Category: 7447-41-8

Moisture sorption isotherms and thermodynamic properties of tiger nuts: An oil-rich tuber was written by Zhang, Zhen-shan;Li, Xiao-dan;Jia, Hui-jie;Liu, Yu-lan. And the article was included in LWT–Food Science and Technology in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

The moisture adsorption isotherms of tiger nuts were determined by a gravimetric static method at 15, 25, 35°C within the water activity varying from 0.113 to 0.979. Ten math. models were selected to fit the adsorption data using non-linear regression technique. Thermodn. properties such as isosteric heat, sorption entropy and Gibbs free energy were evaluated. The results indicated that equilibrium moisture content of tiger nuts tended to increase with increasing water activity and decreasing temperature The isotherm curves of tiger nuts exhibited a Type II sigmoidal shape. Peleg model was the most suitable for describing the exptl. sorption behavior, followed by the Smith and GAB models. The adsorption surface area and monolayer moisture content of tiger nuts obtained from GAB model were 166.37-149.74 m²/g solid and 4.71-4.24 H₂O/100 g solid, resp., which decreased with increasing temperature Moreover, the isosteric heat of adsorption decreased exponentially with the increase of equilibrium moisture content, while the Gibbs free energy was opposite. Adsorption entropy was neg. in value and it decreased sharply and then rose slowly as the moisture content increased, having a min. value (6.43 J/mol K) at a moisture content of 11 g/100 g d.b. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Electrochemical properties of a lithium-impregnated metal foam anode (LIMFA FeCrAl) for molten salt thermal batteries was written by Choi, Yusong;Ahn, Tae-Young;Ha, Sang-Hyeon;Lee, Jae-In;Cho, Jang-Hyeon. And the article was included in Scientific Reports in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:

Although numerous cathode materials with excellent properties have been developed for use in molten salt thermal batteries, similar progress is yet to be made with anode materials. Herein, a high-performance lithium-impregnated metal foam anode (LIMFA) is fabricated by impregnating molten lithium into a gold-coated iron-chrome-aluminum (FeCrAl) foam at 400°C. A test cell employing the LIMFA FeCrAl anode exhibited a specific capacity of 2627 As g^-1. For comparison, a cell with a conventional Li(Si) anode was also discharged, demonstrating a specific capacity of 982 As g^-1. This significant improvement in performance can be attributed to the large amount (18 wt%) of lithium incorporated into the FeCrAl foam and the ability of the FeCrAl foam to absorb and immobilize molten lithium without adopting a cup system. For thermal batteries without a cup, the LIMFA FeCrAl provides the highest-reported specific capacity and a flat discharge voltage curve of molten lithium. After cell discharge, the FeCrAl foam exhibited no lithium leakage, surface damage, or structural collapse. Given these advantageous properties, in addition to its high specific capacity, LIMFA FeCrAl is expected to aid the development of thermal batteries with enhanced performance. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Synthetic Route of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Promoting favorable interfacial properties in lithium-based batteries using chlorine-rich sulfide inorganic solid-state electrolytes was written by Zeng, Dewu;Yao, Jingming;Zhang, Long;Xu, Ruonan;Wang, Shaojie;Yan, Xinlin;Yu, Chuang;Wang, Lin. And the article was included in Nature Communications in 2022.Computed Properties of ClLi The following contents are mentioned in the article:

The use of inorganic solid-state electrolytes is considered a viable strategy for developing high-energy Li-based metal batteries. However, suppression of parasitic interfacial reactions and growth of unfavorable Li metal depositions upon cycling are challenging aspects and not yet fully addressed. Here, to better understand these phenomena, we investigate various sulfide inorganic solid electrolytes (SEs), i.e., Li_7-xPS_6-xCl_x (x = 0.6, 1.0, 1.3, 1.45, and 1.6), via ex situ and in situ physicochem. and electrochem. measurements. We found that the Cl distribution and the cooling process applied during the SE synthesis strongly influence the evolution of the Li|SE interface in terms of microstructure, interphase composition, and morphol. Indeed, for a SE with a moderate chlorine content (i.e., x = 1.3) and obtained via a slow cooling process after sintering, the Cl atoms are located on the surface of the SE grains as interconnected LiCl nanoparticles that form an extended LiCl-based framework. This peculiar microstructure facilitates the migration of the Cl ions to the Li|SE interface during electrochem. cycling, thus, favoring the formation of a LiCl-rich interphase layer capable of improving the battery cycling performances. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Computed Properties of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Computed Properties of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Evaluation of the local structure and electrochemical behavior in the LiCl-KCl-SmCl₃ melt was written by Zhao, Jia;Liu, Zhaoting;Liang, Wenshuo;Lu, Guimin. And the article was included in Journal of Molecular Liquids in 2022.Quality Control of Lithium chloride The following contents are mentioned in the article:

This present work evaluates the local structure and electrochem. behavior of the LiCl-KCl-SmCl₃ melt to facilitate the efficient reprocessing of spent nuclear fuel (SNF). At 723 K, the radial distribution function, coordination number, and structure factors were adopted to understand the local structure of LiCl-KCl and LiCl-KCl-SmCl₃ based on first-principles mol. dynamics (FPMD) simulation. We found the SmCl₃ slight effect on LiCl-KCl melts in short-range order and its influence on the distribution of Li-Li intermediate-range order. Moreover, the diffusion coefficient of Sm(III) 2.012 x 10^-5 cm²/s in LiCl-KCl melts was determined by analyzing the mean square displacement. The electrochem. behavior of Sm(III) was conducted in the temperature range from 673 K to 823 K by a series of electrochem. methods. According to the theory of Matsuda and Ayabe, the Sm(III) + e- = Sm(II) is a quasi-reversible process. The diffusion coefficient of Sm(III) was measured by the chronoamperometry method, which verified the credibility of the FPMD simulation. Furthermore, this work explored the exchange c.d. of Sm(III)/Sm(II), whose value is between 0.826 x 10^-3 and 2.383 x 10^-3 A·cm^-2, by the linear polarization. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Quality Control of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Quality Control of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ion specificity in the measured concentration depth profile of ions at the Vapor-Glycerol interface was written by Kumar, Anand;Craig, Vincent S. J.;Page, Alister J.;Webber, Grant B.;Wanless, Erica J.;Andersson, Gunther. And the article was included in Journal of Colloid and Interface Science in 2022.HPLC of Formula: 7447-41-8 The following contents are mentioned in the article:

Specific ion effects are manifest universally across many systems and solvents. While broad understanding of these effects is emerging particularly for bulk effects, the perturbation introduced by the interfaces are generally not understood. We hypothesise that through a careful investigation of the distribution of ions at the glycerol-vapor interface we can better understand specific ion effects in this system and at interfaces. Neutral impact collision ion scattering spectroscopy (NICISS) is used to obtain and compare individual ion concentration depth profiles (CDP) for a range of monovalent inorganic anions and cations at 12 glycerol electrolyte solutions surfaces. The distribution of ions at the vapor – glycerol interface is non-monotonic. Broadly, anions are concentrated at the outermost region of the interface and cations are depleted from the interface. The distribution of Cl^– and I^– is mostly independent of the counterion. However, for Br^– ions the distribution depends on the counterion where Cs⁺, K⁺, and Na⁺ ions lead to a desorption of Br^– ions from the interface. This is favored by the large solvation energy of Br^– ions and consistent with the law of matching effective ion sizes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8HPLC of Formula: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.HPLC of Formula: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Portable wireless humidity sensor based on hyperbranched polysiloxane for multifunctional non-contact sensing was written by Yang, Yimeng;Li, Xifang;Qi, Duo;Zhao, Chengji. And the article was included in Sensors and Actuators, B: Chemical in 2022.Reference of 7447-41-8 The following contents are mentioned in the article:

Non-contact sensing is an immediate research focus as a much greener and hygienic human-machine interface. Nonetheless, much research remains to be done on fast and stable non-contact sensors based on humidity signals. Hence, in this paper, hyperbranched sulfonated polysiloxane (HPS) with carboxyl groups at the end was synthesized by polycondensation reaction. The resulting polymer was compounded with LiCl and fabricated into humidity sensors. Benefiting from the tailored hydrophilicity/hydrophobicity of the material, flexible siloxane backbones and ionized LiCl, the sensor exhibited five orders of magnitude impedance changes over a wide humidity test range (11-98% RH) with rapid response (1-2 s) and small humidity hysteresis (3% RH). The results of continuous cyclic test confirmed the good reproducibility and stability of the material. Moreover, the sensor was able to distinguish and respond to fingers at different distances, respirations with altered frequencies and various commands. By integrating humidity sensors into the circuit, a low-cost, portable and wireless non-contact monitoring device was developed. The detector enables real-time display of data on a cell phone, which is of great potential value for non-contact distance detection, command recognition and respiration monitoring. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Reference of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Reference of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Hygroscopic holey graphene aerogel fibers enable highly efficient moisture capture, heat allocation and microwave absorption was written by Hou, Yinglai;Sheng, Zhizhi;Fu, Chen;Kong, Jie;Zhang, Xuetong. And the article was included in Nature Communications in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

Aerogel fibers have been recognized as the rising star in the fields of thermal insulation and wearable textiles. Yet, the lack of functionalization in aerogel fibers limits their applications. Herein, we report hygroscopic holey graphene aerogel fibers (LiCl@HGAFs) with integrated functionalities of highly efficient moisture capture, heat allocation, and microwave absorption. LiCl@HGAFs realize the water sorption capacity over 4.15 g g^-1, due to the high surface area and high water uptake kinetics. Moreover, the sorbent can be regenerated through both photo-thermal and electro-thermal approaches. Along with the water sorption and desorption, LiCl@HGAFs experience an efficient heat transfer process, with a heat storage capacity of 6.93 kJ g^-1. The coefficient of performance in the heating and cooling mode can reach 1.72 and 0.70, resp. Notably, with the entrapped water, LiCl@HGAFs exhibit broad microwave absorption with a bandwidth of 9.69 GHz, good impedance matching, and a high attenuation constant of 585. In light of these findings, the multifunctional LiCl@HGAFs open an avenue for applications in water harvest, heat allocation, and microwave absorption. This strategy also suggests the possibility to functionalize aerogel fibers towards even broader applications. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Application of the e-NRTL model to electrolytes in mixed solvents methanol-, ethanol- water, and PEG-water was written by Valverde, J. L.;Ferro, V. R.;Giroir-Fendler, A.. And the article was included in Fluid Phase Equilibria in 2022.Electric Literature of ClLi The following contents are mentioned in the article:

In this work, the e-NRTL binary interaction parameters for the alc.-water (ethanol-water and methanol-water), electrolyte-alc. (NaBr-methanol, NaBr-ethanol, NaCl-methanol, NaCl-ethanol, KCl-methanol and KCl-ethanol), PEG (polyethylene glycol)-water (PEG1000-, PEG4000- and PEG6000-water) and electrolyte-PEG (NaCl and KCl-PEG4000-water, KCl-PEG1000-water, LiCl-PEG4000-Water, CsCl-PEG (PEG1000, PEG4000 and PEG 6000)-Water) were evaluated by the non-linear regression of exptl. data at different temperatures, reported in the literature. The application used was able to evaluate the impact of the NRTL, Debye-Huckel and Born contributions on the activity coefficients of a salt (or an electrolyte) in different media. In addition, the solubility constants, and the free energy of transfer on the molar scale of NaCl, KCl and NaBr in alc.-water mixed solvents (methanol-water and ethanol-water at different temperatures) were evaluated by using the e-NRTL model and the binary interaction parameters previously computed. It was reached an excellent correlation of the exptl. data of water activity, mean activity coefficient and osmotic pressure data of ethanol-water and methanol-water solutions, electrolyte-alc. systems, and electrolyte-PEG, resp. The presence of PEG and alc. in solution had a great influence on the solubility of the solid phases. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Electric Literature of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Toy-blocks-inspired programmable supercapacitors with high energy density was written by Luo, Zhiling;Kou, Bingdong;Wang, Yi;Song, Yuting;Weng, Mingcen;Liu, Changhong;Zhang, Wei;Chen, Luzhuo. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2022.SDS of cas: 7447-41-8 The following contents are mentioned in the article:

Diversity and individuation development of wearable electronics require their power sources to be programmable and customizable. However, how to prepare all-purpose electrodes with high designability and satisfying energy d. for power sources is still a serious challenge. Herein, we propose programmable supercapacitors based on novel electrode blocks, which are inspired from toy blocks. Polyaniline/carbon nanotube strip is adopted as electrode block template, where one end of the strip is loaded with capacitive MnO2 (4.9-12.4 mg cm-2) as the cathode head, while the other end is left untreated as the anode head. These two heads are designed with opposite potential windows, forming a 2.5 V asym. supercapacitor with a high areal capacitance (679.0 mF cm-2). The supercapacitor reaches a remarkable energy d. of 513.3μWh cm-2, which is further utilized to power a high power-consumption fan and an E-ink display. Finally, the electrode blocks are applied to programmably construct a variety of energy devices, such as high-voltage device, stretchable device, three-dimensional supercapacitor lantern and wirelessly self-charged display system. The concept of general electrode block together with its two-head feature to increase energy d. will provide a new route to fabricate programmable power sources for the booming wearable electronics. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8SDS of cas: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.SDS of cas: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Study on the performance of solar interfacial evaporation for high-efficiency liquid desiccant regeneration was written by Wu, Dongxu;Cui, Qi;Gao, Yuanzhi;Dai, Zhaofeng;Chen, Bo;Wang, Changling;Zhang, Xiaosong. And the article was included in Energy (Oxford, United Kingdom) in 2022.Computed Properties of ClLi The following contents are mentioned in the article:

Liquid desiccant air conditioning system (LDAS) was considered a promising air conditioning system due to the advantages of low-grade heat utilization, effective humidity control and environment-friendly. The performance of LDAS significantly depends on the heat and mass transfer components, namely dehumidifier and regenerator, while the regeneration process of traditional regenerator is energy-inefficient. Inspired by the high-efficiency solar interfacial evaporation which can produce drinking water from seawater, this method was introduced in this work for liquid desiccant regeneration to overcome the inefficiency of the regeneration process. Wood was prepared as the regenerator by alkali-assisted method and surface carbonization. The regeneration performance of solar interfacial regeneration was exptl. investigated and compared with that of packed-bed tower regeneration and membrane distillation regeneration. Results show solar interfacial regeneration is very competitive due to the high regeneration rate and efficiency, which can reach 0.57 kg m-2 h-1 and 42.5% for 40% LiCl solution under 1-sun irradiation Moreover, the low temperature rises of concentrated solution, cheap construction costs and operating costs make LDAS more energy-saving. This work is expected to supply a novel method for liquid desiccant regeneration. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Computed Properties of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Computed Properties of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics