakata, Daisuke] Michigan Technol Univ, Dept Civil & Environm Engn, 1400 Townsend Dr, Houghton, MI 49931 USA; [Breitner, Lauren; Howe, Kerry J.] Univ New Mexico, Dept Civil Construct & Environm Engn, MSC01 1070, Albuquerque, NM 87131 USA in 2020.0, Cited 50.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Application In Synthesis of 1-Chloro-2-methylbenzene

Reverse osmosis (RO) is a membrane technology that separates dissolved species from water. RO has been applied for the removal of chemical contaminants from water and is employed in wastewater reclamation to provide an additional barrier to improve the removal of trace organic contaminants. The presence of a wide variety of influent chemical contaminants and the insufficient rejection of low molecular weight neutral chemicals by RO calls for the need to develop a comprehensive model that predicts the rejection of various chemicals in RO. Yet the role of the interaction between neutral organic compounds and a RO membrane, and how the functional groups of organic compounds affect the interaction have not been fully elucidated. In this study, we first constructed a molecular model for a reference polyamide (PA) membrane. We then investigated the impact of explicit water molecules and PA membrane functionality on the membrane structure using quantum mechanical calculations. We examined solvent-membrane interactions and then solvent-membrane-solute interactions using two neutral test solutes, arsenic and boron, by comparing the theoretically calculated aqueous-phase free energies of interaction with their experimental values. Finally, the validated PA membrane model was used to calculate the free energies of interaction for a wide variety of organic compounds such as haloalkanes, haloalkenes, alkylbenzenes and halobenzenes, which correlated with the experimentally obtained mass transfer coefficients. The correlation indicates that the interaction between organic compounds and PA membranes plays a critical role in the rejection mechanism.

Application In Synthesis of 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Zhang, MX; Breitner, L; Howe, KJ; Minakata, D or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Application In Synthesis of 1-Chloro-2-methylbenzene. Chen, YY; Li, CL; Cui, YM; Sun, MM; Jia, XS; Li, J in [Cui, Yongmei; Jia, Xueshun; Li, Jian] Shanghai Univ, Dept Chem, Ctr Supramol Chem & Catalysis, Coll Sci, 99 Shangda Rd, Shanghai 200444, Peoples R China; Shanghai Univ, Inst Sustainable Energy, 99 Shangda Rd, Shanghai 200444, Peoples R China published Bu4NI-Catalyzed C-C Bond Cleavage and Oxidative Esteri?cation of Allyl Alcohols with Toluene Derivatives in 2019, Cited 73. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.

About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Chen, YY; Li, CL; Cui, YM; Sun, MM; Jia, XS; Li, J or concate me.. Application In Synthesis of 1-Chloro-2-methylbenzene

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Quality Control of 1-Chloro-2-methylbenzene. In 2020.0 SYNLETT published article about C-H BONDS; BENZOIC-ACID; MOLECULAR-OXYGEN; N-HYDROXYPHTHALIMIDE; SELECTIVE OXIDATION; METAL-FREE; PHOTOOXIDATION; DERIVATIVES; COBALT; OXIDE in [Zheng, Kun; Yan, Xiaoyu; Zhang, Guofu; Yan, Xinhuan; Li, Xiaoqing; Xu, Xiangsheng] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China in 2020.0, Cited 31.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.

A mild and metal-free procedure is reported for the aerobic oxidation of substituted toluenes to carboxylic acids by using CBr (4) as initiator under irradiation from a 400 nm blue light-emitting diode.

Quality Control of 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Zheng, K; Yan, XY; Zhang, GF; Yan, XH; Li, XQ; Xu, XS or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Authors Merli, D; Speltini, A; Dondi, D; Longhi, D; Milanese, C; Profumo, A in ELSEVIER SCIENCE BV published article about PERFORMANCE LIQUID-CHROMATOGRAPHY; STATIONARY-PHASE; QSAR; FUNCTIONALIZATION; MECHANISM; COLUMNS; ACIDS in [Merli, Daniele; Speltini, Andrea; Dondi, Daniele; Longhi, Diego; Milanese, Chiara; Profumo, Antonella] Univ Pavia, Dept Chem, Via Taramelli 12, I-27100 Pavia, Italy in 2019.0, Cited 48.0. HPLC of Formula: C7H7Cl. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8

Purified multi-walled carbon nanotubes (MWCNTs) grafted onto silica microspheres by gamma-radiation were applied as a HPLC stationary phase for investigating the intermolecular interactions between MWCNTs and substituted benzenes. The synthetic route, simple and not requiring CNTs derivatization, involved no alteration of the nanotube original morphology and physical-chemical properties. The affinity of a set of substituted benzenes for the MWCNTs was studied by correlating the capacity factor (k’) of each probe to its physico-chemical characteristics (calculated by Density Functional Theory). The correlation was found through a theoretical approach based on feedforward neural networks. This strategy was adopted because today these calculations are easily affordable for small molecules (like the analytes), and many critical parameters needed are not known. This might increase the applicability of the proposed method to other cases of study. Moreover, it was seen that the normal linear fit does not provide a good model. The interaction on the MWCNT phase was compared to that of an octadecyl (C18) reversed phase, under the same elution conditions. Results from trained neural networks indicated that the main role in the interactions between the analytes and the stationary phases is due to dipole moment, polarizability and LUMO energy. As expected for the C18 stationary phase correlation, is due to dipole moment and polarizability, while for the MWCNT stationary phase primarily to LUMO energy followed by polarizability, evidence for a specific interaction between MWCNTs and analytes. The CNT-based hybrid material proved to be not only a chromatographic phase but also a useful tool to investigate the MWCNT-molecular interactions with variously substituted benzenes. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of King Saud University.

HPLC of Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Merli, D; Speltini, A; Dondi, D; Longhi, D; Milanese, C; Profumo, A or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

An article A Collection of More than 900 Gas Mixture Adsorption Experiments in Porous Materials from Literature Meta-Analysis WOS:000611072000053 published article about METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; MULTICOMPONENT ADSORPTION; ZEOLITE 13X; TERNARY MIXTURES; ACTIVATED CARBON; CO2-CH4 MIXTURES; CO2 SEPARATION; BINARY-MIXTURE; ETHANE in [Cai, Xuqing; Gharagheizi, Farhad; Bingel, Lukas W.; Shade, Danny; Walton, Krista S.; Sholl, David S.] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA in 2021.0, Cited 83.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Name: 1-Chloro-2-methylbenzene

Information on mixture adsorption equilibrium is vital in developing adsorption-based separation processes. Because measuring mixture adsorption is more difficult than measuring single-component adsorption, far more data of the latter kind are available. Previous efforts to compile experimental mixture adsorption data for gases have given data sets with at most a few dozen examples. Here, we report the results of systematic literature meta-analysis that produced a data set of more than 900 gas mixture adsorption experiments. This collection includes data from 125 different binary mixtures including 60 different molecular species and information from 333 different adsorbents. We refer to this data set as the Binary adsorption ISOtherm ExperimeNtal 2020 (BISON-20) Database. Because the BISON-20 data set enormously expands the number and variety of experimental results for binary gas adsorption that are readily available, it will be a useful resource for future efforts in developing new materials or processes for gas separations. As initial applications of the BISON-20 data set, we show how identifying replicate measurements can be used to assess the reliability of binary adsorption data, how the accuracy of Ideal Adsorbed Solution Theory (IAST) can be systematically tested using experimental data, and how trends in selectivity for gas separations across many materials can be examined.

Name: 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Cai, XQ; Gharagheizi, F; Bingel, LW; Shade, D; Walton, KS; Sholl, DS or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Recently I am researching about PRIVILEGED SCAFFOLD; MEDIATED SYNTHESIS; DERIVATIVES; HYDROPEROXIDE; TBHP; METHYLARENES; ACTIVATION; ENAMINES; TOLUENE; AGENTS, Saw an article supported by the IIT (BHU). Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Chauhan, S; Verma, P; Kandasamy, J; Srivastava, V. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene. Name: 1-Chloro-2-methylbenzene

An efficient synthesis of 3-functionalized coumarins is demonstrated fromo-cresols and active methylene compounds under solvent-, metal- and catalyst-free conditions in the presence of 70 % aqueoustert-butyl hydrogen peroxide. The important features of this protocol are operational simplicity, mild reaction conditions and good to excellent yield of the products.

About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Chauhan, S; Verma, P; Kandasamy, J; Srivastava, V or concate me.. Name: 1-Chloro-2-methylbenzene

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

In 2020.0 NEW J CHEM published article about NANOPARTICLE CATALYSTS; POLYMERS; PALLADIUM; PERFORMANCE in [Liu, Ying; Zhang, Li; Gao, Shengguang; Shi, Buyin; Yu, Haitao; Huang, Kun] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 500 N Dongchuan Rd, Shanghai 200241, Peoples R China in 2020.0, Cited 44.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. SDS of cas: 95-49-8

In this work, we present a facile method for anchoring a transition metal catalyst (Pd(PPh3)(4)) into hollow porous organic nanospheres (H-PONs) based on a co-hyper-crosslinking mediated self-assembly strategy by using polylactide-b-polystyrene (PLA-b-PS) and Pd(PPh3)(4) as precursors. The intrinsic catalytic activity of Pd(PPh3)(4) could be well retained even if immobilized into H-PONs through a one-step Scholl reaction. Owing to the hierarchically porous structure, high surface area and well-dispersed active sites, the resulting H-PONs-Pd(PPh3)(4) exhibited excellent catalytic activity, enhanced stability, and good recyclability for the Suzuki-Miyaura coupling in aqueous media. We hope that such a facile synthesis approach can provide a broad platform to support various transition metal catalysts anchored into hollow porous nanomaterials for the heterogeneous catalysis field.

SDS of cas: 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Liu, Y; Zhang, L; Gao, SG; Shi, BY; Yu, HT; Huang, K or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

In 2019 ORG BIOMOL CHEM published article about AEROBIC OXIDATION; MOLECULAR-OXYGEN; AROMATIC-COMPOUNDS; METAL; ACID; HALOGENATION; EFFICIENT; ALKANES; COPPER; CHLORIDE in [Li, Zi-Hao; Li, Jian-Wei] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China; [Fiser, Bela] Ferenc Rakoczi II Transcarpathian Hungarian Inst, UA-90200 Beregszasz, Transcarpathia, Ukraine; [Fiser, Bela] Univ Miskolc, Inst Chem, Computat Mol Design Res Grp, H-3515 Miskolc, Hungary; [Jiang, Biao-Lin; Xu, Bao-Hua; Zhang, Suo-Jiang] Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, Key Lab Green Proc & Engn, State Key Lab Multiphase Complex Syst,Inst Proc E, Beijing 100190, Peoples R China; [Xu, Bao-Hua; Zhang, Suo-Jiang] Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China; [Li, Zi-Hao] Inst Proc Engn, Beijing, Peoples R China in 2019, Cited 58. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Recommanded Product: 95-49-8

The direct chlorination of C-H bonds has received considerable attention in recent years. In this work, a metal-free protocol for hydrocarbon C-H bond chlorination with commercially available N-chlorosuccinimide (NCS) catalyzed by N-hydroxyphthalimide (NHPI) with 2,3-dicyano-5,6-dichlorobenzoquinone (DDQ) functioning as an external radical initiator is presented. Aliphatic and benzylic substituents and also heteroaromatic ones were found to be well tolerated. Both the experiments and theoretical analysis indicate that the reaction goes through a process wherein NHPI functions as a catalyst rather than as an initiator. On the other hand, the hydrogen abstraction of the C-H bond conducted by a PINO species rather than the highly reactive N-centered radicals rationalizes the high chemoselectivity of the monochlorination obtained by this protocol as the latter is reactive towards the C(sp(3))-H bonds of the monochlorides. The present results could hold promise for further development of a nitroxy-radical system for the highly selective functionalization of the aliphatic and benzylic hydrocarbon C-H.

Recommanded Product: 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Li, ZH; Fiser, B; Jiang, BL; Li, JW; Xu, BH; Zhang, SJ or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article Synthesis and Catalytic Applications of Palladium(II) Complexes Supported by Hydroxyl-Functionalized Triazolylidenes published in 2019. Safety of 1-Chloro-2-methylbenzene, Reprint Addresses Mendoza-Espinosa, D (corresponding author), Univ Autonoma Estado Hidalgo, Area Acad Quim, Carretera Pachuca Tulancingo Km 4-5, Mineral De La Reforma 42090, Hidalgo, Mexico.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene

A series of allyl (1-3) and cinnamyl (4-6) palladium(II) complexes supported by hydroxyl functionalized triazolylidenes have been prepared. All new compounds were fully characterized by means of H-1 and C-13 NMR spectroscopy, FT-IR and elemental analyses. The new triazolylidene palladium complexes were tested as precatalysts in the coupling of aryl chlorides with boronic acids and the coupling of esters with amines to produce biphenyls and amides, respectively. According to the overall results, complexes 4 and 5 displayed the highest catalytic activity in both coupling processes, providing good to excellent yields under mild reaction conditions and using a wide range of substrates.

Safety of 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact De la Fuente-Olvera, AA; Suarez-Castillo, OR; Mendoza-Espinosa, D or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics