Category: 7447-41-8

Tungsten ion complexes in cationic/anionic molten salt system: thermodynamic/dynamic/simulation investigation reveals configuration-induced changes in reaction was written by Feng, Ming;Xi, Xiao-li;Zhang, Li-wen;Nie, Zuo-ren. And the article was included in Journal of Physical Chemistry C in 2022.SDS of cas: 7447-41-8 The following contents are mentioned in the article:

The macroscopic properties of reactions are closely tied not only to the thermodn. and dynamics of the reactions but also to the microstructure of the ionic complexes. We herein report the anal. of the reduction process of tungsten ions in molten salt by combining the electrochem., thermodn., dynamic, and configuration parameters. The thermodn. and dynamic properties, including the apparent electrode potential, Gibbs free energy, and diffusion coefficient, of the tungsten ions were calculated by square-wave voltammetry and were found to be in good agreement with the simulation results. In addition, the concomitant changes of the diffusion coefficient and coordination number are elucidated. In all cases, the change of coordination number of the tungsten ion complexes led to the change of electrochem., thermodn., and dynamic parameters. These findings propose a new dimension for regulating the structure of metal ion complexes and analyzing the reaction properties. The combination of simulation and experiment provides a basis for the mechanism anal. of the reduction and synthesis of metal materials. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8SDS of cas: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.SDS of cas: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Study on the performance characterization and yarn mechanical properties of poly-m-phenylene isophthalamide nanofiber was written by Han, Wanli;Yi, Honglei;Zhang, Yuhao;Xi, Man;Huang, Congliang. And the article was included in Textile Research Journal in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

In this paper, poly-m-phenylene isophthalamide (PMIA) staple fibers were dissolved in a LiCl/N,N-dimethylacetamide solvent system in order to prepare PMIA nanofibers via the electrospinning method. The mean diameter of the nanofiber was between 72 and 247 nm and gradually increased with increasing LiCl concentration PMIA nanofibers were characterized by SEM, Fourier transform IR spectrometry, a thermogravimetric analyzer and Brunauer-Emmett-Teller anal. Besides, the tensile strength of PMIA nanofiber yarns was tested and analyzed, combining the orthogonal array method. The results showed that the diameter and uniformity of nanofibers decreased gradually with increasing PMIA and LiCl solution concentration The thermal properties, the sp. surface area and chem. structures of PMIA nanofibers were improved comparing with PMIA stable fiber. It was found out that the LiCl concentration could influence the interactions among polymer mols. and caused the fibrils to wrap around each other, forming fiber clusters. The LiCl concentration was the most important factor affecting the tensile strength of PMIA nanofiber yarn. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Strong, tough, ionic conductive, and freezing-tolerant all-natural hydrogel enabled by cellulose-bentonite coordination interactions was written by Wang, Siheng;Yu, Le;Wang, Shanshan;Zhang, Lei;Chen, Lu;Xu, Xu;Song, Zhanqian;Liu, He;Chen, Chaoji. And the article was included in Nature Communications in 2022.Electric Literature of ClLi The following contents are mentioned in the article:

Ionic conductive hydrogels prepared from naturally abundant cellulose are ideal candidates for constructing flexible electronics from the perspective of commercialization and environmental sustainability. However, cellulosic hydrogels featuring both high mech. strength and ionic conductivity remain extremely challenging to achieve because the ionic charge carriers tend to destroy the hydrogen-bonding network among cellulose. Here we propose a supramol. engineering strategy to boost the mech. performance and ionic conductivity of cellulosic hydrogels by incorporating bentonite (BT) via the strong cellulose-BT coordination interaction and the ion regulation capability of the nanoconfined cellulose-BT intercalated nanostructure. A strong (compressive strength up to 3.2 MPa), tough (fracture energy up to 0.45 MJ m^-3), yet highly ionic conductive and freezing tolerant (high ionic conductivities of 89.9 and 25.8 mS cm^-1 at 25 and -20°C, resp.) all-natural cellulose-BT hydrogel is successfully realized. These findings open up new perspectives for the design of cellulosic hydrogels and beyond. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Electric Literature of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Cement-and-pebble nanofluidic membranes with stable acid resistance as osmotic energy generators was written by Zhao, Yifei;Xin, Weiwen;Qian, Yongchao;Zhang, Zhehua;Wu, Yadong;Lin, Xiangbin;Kong, Xiang-Yu;Jiang, Lei;Wen, Liping. And the article was included in Science China Materials in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Osmotic energy between river water and seawater has attracted interest as a new source of sustainable energy. Nanofluidic membranes in a reverse electrodialysis configuration can capture energy from salinity gradients. However, current membrane materials suffer from high resistances, low stabilities, and low charge densities, which limit their further application. Here, we designed a high-performance nanofluidic membrane using carboxylic cellulose nanofibers functionalized with graphene oxide nanolamellas with cement-and-pebble microstructures and stable skeletons for enhanced ion transmembrane transport. By mixing artificial river water and seawater, the composite membrane achieved a high output power d. up to 5.26 W m^-2. Addnl., the membrane had an excellent acid resistance, which enabled long-term use with over 67 W m^-2 of power d. The performance of this composite membrane benefited from the mech. strong cellulose fibers and the bonding between nanofibers and nanolamellas. In this work, we highlight promising directions in industrial waste treatment using energy extracted from chem. potential gradients. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Deciphering a novel chloramphenicols resistance mechanism: Oxidative inactivation of the propanediol pharmacophore was written by Zhang, Jiayu;Yang, Chao;Hu, Jiahui;Zhang, Yiting;Lai, Yuezheng;Gong, Hongri;Guo, Fangliang;Li, Xiaoyan;Ye, Lin;Li, Bing. And the article was included in Water Research in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

Expanding knowledge about new types of antibiotic resistance genes is of great significance in dealing with the global antibiotic resistance crisis. Herein, a novel oxidoreductase capO was discovered to be responsible for oxidative inactivation of chloramphenicol and thiamphenicol. The antibiotic resistance mechanism was comprehensively deciphered using multi-omics and multiscale computational approaches. A 66,383 bp DNA fragment carrying capO was shared among four chloramphenicol-resistant strains, and the co-occurrence of capO with a mobile genetic element cluster revealed its potential mobility among different taxa. Metagenomic anal. of 772 datasets indicated that chloramphenicol was the crucial driving factor for the development and accumulation of capO in activated sludge bioreactors treating antibiotic production wastewater. Therefore, we should pay sufficient attention to its possible prevalence and transfer to pathogens, especially in some hotspot environments contaminated with high concentrations of chloramphenicols. This finding significantly expands our knowledge boundary about chloramphenicols resistance mechanisms. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Co-hydrothermal carbonization of rape straw and microalgae: pH-enhanced carbonization process to obtain clean hydrochar was written by Liu, Xiangmin;Fan, Yuwei;Zhai, Yunbo;Liu, Xiaoping;Wang, Zhexian;Zhu, Ya;Shi, Haoran;Li, Caiting;Zhu, Yun. And the article was included in Energy (Oxford, United Kingdom) in 2022.HPLC of Formula: 7447-41-8 The following contents are mentioned in the article:

In this study, co-hydrothermal carbonization of rape straw and microalgae was conducted for clean hydrochar. The effect of different feedwater pH values (pH = 1, 3, 5, 7, 9, 12) on co-HTC and the mechanism of enhanced N, S, and O removal were revealed. The acidic and alk. environment of the feedwater exacerbates the carbonization process. The higher heating value (HHV) of the hydrochar formed at pH = 1 reach 22.30 MJ/kg but the value of feedstock is only 13.87 MJ/kg. Deamination and deoxidation were the main method for protein degradation to remove N, S, and O from hydrochar. O/C, N/C, and S/C ratios of hydrochar reduced and the removal fraction of N, S, and O was 84.61%, 79.84%, and 81.80% of the hydrochar formed at pH = 1, resp. Results showed that the acidic enhanced the content of aromatic clusters in aqueous increases, and the deoxidized hydrochar with high HHV was obtained. GC-MS anal. indicates that the aromatic clusters were formed in acidic and neutral conditions, while long-chain alkanes in alk. N-containing organic substances existing in the aqueous product were removed from the hydrochar by solid-liquid separation This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8HPLC of Formula: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.HPLC of Formula: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Construction of nanosized MoP decorated highly crystalline carbon nitride sphere as an excellent photocatalyst for boosted photocatalytic hydrogen production was written by Cao, Longwen;Shi, Yuxing;Chen, Zhouze;Tian, Yuan;Chen, Lizhuang;Guo, Feng;Shi, Weilong. And the article was included in Materials Today Communications in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

High-crystalline carbon nitride (HCCN) is recognized as a promising semiconductor photocatalyst in alleviating the energy crisis and protecting the environment in the current field of photocatalysis. However, the ordinary crystalline carbon nitride is generally morphol. irregular with few surfactant sites, which limits its further application. In this work, we successfully constructed spherical HCCN embedded with MoP nanoparticles as a co-catalyst by a simple calcination treatment to form a stable and efficient MoP-HCCN composite photocatalyst. As expected, as-prepared MoP-HCCN composites presented superior photocatalytic activities for water splitting into H₂ production, and the optimal 5 wt% MoP-HCCN exhibited the optimum photocatalytic hydrogen production rate up to 10,594.29μmol·g^-1·h^-1 with the corresponding AQE reached 7.2%, which is 3.4 times than pristine HCCN and 109.9 times than amorphous carbon nitride (ACN), resp. The significant promotion in photocatalytic property is mainly due to the synergistic reaction between MoP and HCCN for effectively enhancing the segregation and rapid transportation of photogenerated electron-hole pairs. Finally, the feasible photocatalysis mechanism of MoP-HCCN compound photocatalyst is inferred. This work presents a promising design idea for developing efficient HCCN-based composite photocatalytic for hydrogen production This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Cation selectivity of activated carbon and nickel hexacyanoferrate electrode materials in capacitive deionization: A comparison study was written by Chen, Tsai-Hsuan;Cuong, Dinh Viet;Jang, Yunjai;Khu, Ngee-Zhen;Chung, Eunhyea;Hou, Chia-Hung. And the article was included in Chemosphere in 2022.Formula: ClLi The following contents are mentioned in the article:

In this study, the electrosorption selectivity of porous activated carbon (AC) and nickel hexacyanoferrate (NiHCF), which represent two working mechanisms of capacitive electrosorption and redox intercalation, was investigated to sep. cations in capacitive deionization (CDI). The cyclic voltammetry diagrams of AC showed the rectangular shape of double-layer charging, while that of NiHCF showed separated peaks associated with redox reactions. The specific capacitance of NiHCF was 143.6 F/g in 1 M NaCl, which was almost two times higher than that of AC. Cation selectivity experiments were conducted in single-pass CDI for a multi-cation solution The electrosorption preference of the AC cathode was determined by a counterbalance between the ionic charge and hydrated size, reflecting the selectivity coefficient of different cations over Na⁺ in the range of 0.86-2.63. For the NiHCF cathode, the cation selectivity was mainly dominated by the hydrated radius and redox activity. Notably, high selectivities of K⁺/Na⁺ ≈ 3.57, Na⁺/Ca²⁺ ≈ 9.97, and Na⁺/Mg²⁺ ≈ 18.92 were obtained. A significant improvement in the electrosorption capacity and monovalent ion selectivity can be achieved by utilizing the NiHCF electrode. The study demonstrates the fundamental aspects and promising opportunities of CDI in regard to ion selectivity. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Formula: ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Formula: ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Removal of C₃-C₄ diols in ethylene glycol via selective dehydration reactions over Beta zeolite with acidity tailored was written by Ai, Shuo;Qin, Yue;Hong, Yuxiang;Liu, Linghui;Yu, Wanguo. And the article was included in Journal of Catalysis in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

Biomass-derived ethylene glycol (EG) contains 1,2-propanediol (PDO) and 1,2-butanediol (BDO), and the elimination of PDO and BDO via dehydration reactions leads to EG loss due to acetalization. For the improvement of EG recovery, the selective inhibition of acetalization reaction on ion-exchange-modified H-Beta zeolite was investigated. In batch reactions, over Li₂CO₃-treated zeolite with ion-exchange ratio of 15%, the selectivity to acetals declined from 74% (untreated) to 24%. In continuous reactions, acetalization and oligomerization were obviously suppressed, and the zeolite stability was improved. EG consumption was reduced by half in both batch and continuous reactions. Microcalorimetry, NH₃-TPD, PYIR, and FTIR results demonstrated that the strong Bronsted acid sites (Si(OH)Al) with NH₃ adsorption heat ≥ 158 kJ/mol were responsible for the dehydration reactions, while Bronsted (excluding silanol group) and EFAl Lewis acid sites catalyzed the acetalization and oligomerization reactions. The activation barrier of acetalization between PDO and propanal was increased from 31.1 to 85.9 kJ/mol after the ion exchange, while that of PDO dehydration to propanal was almost kept constant (70-75 kJ/mol). Weak and moderate acid sites were removed by ion exchange, so acetalization and oligomerization were suppressed without evidently inhibiting dehydration reactions. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Aliphatic polyamide nanofilm with ordered nanostripe, synergistic pore size and charge density for the enhancement of cation sieving was written by Yuan, Bingbing;Zhao, Siheng;Xu, Shaojie;Wang, Ning;Hu, Ping;Chen, Kuo;Jiang, Juhui;Cui, Jiabao;Zhang, Xiaozhuan;You, Meng;Niu, Q. Jason. And the article was included in Journal of Membrane Science in 2022.Quality Control of Lithium chloride The following contents are mentioned in the article:

Enhanced cation sieving selectivity is significant for polyamide (PA) nanofiltration membrane in terms of extracting lithium from Salt Lake brines, which enable to reduce production cost and operating energy consumption. Herein, an aliphatic PA nanofilm with ordered nanostripe was fabricated using a novel distorted and non-coplanar monomer, cyclopentane tetracarboxylic acid chloride (CPTC). Because of the fine-tuning of the dendrimer porous layer, the resultant aliphatic PA membrane revealed decreased thickness in separation layer, and an enhanced synergistic effect of size exclusion and Donnan equilibrium on mono-/divalent cation. Separation experiments indicated that a higher MgCl2 rejection (up to 98.36%) and a lower LiCl rejection (33.3%) were obtained, thus achieving a good cation selectivity (48.25 for Na⁺/Mg2⁺, 36.5 for Li⁺/Mg2⁺). This result was better compared with the full-aromatic and most of the literature reported pos. charged PA membranes. Moreover, water flux of the CPTC-tris(2-aminoethyl) amine (TAEA) membrane with nanostripe structure (N-CPTC-TAEA) increased 3.98-4.74 times (for example, 135.9 ± 4.62 for 2000 ppm LiCl) that of the CPTC-TAEA membrane. Meanwhile, the N-CPTC-TAEA also exhibited a better antifouling property than that of the full-aromatic membrane. This study demonstrates that the N-CPTC-TAEA tends to be an alternative membrane material for cation separation This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Quality Control of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Quality Control of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics