Category: 7447-41-8

The interaction studies of novel imine ligands and palladium(II) complexes with DNA and BSA for drug delivery application: The anti-cancer activity and molecular docking evaluation was written by Karami, Kazem;Mehvari, Fariba;Ramezanzade, Vahid;Zakariazadeh, Mostafa;Kharaziha, Mahshid;Ramezanpour, Azar. And the article was included in Journal of Molecular Liquids in 2022.Name: Lithium chloride The following contents are mentioned in the article:

In the effort to discover anti-cancer drugs and improve the therapeutic efficacy of metal-based compounds, two new imine ligands and their palladium [Pd (II)] complexes were synthesized and characterized by several spectroscopic techniques. Besides, a groove interaction of samples with DNA was observed, and the interaction with bovine serum albumin (BSA) revealed the remarkable binding affinity of samples. Also, the quenching properties of BSA were measured by competitive site markers experiments, which they preferred site I and II on BSA. Then, BSA nanoparticles (BSA-NPs) were prepared using the desolvation method and characterized for the drug delivery system of synthesized samples. Next, they were loaded on the BSA-NPs, which their morphol. displayed high compatibility with one another. Further, the in-vitro comparative drug release activity between samples and loaded samples was examined, which the release profiles exhibited a bi-phase pattern involving an initial burst release, obeyed a sustained pattern. Addnl., the cytotoxicity effects of samples were evaluated against the breast cancer cell lines. Based on the calculated IC50, BSA-NPs exhibited the significant role by enhancing the cytotoxicity. Furthermore, the in-silico mol. docking simulation of the samples was examined, and the obtained results were in agreement with the empirical results. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Name: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Name: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Decomposition of PVDF to delaminate cathode materials from end-of-life lithium-ion battery cathodes was written by Ji, Yi;Jafvert, Chad T.;Zyaykina, Nadezhda N.;Zhao, Fu. And the article was included in Journal of Cleaner Production in 2022.Electric Literature of ClLi The following contents are mentioned in the article:

The growing demand of elec. vehicles and rapid consumption of rechargeable lithium-ion batteries (LIBs) require recycling of spent cathode active materials (CAMs) to reduce hazardous wastes and supply raw materials to LIB production To sep. CAMs from the cathode, direct calcination of polyvinylidene fluoride (PVDF) binder is widely applied, which leads to high energy consumption and release of toxic hydrogen fluoride. It is desirable to have an environmentally friendly and effective alternative to traditional direct calcination. In this study, five lithium salts, LiOAc (lithium acetate), LiNO₃, LiCl, Li₂CO₃, and Li₂SO₄, were deployed and compared for their performance in recycling CAMs. A peel-off efficiency of up to 98.5% was achieved at a LiOAc to LiNO₃ molar ratio of 3:2, salt to cathode mass ratio of 10:1, and temperature of 300°C at a holding time of 30 min. This system avoids corrosive chems. and minimizes particle agglomeration of recycled products. Compared with sodium salt systems (NaOAc-NaNO₃) or direct calcination, the LiOAc-LiNO₃ system prevented high reaction temperature or further lithium loss, and minimized crystal structure and morphol. changes. A decomposition mechanism of PVDF through adsorption of HF and fluorine substitution was proposed. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Electric Literature of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Solid-Liquid Equilibria (SLE) of the Quinary Reciprocal Aqueous System Li⁺, K⁺, Rb⁺//Cl^–, Borate-H₂O at 323.2 K was written by Zhuge, Fuyu;Feng, Xia;Yu, Xudong. And the article was included in Journal of Chemical & Engineering Data in 2022.HPLC of Formula: 7447-41-8 The following contents are mentioned in the article:

The isothermal dissolution method was applied for the phase equilibrium experiment of the reciprocal quinary system Li⁺, K⁺, Rb⁺//Cl^–, Borate-H₂O at 323.2 K; the related d. (ρ) of the system was measured by the sp. gr. bottle method exptl., and the crystalloid forms of the equilibrated solid phase were identified by the X-ray diffraction method. Results show that the system belongs to a complex type with the formation of solid solution [(K, Rb)Cl]; six single salts, LiCl·H₂O, KCl, RbCl, Li₂B₄O₇·3H₂O, K₂B₄O₅(OH)₄·2H₂O, and RbB₅O₆(OH)₄·2H₂O, were also formed at 323.2 K; no double salt was found in this system. The space phase diagram consists of five quinary invariant points, fifteen isothermal dissolution curves, and seven crystallization fields. The size of the RbB₅O₆(OH)₄·2H₂O crystallization field is the largest among the coexisting salts in the quinary system. Under the condition of RbB₅O₈ saturation, the crystallization field of Li₂B₄O₇·3H₂O occupied the largest crystallization region, and salt RbCl had the smallest region. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8HPLC of Formula: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.HPLC of Formula: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Diffusiophoretic Movements of Polystyrene Particles in a H-Shaped Channel for Inorganic Salts, Carboxylic Acids, and Organic Salts was written by Timmerhuis, Nicole A. B.;Lammertink, Rob G. H.. And the article was included in Langmuir in 2022.Name: Lithium chloride The following contents are mentioned in the article:

Diffusiophoresis is the movement of particles as a result of a concentration gradient, where the particles can move toward higher concentrations The magnitude of the movement is largest for the electrolyte solute and depends upon the relative concentration gradient, surface potential, and diffusivity contrast between the cation and anion. Here, diffusiophoresis of ordinary polystyrene particles is studied in a H-shaped channel for different solutes. The exptl. results are compared to a numerical model, which is solely based on the concentration gradient, surface potential, and diffusivity contrast. The surface potential of the particles was measured to use as input for the numerical model. The diffusiophoretic movement of the experiments aligns well with the theor. predicted movement for the inorganic (lithium chloride and sodium bicarbonate) and organic (lithium formate, sodium formate, and potassium formate) salts measured. However, for the carboxylic acids (formic, acetic, and oxalic acids) measured, the theor. model and experiment do not align because they are weak acids and only partially dissociate, creating a driving force for diffusiophoresis. Overall, the H-shaped channel can be used in the future as a platform to measure diffusiophoretic movement for more complex systems, for example, with mixtures and asym. valence electrolytes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Name: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Name: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

BSA fragmentation specifically induced by added electrolytes: An electrospray ionization mass spectrometry investigation was written by Lusci, Gloria;Pivetta, Tiziana;Carucci, Cristina;Parsons, Drew Francis;Salis, Andrea;Monduzzi, Maura. And the article was included in Colloids and Surfaces, B: Biointerfaces in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:

Biointerfaces are significantly affected by electrolytes according to the Hofmeister series. This work reports a systematic investigation on the effect of different metal chlorides, sodium and potassium bromides, iodides and thiocyanates, on the ESI/MS spectra of bovine serum albumin (BSA) in aqueous solution at pH = 2.7. The concentration of each salt was varied to maximize the quality of the ESI/MS spectrum, in terms of peak intensity and bell-shaped profile. The ESI/MS spectra of BSA in the absence and in the presence of salts showed a main protein pattern characterized by the expected mass of 66.5 kDa, except the case of BSA/RbCl (mass 65.3 kDa). In all systems we observed an addnl. pattern, characterized by at least three peaks with low intensity, whose deconvolution led to suggest the formation of a BSA fragment with a mass of 19.2 kDa. Only NaCl increased the intensity of the peaks of the main BSA pattern, while minimizing that of the fragment. NaCl addition seems to play a crucial role in stabilizing the BSA ionized interface against hydrolysis of peptide bonds, through different synergistic mechanisms. To quantify the observed specific electrolyte effects, two “Hofmeister” parameters (Hs and Ps) are proposed. They are obtained using the ratio of (BSA-Salt)/BSA peak intensities for both the BSA main pattern and for its fragment. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Synthetic Route of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Analysis on in vitro effect of lithium on telomere length in lymphoblastoid cell lines from bipolar disorder patients with different clinical response to long-term lithium treatment. was written by Squassina, Alessio;Meloni, Anna;Congiu, Donatella;Bosganas, Panagiotis;Patrinos, George P;Lin, Rixing;Turecki, Gustavo;Severino, Giovanni;Ardau, Raffaella;Chillotti, Caterina;Pisanu, Claudia. And the article was included in Human genomics in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

BACKGROUND: It has been suggested that bipolar disorder (BD) is associated with clinical and biological features of accelerated aging. In our previous studies, we showed that long-term lithium treatment was correlated with longer leukocyte telomere length (LTL) in BD patients. A recent study explored the role of TL in BD using patients-derived lymphoblastoid cell lines (LCLs), showing that baseline TL was shorter in BD compared to controls and that lithium in vitro increased TL but only in BD. Here, we used the same cell system (LCLs) to explore if a 7-day treatment protocol with lithium chloride (LiCl) 1 mM was able to highlight differences in TL between BD patients clinically responders (Li-R; n = 15) or non-responders (Li-NR; n = 15) to lithium, and if BD differed from non-psychiatric controls (HC; n = 15). RESULTS: There was no difference in TL between BD patients and HC. Moreover, LiCl did not influence TL in the overall sample, and there was no difference between diagnostic or clinical response groups. Likewise, LiCl did not affect TL in neural precursor cells from healthy donors. CONCLUSIONS: Our findings suggest that a 7-day lithium treatment protocol and the use of LCLs might not represent a suitable approach to deepen our understanding on the role of altered telomere dynamics in BD as previously suggested by studies in vivo. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Crystal structure prediction by combining graph network and optimization algorithm was written by Cheng, Guanjian;Gong, Xin-Gao;Yin, Wan-Jian. And the article was included in Nature Communications in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

Crystal structure prediction is a long-standing challenge in condensed matter and chem. science. Here we report a machine-learning approach for crystal structure prediction, in which a graph network (GN) is employed to establish a correlation model between the crystal structure and formation enthalpies at the given database, and an optimization algorithm (OA) is used to accelerate the search for crystal structure with lowest formation enthalpy. The framework of the utilized approach (a database + a GN model + an optimization algorithm) is flexible. We implemented two benchmark databases, i.e., the open quantum materials database (OQMD) and Matbench (MatB), and three OAs, i.e., random searching (RAS), particle-swarm optimization (PSO) and Bayesian optimization (BO), that can predict crystal structures at a given number of atoms in a periodic cell. The comparative studies show that the GN model trained on MatB combined with BO, i.e., GN(MatB)-BO, exhibit the best performance for predicting crystal structures of 29 typical compounds with a computational cost three orders of magnitude less than that required for conventional approaches screening structures through d. functional theory calculation The flexible framework in combination with a materials database, a graph network, and an optimization algorithm may open new avenues for data-driven crystal structural predictions. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

A novel lithium ion-imprinted membrane with robust adsorption capacity and anti-fouling property based on the uniform multilayered interlayer was written by He, Guangze;Li, Zheng;Liu, Yuxiao;Liu, Meijun;Zhu, Chuntao;Zhang, Lanhe;Zhang, Haifeng. And the article was included in Desalination in 2022.Recommanded Product: 7447-41-8 The following contents are mentioned in the article:

Effective modification strategies contribute to high adsorption capacity, separation efficiency and anti-fouling properties of ion-imprinted membranes. The design of a homogeneous and hydrophilic interlayer between the substrate membrane and ion-imprinted layer is crucial factor for the excellent performance of ion-imprinted membranes. In this study, a novel multilayered interlayer (SiO₂@SP-PDA) was developed and uniformly coated on the substrate surface (PVDF membrane). The polydopamine (PDA) prepared via oxidation of sodium periodate (SP-PDA) increases the uniformity of SiO₂@SP-PDA modification, which reduces the agglomeration of the ion-imprinted layer, and thereby boosts the adsorption capacity to 231.77 mg·g^-1. The prepared ion-imprinted membrane (SiO₂@SP-PDA-IIM) exhibits a favorable anti-fouling property due to the incremental hydrophilicity and the presence of SiO₂ nano interlayer. Based on the XDLVO theory, it can be deduced that the SiO₂ modification increases the membrane surface electron donor tension (γ-), which plays an essential role in enhancing the anti-fouling property of SiO₂@SP-PDA-IIM. In this paper, the design of multilayered structure is of great significance to make the ion-imprinted membrane be a potential candidate for Li+ efficient separation in natural water. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Recommanded Product: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Effect of Dielectric Saturation on Ion Activity Coefficients in Ion Exchange Membranes was written by Paspureddi, Akhilesh;Sharma, Mukul M.;Katz, Lynn E.. And the article was included in ACS Omega in 2022.SDS of cas: 7447-41-8 The following contents are mentioned in the article:

Polymeric ion exchange membranes are used in water purification processes to sep. ions from water. The distribution and transport of ionic species through these membranes depend on a variety of factors, including membrane charge d., morphol., chem. structure and the specific ionic species present in the fluid. The elec. potential distribution between membranes and solutions is typically described using models based on Donnan theory. An extension of the original theory is proposed to account for nonideal behavior of ions both in the fluid and in the membrane as well to provide a more robust description of interactions of solutes with fixed charge groups on the polymer backbone. In this study, the variation in dielec. permittivity in the membrane medium with elec. field strength is taken into account in a model based on Gouy-Chapman double-layer theory to provide a more accurate description of ion activity coefficients in an ion exchange membrane. A semianal. model is presented that accounts for the variation in dielec. permittivity of water in a charged polymer membrane. A comparison of this model with Manning’s counterion condensation model clearly demonstrates that by incorporating changes in water dielec. permittivity with elec. field strength, much better agreement with experiments can be obtained over a range of salt concentrations for different ions. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8SDS of cas: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.SDS of cas: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Limited ion-ion selectivity of salt-rejecting membranes due to enthalpy-entropy compensation was written by Shefer, Idit;Peer-Haim, Ophir;Epsztein, Razi. And the article was included in Desalination in 2022.Electric Literature of ClLi The following contents are mentioned in the article:

Water and ion transport in salt-rejecting membranes, such as nanofiltration (NF) and reverse osmosis (RO), are exposed to different hindrance effects that result in selectivity between species. In this study, we explored systematically the hindrance effects that govern water-salt and ion-ion selectivity in NF and RO membranes. More specifically, we measured the permeability of different species at varying temperatures and applied an Eyring-type equation to quantify the enthalpic and entropic barriers for their transport in three types of salt-rejecting membranes. We found that water-salt selectivity is entropically driven, where water mols. gain entropy in the membrane, while the salt ions face a substantial entropic barrier due to their larger size that reduces their possible configurations in the membrane. As the enthalpic barriers of the water and salt did not show a prominent difference (with minor effect on the water-salt selectivity), most ion-ion separations were restricted by an enthalpy-entropy compensation (EEC) effect; i.e., an ion with a higher entropic barrier experienced a lower enthalpic barrier compared to the competing ion, resulting in minor variations in the free-energy barriers between ions that limit the ion-ion selectivity. We conclude by proposing possible mechanisms that promote EEC during ion transport in salt-rejecting membranes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics