Category: 7447-41-8

A novel O²– (2,4-dinitrophenyl) diazeniumdiolate inhibits hepatocellular carcinoma migration, invasion, and EMT through the Wnt/β-catenin pathway was written by Xing, Yihao;Hu, Yile;Zou, Hanzhi;Xie, Huaxia;Jiang, Tianci;Liu, Ling. And the article was included in Toxicology In Vitro in 2022.Formula: ClLi The following contents are mentioned in the article:

Targeted Wnt/β-catenin pathway is considered to be a promising therapy for cancer metastasis. The novel O2 -(2,4-dinitrophenyl) diazeniumdiolate (JS-K) plays a potent inhibitory role in the proliferation of cancers. In this study, HepG2 and SMMC7721 were used to clarify the efficacy of JS-K inhibition of HCC metastasis. JS-K significantly inhibited cell motility through a wound-healing assay and restrained cell migration and invasion at noncytotoxic concentrations However, the inhibitory effects of migration and invasion were abolished after the addition of NO scavenger, Carboxy-PTIO. In addition, JS-K inhibited the Wnt/β-catenin pathway by a decrease of p-GSK-3β at Ser9, cytosolic β-catenin, and nuclear β-catenin accumulation whereas an increase of p-β-catenin. Furthermore, the transcription regulators c-Myc, survivin, and Cyclin D1 were down-regulated after treating with JS-K. The inhibitory of the Wnt/β-catenin pathway was reversed after the addition of Carboxy-PTIO or LiCl. Meanwhile, JS-K also inhibited the epithelial-mesenchymal transition (EMT)-mediated cell migration and invasion. The characteristics of the inhibition were reflected by the upregulation of E-cadherin whereas the downregulation of Vimentin, Snail, and Slug. Taking together, these results demonstrated that JS-K inhibited HepG2 and SMMC7721 cells migration and invasion by reversing EMT via the Wnt/β-catenin pathway. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Formula: ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Formula: ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Bilayer heterojunction electrode to realize multivalent ion in bifunctional devices: aqueous aluminum electrochromic supercapacitor with transparent nanostructured titania/molybdenum oxide was written by Ezhilmaran, Bhuvaneshwari;Bhat, S. Venkataprasad. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2022.Related Products of 7447-41-8 The following contents are mentioned in the article:

Bifunctional electrochromic energy storage devices are of great potential in energy-efficient technologies. Present electrochromic capacitors utilize monovalent ion intercalation, and switching to a multivalent ion such as Al³⁺ is sought to sustainably overcome the prevailing performance limitations. However, the realization of such a bifunctional device has remained a challenge, owing to the strong electrostatic interaction of multivalent ions with the electrode material. To cross this hurdle, we present here a nanostructured transparent anatase TiO₂/α-MoO₃ bi-layer electrode having a host with wide lattice spacing and forming a type II heterojunction at the interface. The favorable features offered by MoO₃ and the built-in potential at the heterojunction interface resulted in a superior and stable performance in terms of coloration efficiency (128 cm²/C), transmittance change (54%), switching time (∼1s) and areal capacitance (218.8 mF/cm²). Thus, a new approach of electrode design for achieving multivalent ion intercalation in bifunctional devices is exemplified with an aqueous aluminum electrochromic supercapacitor, and the best-in-class bifunctional performance of the TiO₂/MoO₃ bilayer heterojunction electrode proves its potential to be used in energy-saving technologies of the future. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Related Products of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Related Products of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Mechanism and process for the extraction of lithium from the high magnesium brine with N,N-bis(2-ethylhexyl)-2-methoxyacetamide in kerosene and FeCl₃ was written by Ji, Lianmin;Zhang, Licheng;Shi, Dong;Peng, Xiaowu;Li, Jinfeng;zhang, Yuze;Xu, Taoshan;Li, Lijuan. And the article was included in Journal of Industrial and Engineering Chemistry in 2022.Product Details of 7447-41-8 The following contents are mentioned in the article:

The degradation of TBP has become a stumbling block to the industrial continuous production of lithium chloride extraction from brines with high Mg/Li ratio by solvent extraction To develop a more stable and more efficient extraction system, a novel amide system, containing newly synthesized extractant N,N-bis(2-ethylhexyl)-2-methoxyacetamide (NBEHMOA), FeCl₃ 6H₂O and sulfonated kerosene, was proposed in this work. Compared with TBP and N523, NBEHMOA extracted Li⁺ and H⁺ in the sequence of TBP NBEHMOA N523 and N523 TBP NBEHMOA resp. The solution containing 5.5 mol/L LiCl and 0.5 mol/L HCl was used as the eluent in the scrubbing process. A Li⁺ extraction efficiency of 96.7% and 22.31 g/L Li⁺ in the stripping solution were achieved by the whole process with counter-current twelve stages. The extraction mechanism investigated via FT-IR spectroscopy illustrated that the metal ions Fe³⁺ and Li⁺ were mainly coordinated by the carbonyl C = O in NBEHMOA. This novel amide system can successfully achieve the cascade extraction effect for lithium, Li/Mg separation and avoid the generation of phase interface objects through counter-current extraction of lithium from brine at a lower acidity. This work provided a novel extraction system to recover lithium from the higher magnesium/lithium ratio brines. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Product Details of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Product Details of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Construction of anti-counterfeiting pattern on the cellulose film by in-situ regulation strategies was written by Jing, Yidan;Wu, Chengfeng;Zhang, Xiaomin;Su, Shengpei;Mahmud, Sakil;Zhu, Jin. And the article was included in Cellulose (Dordrecht, Netherlands) in 2022.HPLC of Formula: 7447-41-8 The following contents are mentioned in the article:

Abstract: Cellulose and its derivatives films are increasingly used in paper, packaging, and other fields, but there is limited research on its films with anti-counterfeiting patterns. Here, we demonstrate an approach to prepare cellulose film with a micro-millimeter scale pattern by lithium chloride (LiCl) crystal template, which grows out by the in-situ generation in the film formation process. The surface morphologies of the as-prepared film were systematically controlled by regulating the solution viscosity (η) and the surrounding temperature The imprinting of LiCl crystal was retained on the film surface after rinsing. Moreover, the crystallinity of patterned film was significantly improved, and about 62 MPa increased tensile strength than the film without a pattern. Incredibly, these patterns were similar to fingerprint size, which exhibited an excellent function to unlock fingerprint locked phones and showed potential in the anti-counterfeiting yield. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8HPLC of Formula: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.HPLC of Formula: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Efficient lithium extraction via electrodialysis using acid-processed lithium-adsorbing lithium lanthanum titanate was written by Morita, Kenji;Matsumoto, Takanori;Hoshino, Tsuyoshi. And the article was included in Desalination in 2022.Recommanded Product: 7447-41-8 The following contents are mentioned in the article:

Increasing demands of lithium (Li) for lithium-ion batteries (LIBs) call for efficient Li extraction methods from natural resources and used LIBs. In this study, we efficiently extract Li from a Li-containing solution via electrodialysis using a fast ion conductor, lithium lanthanum titanate (LLT, Li_0.29La_0.57TiO₃), as a separation membrane. Here, the LLT surface was modified by immersing in a strong acid solution such as hydrochloric acid to adsorb Li ions. For a mixed alk. solution of lithium hydroxide, sodium hydroxide, and potassium hydroxide with a 0.1-M concentration, the maximum extraction speed of Li reached 3.5 mg/h when 5 V voltage was applied to the ionic conductor membrane with an area of 16 cm². With the Li-adsorbing LLT, 40 mg of Li was extracted after 72 h from an aqueous solution in which Li was eluted by immersing black powder of used LIBs in water. The result indicates that high alkalinity may play a key role to achieve fast extraction This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Recommanded Product: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Self-driven lithium extraction by directional liquid transport nonwoven was written by Chen, Xin;Wu, Cong;Lv, Yinjie;Zhang, Chang;Zhang, Xinshui;Nie, Lu;Zhang, Yue;Zhao, Lianqi;Huang, Chen;Liu, Wei. And the article was included in Matter in 2022.Application of 7447-41-8 The following contents are mentioned in the article:

Lithium extraction from seawater/brine has attracted increasing attention because of its abundant reserves. However, most extraction technologies require extra energy consumption to enrich lithium in the solution Here, we develop a self-driven lithium extraction method by a composite asym. nonwoven (CAN) with directional liquid transport functionality. CAN consists of one hydrophobic fibrous layer containing Li-ion sieve particles and one hydrophilic fibrous layer. As a result, a solution containing various types of ions can spontaneously transport through CAN from the hydrophobic to the hydrophilic layer, absorbing Li ions in the hydrophobic layer. CAN exhibits high Li⁺ selective adsorption capacity, good chem. stability, easy recyclability, and long service life. Importantly, extremely low energy of ∼1.631 J is consumed on extracting 1 mg lithium ion by our method using CAN. This work opens a great promise of saving huge energy costs on lithium extraction from seawater or salt lakes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Understanding the Chemical Shifts of Aqueous Electrolyte Species Adsorbed in Carbon Nanopores was written by Sasikumar, Anagha;Griffin, John M.;Merlet, Celine. And the article was included in Journal of Physical Chemistry Letters in 2022.Related Products of 7447-41-8 The following contents are mentioned in the article:

Interfaces between aqueous electrolytes and nanoporous carbons are involved in a number of technol. applications such as energy storage and capacitive deionization. Nuclear magnetic spectroscopy is a very useful tool to characterize ion adsorption in such systems thanks to its nuclei specificity and the ability to distinguish between ions in the bulk and in pores. We use complementary methods (d. functional theory, mol. dynamics simulations and a mesoscopic model) to investigate the relative importance of various effects on the chem. shifts of adsorbed species: ring currents, ion organization in pores of various sizes, specific ion-carbon interactions and hydration. We show that ring currents and ion organization are predominant for the determination of chem. shifts in the case of Li⁺ ions and hydrogen atoms of water. For the large Rb⁺ and Cs⁺ ions, the addnl. effect of the hydration shell should be considered to predict chem. shifts in agreement with experiments This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Related Products of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Related Products of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Water recovery assessment from hypersaline lithium-rich brines using Membrane Distillation-Crystallization was written by Quilaqueo, Michelle;Seriche, Gabriel;Barros, Lorena;Gonzalez, Carol;Romero, Julio;Ruby-Figueroa, Rene;Santoro, Sergio;Curcio, Efrem;Estay, Humberto. And the article was included in Desalination in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

The current lithium extraction from hypersaline salt-lake brines is causing concerns, mainly due to the evaporation and loss of around 90% of the water contained in the brines, tensioning the relationship between communities and industrial companies located in zones with a severe water scarcity. This study assesses the water recovery from synthetic hypersaline brines – mimicking the contents variability of Na, K, and Mg – using a Membrane Distillation-Crystallization process. An evaluation of the operational parameters of the process, such as feed temperature, flowrate and water activity was carried-out using a Response Surface Methodol. Final validation was performed to assess the process performance by comparing a real brine from Maricunga salt-lake (Chile) and a synthetic brine. An average flux of around 3.5 kg/m2 h at 60°C brine feed temperature was obtained for real and synthetic brines, achieving a high quality recovered freshwater (elec. conductivity <40μS/cm) and low contents of ions. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Simultaneous improvement of flux and monovalent selectivity of multilayer polyelectrolyte membranes by ion-imprinting was written by Chen, Shunmei;Mao, Cuicui;Hu, Baisong;Zhang, Wei;Deng, Huining. And the article was included in Desalination in 2022.Application of 7447-41-8 The following contents are mentioned in the article:

This study aims to fabricate monovalent cations selective membranes through Layer-by-Layer (LbL) assembly with ion-imprinting introduced. Nickel ions (Ni²⁺) were introduced into the polycation of polyethyleneimine (PEI) as template and then modified the ultrafiltration membrane through LbL assembly followed by glutaraldehyde (GA) crosslinking and reduction After eluting the template, ion-imprinting channels with specific size were formed in the modified layer. These channels enhanced the water flux with the selectivity for Na⁺/Mg²⁺ improved 2.25 times simultaneously compared to the non-imprinted membrane. Besides, the membrane preparation conditions were optimized and the optimum selectivity of 4.16 was achieved. We analyzed the mechanism of improving separation performance via ion-imprinting technol. and believed that this environmental-friendly method provides a new road to fabricate monovalent selective membrane for seawater softening and lithium extraction from magnesium-rich brine. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Novel (100-x-y)Li₃PS₄-xLiBF₄-yLiCl amorphous solid electrolytes for all-solid-state Li ion battery was written by Phuc, Nguyen H. H.;Gamo, H.;Hikima, K.;Muto, H.;Matsuda, A.. And the article was included in Journal of Non-Crystalline Solids in 2022.Application of 7447-41-8 The following contents are mentioned in the article:

Amorphous solid electrolytes in the composition (100-x-y)Li₃PS₄-xLiBF₄-yLiCl (x, y: mol%) were prepared using the high-energy ball-milling method. XRD, FT-IR, and solid-state ³¹P NMR proved the formation of amorphous samples. Peak shifting in FT-IR spectra illustrated the dissociation of LiBF₄ and LiCl. Solid-state ³¹P NMR demonstrated the formation of highly distorted PS₄ tetrahedral. Those structural characteristics accompanied by elec. conductivity enhancement from 2.8 x 10^-4 Scm^-1 of Li₃PS₄ to 6.3 x 10^-4 Scm^-1 in 50Li₃PS₄·40LiBF₄·10LiCl solid electrolyte. Besides elec. conductivity, electrochem. stability against Li metal and LiNi₀.₅Co₀.₂Mn₀.₃O₂, operated at high voltage, was also achieved with the existence of LiBF₄ and LiCl in solid electrolytes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics