Category: 75-57-0

Synthesis and curing properties of castor oil-based triglycidyl ether epoxy resin was written by Fu, Qinghe;Tan, Jihuai;Han, Changhao;Zhang, Xiaoxiang;Fu, Bo;Wang, Fang;Zhu, Xinbao. And the article was included in Polymers for Advanced Technologies in 2020.Electric Literature of C4H12ClN The following contents are mentioned in the article:

Three epoxy resins castor oil glycidyl ether (COGE), epoxidized castor oil glycidyl ether (ECOGE) and hydrogenated castor oil glycidyl ether (HCOGE) have been synthesized based on castor oil through a mild epoxidation reaction. The research on curing performance shows that the modified products could improve the toughness of traditional epoxy resins remarkably. Moreover, when adding a small amount of products into traditional epoxy resin E-51, the mech. properties of the cured products were also significantly improved. Specifically, by blending ECOGE into E-51 at a ratio of 5%, the tensile strength, elongation at break, and impact resistance of the cured product were improved by 27.5%, 33.9%, and 39.7%, resp., from 64.03 MPa, 3.15% and 11.37 MPa to 81.61 MPa, 4.4%, and 15.22 MPa. DMA illustrated that after incorporating, the crosslinking d. of the cured product increase, but the glass transition temperatures were reduced by more than 20°C compared with E-51. SEM showed that COGE and ECOGE caused the cured products to exhibit tough fracture. TGA explained that the initial decomposition temperatures of the mixed systems reduced, but the high temperature resistance of the cured products improved. The design strategy based on castor oil highlights a sustainable avenue for preparing cost-effective and high-efficiency epoxy resins. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Electric Literature of C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Defined Ion-Transfer Voltammetry of a Single Microdroplet at a Polarized Liquid/Liquid Interface was written by Ma, Yamin;Liu, Cheng;Wang, Lishi. And the article was included in Analytical Chemistry (Washington, DC, United States) in 2022.Quality Control of Tetramethylammonium chloride The following contents are mentioned in the article:

A strategy for the fast anal. of ion transfer/facilitated ion transfer toward a tiny (femtoliter) water-in-oil droplet has been established. This scenario is embodied by the fusion of a w/o microdroplet at the micro liquid/liquid (L/L) interface, with the use of Fourier transform fast-scan cyclic voltammetry (FT-FSCV) to express the apparent half-wave potentials of anions or cations encapsulated inside the w/o microdroplet. First, the half-wave potential is in strict accordance with the transfer Gibbs free energy of either cations or anions. Second, the half-wave potential has been found to be pos. proportional to the logarithmic concentration of ions, shedding thermodn. insight into ion transfer. Third, as an instance of multivalent biopolymers, the transfer of protamine inside the single w/o microdroplet has been investigated. Obvious discrepancies in the behaviors of the fusion impacts at different pH, as well as in the absence and presence of the cationic surfactant DNNS^–, are revealed. The internal mechanism of protamine transfer has been thoroughly investigated. This work proposes a strategy to sensitively and quickly determine the transfer Gibbs energy and the concentration of ions encapsulated in a single microdroplet, and it provides the possibility of analyzing the interfacial transfer properties of trace biomacromols. inside an aqueous micro- or nanoscale droplet. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Quality Control of Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Quality Control of Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Difluorobis(pentafluoroethyl)phosphoranide: A Promising Building Block for Phosphoranidometal Complexes was written by Kessler, Mira;Stammler, Hans-Georg;Neumann, Beate;Roeschenthaler, Gerd-Volker;Hoge, Berthold. And the article was included in Inorganic Chemistry in 2021.Electric Literature of C4H12ClN The following contents are mentioned in the article:

Despite the fact that different metal tetrafluorophosphoranides, M[PF₄] (M = Cs, Ag, K), decompose readily, the authors successfully enhanced the stability of such species by the replacement of two F atoms with electron withdrawing pentafluoroethyl groups. Thus, AgF adds to P(C₂F₅)₂F, yielding Ag[P(C₂F₅)₂F₂], which served as a starting material for the synthesis of mono-, bis-, and tris[difluorobis(pentafluoroethyl)phosphoranido]silver complexes. Addition of 2,2′-bipyridine allowed for the isolation of stable [Ag(bipy){P(C₂F₅)₂F₂}], whereas the reaction with the chlorides [NMe₄]Cl and CoCl₂ afforded the bis- and trisphosphoranidoargentates [NMe₄][Ag{P(C₂F₅)₂F₂}₂(OEt₂)] and [Co(NCMe)₆][Ag{P(C₂F₅)₂F₂}₃]·2MeCN, resp. Altogether, the difluorobis(pentafluoroethyl)phosphoranido moiety serves as a novel, small, noncyclic phosphoranido ligand. It provided access to the 1st homoleptic phosphoranidometal complex, [Co(NCMe)₆][Ag{P(C₂F₅)₂F₂}₃]·2MeCN, which itself features the unusual structural motif of an [AgX₃]^2- ion. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Electric Literature of C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Electric Literature of C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Polymerizable deep eutectic solvent-based mechanically strong and ultra-stretchable conductive elastomers for detecting human motions was written by Zhang, Kaili;Li, Ren’ai;Chen, Guangxue;Yang, Jimin;Tian, Junfei;He, Minghui. And the article was included in Journal of Materials Chemistry A in 2021.HPLC of Formula: 75-57-0 The following contents are mentioned in the article:

Conductive elastomers (CEs) with strong mech. properties have been fabricated and used in flexible electronics. However, the development of CEs with both super-high mech. strength and extreme stretchability remains challenging. This paper reports on the development of a series of mech. strong and tough CEs based on photopolymerizable deep eutectic solvents (PDESs) with dense hydrogen bonding interactions. One of these CEs exhibits the highest reported mech. performance for elastomers, with tensile strength, strain at break and toughness up to 31.21 MPa, 3645% and 615 MJ m^-3, resp. Notably, this CE tolerates puncture and can lift a 10.5 kg weight (9500 times its own weight) without any failure. In addition, the series of CEs also shows excellent transparency (>94% in the visible range), favorable conductivity (0.007-0.04 S m^-1), tunable stretchability (strain from 22% to 6164%) and good self-healing capability (elec. healing efficiency of 99% within 0.26 s). In view of the comprehensive properties of the CEs, we demonstrate the practical suitability of CEs by including them in a strain sensor to detect human motion. Based on their extremely facile preparation process and practical functionalities, we believe that CEs will not only contribute new methods for the development of mech. strong conductors, but also open up novel avenues for flexible electronics. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0HPLC of Formula: 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.HPLC of Formula: 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

In-situ formation of a hydrophobic deep eutectic solvent based on alpha terpineol and its application in liquid-liquid microextraction of three β-blockers from plasma samples was written by Jouyban, Abolghasem;Ali Farajzadeh, Mir;Afshar Mogaddam, Mohammad Reza;Khodadadeian, Fariba;Nemati, Mahboob;Khoubnasabjafari, Maryam. And the article was included in Microchemical Journal in 2021.Recommanded Product: Tetramethylammonium chloride The following contents are mentioned in the article:

A new microextraction procedure based on liquid-liquid microextraction using a deep eutectic solvent has been used for the extraction of three β-blockers (atenolol, propranolol, and metoprolol) from plasma samples. The enriched analytes were analyzed by gas chromatog.-mass spectrometry. In this study, both of the microextraction and synthesis processes were accelerated by using microwave radiations. In this procedure, 5 mL diluted plasma sample was transferred into a glass test tube and it was mixed with 0.20 g tetramethylammonium chloride. Then 0.5 mL of DMF (as a co-disperser) was mixed with 610μL alpha terpineol and the mixture was dispersed into the solution to form a homogenous solution The tube was placed under microwave radiations for 1 min. By doing so, tetramethylammonium chloride-alpha terpineol deep eutectic solvent was formed in sample solution as tiny droplets and the analytes were extracted into them. Then the tube was cooled with tap water and centrifuged for 5 min at 5000 rpm. Finally 1μL of the deep eutectic solvent was injected into the determination system. Low limits of detection (0.130-0.205 ng mL-1) and quantification (0.435-0.692 ng mL-1), high extraction recovery (72-86%), and good precision (relative standard deviation ≤ 5.3%) were obtained. The introduced method was effectively applied for determination of the β-blockers concentrations in plasma samples. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Recommanded Product: Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Influence of fat crystallization in W/O emulsions on the water droplet size determination by NMR diffusometry was written by Nelis, Veronique;De Neve, Lorenz;Balcaen, Mathieu;Dewettinck, Koen;Courtin, Timothee;Martins, Jose C.;Van der Meeren, Paul. And the article was included in Journal of Colloid and Interface Science in 2021.Reference of 75-57-0 The following contents are mentioned in the article:

It is expected that low resolution (LR) NMR diffusometry enables (more) accurate water droplet size determination for solid-fat based water-in-oil (W/O) emulsions with (sub)-micron size water droplets in comparison to liquid-oil based W/O emulsions due to hindered extra-droplet water diffusion. W/O emulsions with a volume-weighed mean diameter of about 1μm and a solid fat content (SFC) ranging from 0% to 74% were produced. The aqueous phase contained the ionic marker tetraphenylphosphonium chloride (TPPCl). The water droplet size was estimated using LR and high resolution (HR) NMR diffusometry. HR-NMR diffusometry showed that the diffusion behavior of water and TPPCl was different, indicating water diffusion beyond the droplet’s interfacial boundaries. From a certain SFC onwards, a slower echo decay was observed for the water mols., thus decreasing the overestimation of the water droplet size in (sub)micron W/O emulsions. For those emulsions, the solid fat matrix is believed to hinder extra-droplet water diffusion, which is most likely to be related to the increased tortuosity of the diffusive path in the porous fat crystal network. Using LR-NMR, it can be verified whether the water echo attenuation is mono-exponential or bi-exponential by increasing the gradient pulse duration for the maximum gradient strength, which is more convenient for routine anal. compared to HR-NMR. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Reference of 75-57-0).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Reference of 75-57-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Tetramethylammonium Fluoride Alcohol Adducts for S_NAr Fluorination was written by Morales-Colon, Maria T.;See, Yi Yang;Lee, So Jeong;Scott, Peter J. H.;Bland, Douglas C.;Sanford, Melanie S.. And the article was included in Organic Letters in 2021.COA of Formula: C4H12ClN The following contents are mentioned in the article:

Nucleophilic aromatic fluorination (S_NAr) is among the most common methods for the formation of C(sp²)-F bonds. Despite many recent advances, a long-standing limitation of these transformations was the requirement for rigorously dry, aprotic conditions to maintain the nucleophilicity of fluoride and suppress the generation of side products. This report addresses this challenge by leveraging tetramethylammonium fluoride alc. adducts (Me₄NF·ROH) as fluoride sources for S_NAr fluorination. Through systematic tuning of the alc. substituent (R), tetramethylammonium fluoride tert-amyl alc. (Me₄NF·t-AmylOH) was identified as an inexpensive, practical, and bench-stable reagent for S_NAr fluorination under mild and convenient conditions (80°C in DMSO, without the requirement for drying of reagents or solvent). A substrate scope of more than 50 (hetero) aryl halides and nitroarene electrophiles was demonstrated. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0COA of Formula: C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).COA of Formula: C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

High-voltage and long-lasting aqueous chlorine-ion battery by virtue of “water-in-salt” electrolyte was written by Li, Tong;Li, Mingqiang;Li, Hang;Zhao, Hu. And the article was included in iScience in 2021.Recommanded Product: Tetramethylammonium chloride The following contents are mentioned in the article:

Chloride-ion battery (CIB) is regarded as a promising electrochem. storage device due to their high theor. volumetric capacities, low cost, and high abundance. However, low-cycle life limits its application in the energy storage field. Herein, we report a rechargeable CIB composed of a “water-in-salt” electrolyte, a zinc anode, and a carbon cathode (graphene, carbon nanotubes, carbon black). These cathodes exhibit initial reversible specific capacities of 136, 108, and 102 mAh g-1, resp. Especially, a reversible discharge capacity of 95 mAh g-1 was retained after 2000 cycles when graphene is used as the cathode. Such high cycling stability was first reported in CIBs. Furthermore, the use of “water-in-salt” electrolytes has improved the discharge platform of aqueous CIBs to 2.6V. The charge and discharge mechanism of the carbon cathode was investigated by TEM, FTIR, Raman, and XPS, proving the chloride ions reversible absorption/desorption in carbon cathodes. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Recommanded Product: Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Recommanded Product: Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Solubility of Calcium Oxalate Monohydrate in Concentrated Electrolyte Solutions was written by Konigsberger, Erich;Tromans, Andrew;May, Peter M.;Hefter, Glenn. And the article was included in Journal of Chemical & Engineering Data in 2021.Quality Control of Tetramethylammonium chloride The following contents are mentioned in the article:

The solubility of solid calcium oxalate monohydrate (CaC₂O₄·H₂O, COM) has been measured in aqueous solutions of four 1:1 electrolytes (NaCl, KCl, CsCl, and Me₄NCl) at temperatures T = 298.15, 323.15, and 343.15 K. Solubilities at industrially relevant electrolyte concentrations of up to 5.0 mol·kg^-1 were determined by at. absorption spectrophotometry of the dissolved calcium ions. The solubility of COM in 1.0 mol·kg^-1 electrolyte solutions was 2-4 times higher than in pure water but varied little at higher ionic strengths for all of the systems studied. Most of the observed solubilities were well correlated at all temperatures and electrolyte concentrations using a simple Specific Ion-interaction Theory (SIT) model with only one adjustable, temperature-independent, interaction parameter. For Me₄NCl solutions, an addnl. empirical ionic strength dependence of the SIT parameter significantly improved the fit. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0Quality Control of Tetramethylammonium chloride).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Quality Control of Tetramethylammonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Contribution of Molecular Dynamics in pNMR for the Structural Determination of An^V and An^VI Complexes in Solution was written by Poulin-Ponnelle, Clovis;Duvail, Magali;Dumas, Thomas;Berthon, Claude. And the article was included in Inorganic Chemistry in 2022.COA of Formula: C4H12ClN The following contents are mentioned in the article:

In this study, we propose to use classical mol. dynamics (MD) coupled with ¹H NMR spectroscopy to study the conformations of different actinyl An^VI (An = U, Np, and Pu) and An^V (An = Np) complexes with tetra-Et dyglicolamide (TEDGA) ligands in order to have a better representation of such complexes in solution Mol. dynamics simulations showed its effectiveness in interpreting the experiments by the calculation of geometric factors needed for the determination of magnetic properties of these complexes. We demonstrated that different conformations of the An^V and An^VI complexes with TEDGA exist in solution with different coordination modes, which is exptl. confirmed by ¹H NMR and EXAFS spectroscopies. Furthermore, MD simulations provide addnl. insights into the structures of complexes in solution since conformations with fast exchanges, which are not accessible from NMR experiments, have been observed by MD simulations. This study involved multiple reactions and reactants, such as Tetramethylammonium chloride (cas: 75-57-0COA of Formula: C4H12ClN).

Tetramethylammonium chloride (cas: 75-57-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.COA of Formula: C4H12ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics