Category: 75-57-0

Nucleophilic interfacial layer enables stable Zn anodes for aqueous Zn batteries was written by Xu, Yan;Zheng, Xinhua;Sun, Jifei;Wang, Weiping;Wang, Mingming;Yuan, Yuan;Chuai, Mingyan;Chen, Na;Hu, Hanlin;Chen, Wei. And the article was included in Nano Letters in 2022.Application of 75-57-0 The following contents are mentioned in the article:

Aqueous Zn batteries are emerging as promising energy storage devices. However, severe dendrite growth and side reactions of Zn anodes restrict their further development. Herein, we develop a nucleophilic interfacial layer (NIL) on Zn to achieve a highly stable Zn anode for rechargeable Zn batteries. The NIL in a composition of zinc acetate acetamide is homogeneous, compact, and Zn²⁺-conductive, rendering dendrite-free Zn deposition, which is observed by in situ optical microscopy. Benefiting from the advantages of NIL, the Zn||Zn sym. cells show a low overpotential of 0.12 V at a high c.d. of 40 mA/cm², enhanced Coulombic efficiency up to 99.9%, and extended lifespan over 2600 cycles. The Zn||Ti asym. cells exhibit a high areal capacity of 5 mAh/cm². Moreover, the NIL functionalized Zn anode enables stable cycling of both anode-free Zn||Cl₂ cells and zinc-ion capacitors, providing opportunities for the development of high-performance energy storage devices. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Application of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Application of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Dual Passivation of SnO₂ by Tetramethylammonium Chloride for High-Performance CsPbI₂Br-Based Inorganic Perovskite Solar Cells was written by Parida, Bhaskar;Jin, In Su;Jung, Jae Woong. And the article was included in Chemistry of Materials in 2021.SDS of cas: 75-57-0 The following contents are mentioned in the article:

Here, the modification of the SnO₂ electron transport layer (ETL) by tetramethylammonium chloride (TMACl) is described. The theor. and exptl. studies in this work demonstrate that TMA and Cl ions complementarily passivate the oxygen vacancies on the surface of SnO₂ ETL, while TMACl passivation also contributes to increase the conduction band edge of SnO₂ by reducing the work function. As a result, the charge carrier recombination and electron transfer/extraction behaviors at the interface of CsPbI₂Br and SnO₂ ETL are significantly improved, leading to inorganic perovskite solar cells with efficiencies of up to 13.84% and 28.68% under 1-sun illumination and indoor lighting, resp. TMACl-passivated SnO₂ also boosts the operative stability of the device under humidity and thermal stress, which reveals the potential of TMACl as a promising passivation agent of SnO₂ for high-performance perovskite optoelectronics. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0SDS of cas: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.SDS of cas: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Structure-property-performance relationships of lactic acid-based deep eutectic solvents with different hydrogen bond acceptors for corn stover pretreatment was written by Liang, Xinquan;Zhu, Yuan;Qi, Benkun;Li, Shiqian;Luo, Jianquan;Wan, Yinhua. And the article was included in Bioresource Technology in 2021.HPLC of Formula: 75-57-0 The following contents are mentioned in the article:

Herein, ten types of lactic acid-based deep eutectic solvents (DESs) with differently structured hydrogen bond acceptors (HBAs) were used for corn stover pretreatment. Among the tested DESs, those composed of HBAs with short alkyl chain were more effective to remove lignin and xylan, resulting in higher enzymic digestion of the pretreated solids than their counterparts with long alky chain. Also, functional groups of HBAs demonstrated significant effects on biomass deconstruction. In order to interpret the different pretreatment performance of the tested DESs, Kamlet-Taft solvent polarity parameters of the tested DESs were correlated to their lignocellulose pretreatment performance. It was found that hydrogen bond acidity (Kamlet-Taft α parameter) had strong pos. relationships with pretreatment efficacy of the studied DESs. These findings not only clarified the structure-property-performance relationships of the DESs, but also provided novel insights into design and selection of DESs for lignocellulose pretreatment. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0HPLC of Formula: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.HPLC of Formula: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Effects of N-, P-, or O-containing ligands on gold-based complex catalysts for acetylene hydrochlorination was written by Li, Yanqin;Zhang, Chuanming;Zhang, Haiyang;Li, Linfeng;Zhang, Jinli;Oh, Rena;Yao, Lisha;Cai, Ming;Li, Jian;Zhang, Miaomiao;Li, Feng. And the article was included in Applied Catalysis, A: General in 2021.Synthetic Route of C4H12ClN The following contents are mentioned in the article:

In line with the fulfillment of international Minamata Convention and the urgent need for developing non-mercury catalysts, Au-Lx/AC catalysts were synthesized and evaluated for the hydrochlorination of acetylene. The results showed that the interaction between ligands and Au species contributed to the enhanced catalytic activity with important and different roles of each ligand. Depending on the high electronegativity of heteroatoms, all the prepared catalysts had effectively improved their adsorption and activation capacity of hydrogen chloride. Specifically, the N-containing ligands in catalysts increased the dispersion of Au species and an enhanced adsorption of acetylene was observed While, the coordination of P-containing ligands with Au can increase the relative content of active Aun+ species and the O-containing ligands rather decreased the adsorption of acetylene. Furthermore, all the prepared Au-Lx/AC catalysts showed good stabilities based on the inhibition of the agglomeration of Au components or of coking deposition. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Synthetic Route of C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Synthetic Route of C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

A high capacity aqueous zinc-based chlorine ion battery improved by zinc selenide-modified anode was written by Fang, Ziren;Li, Mingqiang;Zhao, Hu;Wang, Lixiang;Duan, Xinping. And the article was included in Inorganic Chemistry Communications in 2021.Product Details of 75-57-0 The following contents are mentioned in the article:

Chloride ion battery (CIB) is a novel anionic battery first reported in 2013. The high open circuit voltage and high theor. capacity have attracted wide attention. However, its low cycle life imposes restrictions on its application. Since the electrochem. performance of zinc anode in chloride ion batteries is different from zinc ion batteries, we attempted to modify the zinc anode with kinds of strategies or addictives to match the zinc electrode with the zinc-free electrolyte and finally found the pos. influence of ZnSe. The zinc selenide-modified anode improved the capacity to 177.4mAh g^-1 and expanded the cycle life to 2500 times. Besides, our work may also have reference significance for other zinc based batteries. The mechanism of anode was analyzed using X-ray diffraction (XRD), XPS as well as high-definition SEM (HD SEM) and simulated by adsorption models. The electrochem. performance of the anode was tested by cyclic voltammetry (CV) and the full cell was test on BTS4000 battery program-control test system. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Product Details of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Product Details of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Molecular Mechanism of Acceleration and Retardation of Collective Orientation Relaxation of Water Molecules in Aqueous Solutions was written by Moritsugu, Norifumi;Nara, Takafumi;Koda, Shin-ichi;Tominaga, Keisuke;Saito, Shinji. And the article was included in Journal of Physical Chemistry B in 2020.Product Details of 75-57-0 The following contents are mentioned in the article:

The collective orientation relaxation (COR) of water mols. in aqueous solutions is faster or slower with an increase in the concentration of the solutions than that in pure water; for example, acceleration (deceleration) of the COR is observed in a solution of sodium chloride (tetramethylammonium chloride) with increasing concentration However, the mol. mechanism of the solution and concentration dependence of the relaxation time of the COR has not yet been clarified. We theor. investigate the concentration dependence of the COR of water mols. in solutions of tetramethylammonium chloride (TMACl), guanidinium chloride (GdmCl), and sodium chloride (NaCl). Based on the Mori-Zwanzig equation, we identify two opposing factors that determine the COR of water mols. in any aqueous solution: the correlation of dipole moments and the single-mol. orientation relaxation. We reveal the mol. mechanism of the concentration dependence of the relaxation time of the COR in the TMACl, GdmCl, and NaCl solutions in terms of these two factors. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Product Details of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Product Details of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Supramolecular hydrogelation via host-guest anion recognition: Lamellar hydrogel materials for the release of cationic cargo was written by Kokan, Zoran;Duskova-Smrckova, Miroslava;Sindelar, Vladimir. And the article was included in Chem in 2021.COA of Formula: C4H12ClN The following contents are mentioned in the article:

Hydrogelation triggered by host-guest anion recognition is difficult to achieve due to the challenging anion recognition in water and de novo gelator design. Herein, we report such a hydrogel system, based on bambus[6]uril anion receptor, BU. Albeit not a gelator per se, BU formed hydrogels selectively in the presence of iodides or perchlorates. Anion recognition by BU governed the hydrogelation, indicated by the NMR, ATR-IR, and single-crystal X-ray. Gelation mechanism and lamellar nature of the network structure were elucidated by SAXS, cryoSEM, and holotomog. methods. Rheol. characterization revealed the hydrogels were stable and relatively strong. In physiol. saline solutions, the hydrogels released cationic cargo by cation metathesis, leading to a gel-to-gel transformation. Choline derivatives, as model drugs, exhibited slow release from the hydrogels. Our simple hydrogel system may inspire the design of smart materials based on host-guest anion recognition, where the release or sequestration of specific charged species are desirable. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0COA of Formula: C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.COA of Formula: C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Small Variations, Big Impact: Structural Diversity of the Complexes of a Phosphane-Decorated Benzenedithiol with Group-11 Metals was written by Schlindwein, Simon H.;Nieger, Martin;Gudat, Dietrich. And the article was included in European Journal of Inorganic Chemistry in 2021.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Reaction of a phosphine-decorated benzenedithiol (pbdtH₂) with coinage metal salts furnished polynuclear complexes [M₂(pbdtH)₂] (M = Au^I) or [cat][M₅(pbdt)₃] (cat = unipos. cation, M = Ag^I, Cu^I), which were characterized by anal. and spectroscopic techniques and single-crystal x-ray diffraction studies. Also, a double salt with an anion [Ag₅(pbdt)₃(PPh₃)]^– that proved unstable in solution was characterized crystallog. The spectroscopic and crystallog. data revealed that the Cu(I) and Ag(I) complexes exhibit, despite their like stoichiometric composition, isomeric mol. structures. The observed disparities were reproduced by DFT studies. The dinuclear Au(I) complex was found to undergo air-oxidation to furnish a mixed-valent complex [(Au^III)₂(Au^I)₂(pbdt)₄]. The copper(I) – but not the isomeric silver(I) complexes – showed luminescence in the solid state. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Category: chlorides-buliding-blocks).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Simulating intergrowth formation in zeolite crystals: impact on habit and functionality was written by Trueman, Mollie;Akporiaye, Duncan;Anderson, Michael W.. And the article was included in Faraday Discussions in 2021.SDS of cas: 75-57-0 The following contents are mentioned in the article:

A kinetic Monte-Carlo methodol. is presented for simulating crystal growth in materials which contain stacking faults. By simulating a large number of potential growth and dissolution events, a representation of the crystal is generated at various stages throughout the crystallization, allowing the effects of disorder on the evolution of crystal habit and nanoscale surface topog. to be explored. As examples, simulations were performed on two intergrown zeolite materials – zeolite T and zeolite beta. In both zeolite T and zeolite beta, simulations demonstrate how an intergrown structure leads to a characteristic roughening of certain crystal facets. In zeolite beta, this is accompanied by the development of internal defects which shows a non-homogeneous distribution. Results of simulations are validated by direct comparison to exptl. SEM, at. force microscopy and X-ray diffraction data. All simulations are performed using the CrystalGrower software package with modifications to account for disorder and should be generally applicable to all classes of crystals. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0SDS of cas: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.SDS of cas: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Assessment of COSMO-SAC Predictions for Solid-Liquid Equilibrium in Binary Eutectic Systems was written by Peng, Daili;Alhadid, Ahmad;Minceva, Mirjana. And the article was included in Industrial & Engineering Chemistry Research in 2022.Safety of Tetramethylammonium chloride The following contents are mentioned in the article:

As green and sustainable solvents, deep eutectic solvents (DESs) have received wide attention in various fields. Predictions of solid-liquid equilibrium (SLE) make it easier to choose DES constituents from a large pool of potential compounds The conductor-like screening model for segment activity coefficient (COSMO-SAC) predictions for the SLE of 94 nonsalt and 122 salt-based binary eutectic systems was evaluated in this study. It was found that the COSMO-SAC model can provide satisfactory predictions for the eutectic point of most nonsalt eutectic systems. Similar results were obtained when using the ideal solution model. The salt was represented in salt-based eutectic systems using one of two methods: as an ion pair or as fully dissociated ions. COSMO-SAC predictions for salt-based eutectic systems were unsatisfactory regardless of the salt representation method used. This inaccuracy in predicting SLE in the salt-based eutectic systems is not only due to model limitations but also due to the lack of reliable melting properties for thermally unstable salts. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Safety of Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics