Category: 95-49-8

Name: 1-Chloro-2-methylbenzene. In 2020.0 RENEW ENERG published article about COAL-GASIFICATION; PYROLYSIS; BIOMASS; TAR; CATALYST; DISSOCIATION; COMPONENTS; CONVERSION; MECHANISM; CARBON in [Yang, Fu; Hu, Hongyun; Gao, Qiang; Yang, Yuhan; Tang, Hua; Xie, Kang; Liu, Huan; Yao, Hong] Huazhong Univ Sci & Technol, Sch Energy & Power Engn, State Key Lab Coal Combust, Wuhan 430074, Peoples R China; [Liu, Huan] Huazhong Univ Sci & Technol, Sch Energy & Power Engn, Dept New Energy Sci & Engn, Wuhan 430074, Peoples R China; [He, Yao] Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Environm Hlth & Pollut Control, Guangzhou Key Lab Environm Catalysis & Pollut Con, Guangzhou 510006, Peoples R China in 2020.0, Cited 32.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.

The upgrading of tar is a key issue for the sufficient application of biowaste pyrolysis technology. Molten salt, with high migration and diffusion of ions to prevent the deactivation of coke deposition of tar reforming functional metals, is considered as a feasible catalytic reaction medium and heat carrier for the upgrading of tar. The present study investigated the interactions between small molecular pyrolysis gases (including H-2, CO, CH4) and main tar model compound in ternary carbonate eutectics (Li2CO3-Na2CO3-K2CO3). The results demonstrated that H-2 could be decomposed to produce H radicals, promoting the conversion of toluene into gaseous products. CO32- could consume H radicals required by toluene cracking, making the process toluene polymerized to polycyclic aromatic hydrocarbons be strengthened. On the other hand, CO would react with OH radicals to produce H radicals and could enhance gas-generating process. In addition, toluene could react with CO to form benzaldehyde and phenylacetaldehyde. With the addition of CH4, more H radicals were supposed to be consumed, and toluene cracking process was further inhibited. Finally, the effect sequence of small molecular gases (H-2 > CH4 > CO) on toluene reforming reaction was authenticated by investigating the impacts of introducing any two gases in toluene reforming. (C) 2020 Elsevier Ltd. All rights reserved.

Name: 1-Chloro-2-methylbenzene. Bye, fridends, I hope you can learn more about C7H7Cl, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Name: 1-Chloro-2-methylbenzene. Authors Gupta, SSR; Vinu, A; Kantam, ML in WILEY-V C H VERLAG GMBH published article about in [Gupta, Shyam Sunder R.; Kantam, Mannepalli Lakshmi] Inst Chem Technol, Dept Chem Engn, Mumbai 400019, Maharashtra, India; [Vinu, Ajayan] Univ Newcastle, Fac Engn & Built Environm, Sch Engn, Global Innovat Ctr Adv Nanomat GICAN, Callaghan, NSW 2308, Australia in 2021.0, Cited 62.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8

One-pot synthesis of furan-2,5-dimethylcarboxylate (FDMC) from 5-hydroxymethylfurfural (HMF) is highly demanding for the commercial production of polyethylene furanoate (PEF). Herein, a direct synthesis of FDMC is reported from oxidative esterification of HMF using ultrafine CuO particles dispersed on nitrogen-doped hollow carbon nanospheres (CuO/N-C-HNSs) as a catalyst and tert-butyl hydroperoxide (TBHP) as an oxidizing and methylating reagent. The CuO/N-C-HNSs was prepared through a template protection-sacrifice strategy using SiO2 as a sacrificial template and histidine as the precursor for N and C. N-doping facilitated a strong interaction between the support and copper species, affording formation of CuO nanoparticles of less than 10 nm in size. By virtue of the highly dispersed CuO nanoparticles and a high BET surface area 373 m(2)/g, the CuO/N-C-HNSsshows excellent catalytic performance in the selective conversion of HMF into FDMC affording 93 % yield of the desired product with a TON value of 49. Furthermore, the oxidative esterification involving (SPC)-C-3-H bond functionalization is also demonstrated using the same catalyst.

Bye, fridends, I hope you can learn more about C7H7Cl, If you have any questions, you can browse other blog as well. See you lster.. Name: 1-Chloro-2-methylbenzene

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Quality Control of 1-Chloro-2-methylbenzene. I found the field of Chemistry very interesting. Saw the article Ni(acac)(2)/2,6-bis(diphenylphosphino)pyridine/CuI: A highly efficient palladium-free homogeneous catalyst for the Sonogashira cross-coupling reaction published in 2020.0, Reprint Addresses Joshaghani, M (corresponding author), Razi Univ, Dept Inorgan Chem, Fac Chem, Kermanshah 67149, Iran.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene.

A highly efficient palladium-free homogeneous catalyst involving Ni(acac)(2)/2,6-bis(diphenylphosphino) pyridine ((Ph2P)(2)py)/CuI components was used for the Sonogashira cross-coupling reaction. The Sonogashira reaction was investigated between phenylacetylene and various bromoand chloroarenes containing electron neutral, electron-rich, electron-poor, electron-deficient, and sterically hindered aryl fragments. The aryl alkynes coupling products were obtained with good to excellent yields at the optimized conditions using Ni(acac)(2) (0.3 mol%)/(Ph2P)(2)py (0.6 mol%)/CuI (0.03 mol%) as the catalyst, tetrabutylammonium bromide (TBAB) as the additive, Et3N as the base in DMF at 100 degrees C under N-2 atmosphere.

About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Daryanavard, M; Ataei, A; Rafiee, E; Joshaghani, M or concate me.. Quality Control of 1-Chloro-2-methylbenzene

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Product Details of 95-49-8. In 2020.0 ANGEW CHEM INT EDIT published article about O BOND FORMATION; COUPLING REACTIONS; ENANTIOSELECTIVE SYNTHESIS; CROSS-COUPLINGS; ACTIVATED ARYL; HALIDES; ETHERS; MILD; HYDROXYLATION; PHOTOREDOX in [Yang, Liu; Lu, Huan-Huan; Lai, Chu-Hui; Li, Gang; Zhang, Wei; Cao, Rui; Liu, Fengyi; Wang, Chao; Xiao, Jianliang; Xue, Dong] Shaanxi Normal Univ, Key Lab Appl Surface & Colloid Chem, Minist Educ, Xian 710062, Peoples R China; [Yang, Liu; Lu, Huan-Huan; Lai, Chu-Hui; Li, Gang; Zhang, Wei; Cao, Rui; Liu, Fengyi; Wang, Chao; Xiao, Jianliang; Xue, Dong] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Peoples R China; [Xiao, Jianliang] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England in 2020.0, Cited 71.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.

A highly effective C-O coupling reaction of (hetero)aryl electrophiles with primary and secondary alcohols is reported. Catalyzed by a Ni-II-aryl complex under long-wave UV (390-395 nm) irradiation in the presence of a soluble amine base without any additional photosensitizer, the reaction enables the etherification of aryl bromides and aryl chlorides as well as sulfonates with a wide range of primary and secondary aliphatic alcohols, affording synthetically important ethers. Intramolecular C-O coupling is also possible. The reaction appears to proceed via a Ni-I-Ni-III catalytic cycle.

Product Details of 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Yang, L; Lu, HH; Lai, CH; Li, G; Zhang, W; Cao, R; Liu, FY; Wang, C; Xiao, JL; Xue, D or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Guo, P; Wang, K; Jin, WJ; Xie, H; Qi, LL; Liu, XY; Shu, XZ in [Guo, Peng; Wang, Ke; Jin, Wen-Jie; Xie, Hao; Qi, Liangliang; Liu, Xue-Yuan; Shu, Xing-Zhong] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China published Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis in 2021, Cited 104. Formula: C7H7Cl. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.

Catalytic transformation of alcohols via metal-catalyzed cross-coupling reactions is very important, but it typically relies on a multistep procedure. We here report a dynamic kinetic cross-coupling approach for the direct functionalization of alcohols. The feasibility of this strategy is demonstrated by a nickel-catalyzed cross-electrophile arylation reaction of benzyl alcohols with (hetero)aryl electrophiles. The reaction proceeds with a broad substrate scope of both coupling partners. The electron-rich, electron-poor, and ortho-/meta-/para-substituted (hetero)aryl electrophiles (e.g., Ar-OTf, Ar-I, Ar-Br, and inert Ar-Cl) all coupled well. Most of the functionalities, including aldehyde, ketone, amide, ester, nitrile, sulfone, furan, thiophene, benzothiophene, pyridine, quinolone, Ar-SiMe3, Ar-Bpin, and Ar-SnBu3, were tolerated. The dynamic nature of this method enables the direct arylation of benzylic alcohol in the presence of various nucleophilic groups, including nonactivated primary/secondary/tertiary alcohols, phenols, and free indoles. It thus offers a robust alternative to existing methods for the precise construction of diarylmethanes. The synthetic utility of the method was demonstrated by a concise synthesis of biologically active molecules and by its application to peptide modification and conjugation. Preliminary mechanistic studies revealed that the reaction of in situ formed benzyl oxalates with nickel, possibly via a radical process, is an initial step in the reaction with aryl electrophiles.

Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Guo, P; Wang, K; Jin, WJ; Xie, H; Qi, LL; Liu, XY; Shu, XZ or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Recommanded Product: 95-49-8. I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Cp*Co(iii) and Cu(OAc)(2) bimetallic catalysis for Buchwald-type C-N cross coupling of aryl chlorides and amines under base, inert gas & solvent-free conditions published in 2020.0, Reprint Addresses Joshi, RK (corresponding author), Malaviya Natl Inst Technol, Dept Chem, Jaipur 302017, Rajasthan, India.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene.

A strategy involving bimetallic catalysis with a combination of Cp*Co(CO)I-2 and Cu(OAc)(2) was used for performing Buchwald-type C-N coupling reactions of aryl chlorides with amines. The reactions proceeded at 100 degrees C to produce excellent yields of many of the desired C-N coupled products, in 4 h, under aerobic reaction conditions. The reactions were shown to run under base-free and solvent-free conditions, enabling this strategy to work efficiently for electron-withdrawing and base-sensitive functionalities. The presented methodology was found to be equally efficient for electron-donating functionalities as well as for primary (1 degrees) and secondary (2 degrees) aromatic and aliphatic amines. Moreover, the products were easily separated through the extractions of the organic aqueous layer, with this process chromatographic separations is not required.

Recommanded Product: 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Srivastava, AK; Sharma, C; Joshi, RK or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

An article Redox-neutral photochemical Heck-type arylation of vinylphenols activated by visible light WOS:000518011700008 published article about C-H ARYLATION; DIARYLIODONIUM SALTS; ROOM-TEMPERATURE; METAL-FREE; UNACTIVATED ALKYL; ELECTRON-TRANSFER; CHLOROGENIC ACID; TRANSFORMATIONS; HETEROARENES; DISSOCIATION in [Liang, Kangjiang; Li, Tao; Li, Na; Zhang, Yang; Shen, Lei; Ma, Zhixian; Xia, Chengfeng] Yunnan Univ, Lib Yunnan Univ,Sch Chem Sci & Technol, Key Lab Med Chem Nat Resource,Minist Educ & Yunna, State Key Lab Conservat & Utilizat Bioresources Y, 2 North Cuihu Rd, Kunming 650091, Yunnan, Peoples R China in 2020.0, Cited 57.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Product Details of 95-49-8

Disclosed herein is a photochemical Heck-type arylation of vinylphenols with non-activated aryl and heteroaryl halides under visible light irradiation. Preliminary mechanistic studies suggested that the colored vinylphenolate anions acted as a strong reducing photoactivator to directly activate (hetero)aryl halides without the need for any sacrificial reductants. The photochemically generated aryl radicals coupled with another molecule of vinylphenol to afford the Heck-type arylation product in a regiospecific and stereoselective manner. The developed photochemical arylation protocol showed exceptional functional group tolerance and was successfully applied in the challenging late-stage modification of natural products without any protection-deprotection procedures.

Product Details of 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Liang, KJ; Li, T; Li, N; Zhang, Y; Shen, L; Ma, ZX; Xia, CF or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Liu, F; Xiao, CX; Meng, LH; Chen, L; Zhang, Q; Liu, JB; Shen, S; Guo, JK; Au, CT; Yin, SF in [Liu, Fan; Xiao, Chen-Xi; Meng, Ling-Hu; Chen, Lang; Zhang, Qi; Liu, Jia-Bin; Shen, Sheng; Guo, Jun-Kang; Yin, Shuang-Feng] Hunan Univ, Changsha, Peoples R China; [Au, Chak-Tong] Fuzhou Univ, Fuzhou, Peoples R China published Facile Fabrication of Octahedral CdS-ZnS by Cation Exchange for Photocatalytic Toluene Selective Oxidation in 2020.0, Cited 47.0. Product Details of 95-49-8. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.

Octahedral CdS-ZnS composites were synthesized using a simple method of cation exchange and hydrothermal treatment, using Cd-3(C3N3S3)(2) (denoted as Cd-3(TMT)(2)) as a precursor and Zn2+ for ion exchange. In the spontaneous ion exchange process, there is the formation of compact heterojunctions and three-dimensional octahedral structures. By controlling the ion exchange level, the composition of (CdxZn1-x)(3) (TMT)(2) hybrid nanomaterials can be regulated, and the composite can be used as a template to generate octahedral CdS-ZnS. Photocatalytic oxidation of toluene to benzaldehyde was used as a model reaction to evaluate the performance of the as-prepared samples, and the CZ-2 catalyst shows the highest photocatalytic activity, giving a benzaldehyde formation rate of 1078 mu mol.g(-1).h(-1) without the need of any solvent. The excellent performance is ascribed to the octahedral structure which is large in specific surface area and compact in heterojunctions. It is envisaged that the method is suitable for the generation of heterojunctions for photocatalytic purposes.

Product Details of 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Liu, F; Xiao, CX; Meng, LH; Chen, L; Zhang, Q; Liu, JB; Shen, S; Guo, JK; Au, CT; Yin, SF or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

I found the field of Chemistry very interesting. Saw the article A Practical Synthesis of 3-Functionalized Coumarins fromo-Cresols and Active Methylene Compounds under Metal and Catalyst-Free Conditions Usingtert-Butyl Hydrogen Peroxide published in 2020.0. Category: chlorides-buliding-blocks, Reprint Addresses Srivastava, V (corresponding author), Indian Inst Technol BHU, Dept Chem, Varanasi 221005, Uttar Pradesh, India.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene

An efficient synthesis of 3-functionalized coumarins is demonstrated fromo-cresols and active methylene compounds under solvent-, metal- and catalyst-free conditions in the presence of 70 % aqueoustert-butyl hydrogen peroxide. The important features of this protocol are operational simplicity, mild reaction conditions and good to excellent yield of the products.

Category: chlorides-buliding-blocks. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Chauhan, S; Verma, P; Kandasamy, J; Srivastava, V or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Recently I am researching about NANOPARTICLE CATALYSTS; POLYMERS; PALLADIUM; PERFORMANCE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21574042, 51273066]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [40500-20104-222047]. Quality Control of 1-Chloro-2-methylbenzene. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Liu, Y; Zhang, L; Gao, SG; Shi, BY; Yu, HT; Huang, K. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene

In this work, we present a facile method for anchoring a transition metal catalyst (Pd(PPh3)(4)) into hollow porous organic nanospheres (H-PONs) based on a co-hyper-crosslinking mediated self-assembly strategy by using polylactide-b-polystyrene (PLA-b-PS) and Pd(PPh3)(4) as precursors. The intrinsic catalytic activity of Pd(PPh3)(4) could be well retained even if immobilized into H-PONs through a one-step Scholl reaction. Owing to the hierarchically porous structure, high surface area and well-dispersed active sites, the resulting H-PONs-Pd(PPh3)(4) exhibited excellent catalytic activity, enhanced stability, and good recyclability for the Suzuki-Miyaura coupling in aqueous media. We hope that such a facile synthesis approach can provide a broad platform to support various transition metal catalysts anchored into hollow porous nanomaterials for the heterogeneous catalysis field.

Quality Control of 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Liu, Y; Zhang, L; Gao, SG; Shi, BY; Yu, HT; Huang, K or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics