Category: 7447-41-8

Frequency-controlled electrophoretic mobility of a particle within a porous, hollow shell was written by Welling, Tom A. J.;Grau-Carbonell, Albert;Watanabe, Kanako;Nagao, Daisuke;de Graaf, Joost;van Huis, Marijn A.;van Blaaderen, Alfons. And the article was included in Journal of Colloid and Interface Science in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:

The unique properties of yolk-shell or rattle-type particles make them promising candidates for applications ranging from switchable photonic crystals, to catalysts, to sensors. To realize many of these applications it is important to gain control over the dynamics of the core particle independently of the shell. The core particle may be manipulated by an AC elec. field with rich frequency-dependent behavior. Here, we explore the frequency-dependent dynamic electrophoretic mobility of a charged core particle within a charged, porous shell in AC elec. fields both exptl. using liquid-phase electron microscopy and numerically via the finite-element method. These calculations solve the Poisson-Nernst-Planck-Stokes equations, where the core particle moves according to the hydrodynamic and elec. forces acting on it. In experiments the core exhibited three frequency-dependent regimes of field-driven motion: (i) parallel to the field, (ii) diffusive in a plane orthogonal to the field, and (iii) unbiased random motion. The transitions between the three observed regimes can be explained by the level of matching between the time required to establish ionic gradients in the shell and the period of the AC field. We further investigated the effect of shell porosity, ionic strength, and inner-shell radius. The former strongly impacted the core’s behavior by attenuating the field inside the shell. Our results provide phys. understanding on how the behavior of yolk-shell particles may be tuned, thereby enhancing their potential for use as building blocks for switchable photonic crystals. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Synthetic Route of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Quantum chemical calculations of formation enthalpies of cations and anions of ionic liquids was written by Govorov, Dmitrii N.;Dunaev, Anatoliy M.;Motalov, Vladimir B.;Kudin, Lev S.. And the article was included in Journal of Molecular Liquids in 2022.Recommanded Product: 7447-41-8 The following contents are mentioned in the article:

The development of advanced ionic-liquid-based applications requires accurate thermochem. data for both ionic liquids and their constituent ions. Herein, the formation enthalpies of alkylimidazolium cations ([C_nMIm⁺], n = 2, 4, 6, 8, 10) and various anions (trifluoromethanesulfonate ([TfO^–]), Et sulfate ([ES^–]), dicyanamide ([DCA^–]), and bis(trifluoromethane)sulfonylimide ([NTf₂^–])) in the ideal gas state were obtained by quantum chem. calculations using d. functional theory (DFT: B3LYP, B98, M06, M06-2X) and composite (G4) thermochem. models in the framework of the isodesmic reaction approach. The enthalpies of heterolytic dissociation of neutral ion pairs (NIPs) for the [C_nMIm⁺][X^–] series (n = 2, 4, 6, 8, 10; X- = [TfO^–], [ES^–], [NTf₂^–], [DCA^–], [BF₄^–], [PF₆^–], [Cl^–], [Br^–], [I^–]) were derived using the obtained data and literature formation enthalpies (Δ_fH°) of NIPs. Anal. of the thermochem. property trends revealed that the formation enthalpies of [C_nMIm⁺] decrease linearly as the alkyl chain length increases. In addition, the use of the isodesmic reaction approach improved the reliability of the computed data. Furthermore, owing to its internal self-consistency, the G4 method was found to be the most appropriate for describing the thermodn. quantities of the cations and anions of ionic liquids This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Selective recovery of lithium resources in salt lakes by polyacrylonitrile/ion-imprinted polymer: Synthesis, testing, and computation was written by Ding, Tao;Wu, Qian;Nie, Zhen;Zheng, Mianping;Wang, Yunsheng;Yang, Donghui. And the article was included in Polymer Testing in 2022.Reference of 7447-41-8 The following contents are mentioned in the article:

Lithium as a strategic metal exhibits extensive applications in the 21st century. The high-efficiency extraction of lithium resources is of economic significance as the market demand for elec. vehicles powered by lithium-ion batteries increases rapidly. A novel silica gel (SG)/graphene oxide (GO) composite nanofiber was prepared by combining surface imprinting technol. with electrospinning technol. to capture Li(I) from salt lakes in an oriented manner. The batch adsorption experiments and fixed-bed adsorption experiments were conducted to evaluate the adsorption performance of the composites. The SG/GO composite exhibited a maximum adsorption capacity of 1.1 mg/g for Li(I). The adsorption kinetics tallied with the pseudo-second-order model, and the isothermal adsorption was similar to the Langmuir model. The adsorption process of the SG/GO composite is one of monolayer chem. adsorption, and the adsorbates did not interact. The adsorption mechanism was revealed by Fourier transform IR (FT-IR) spectroscopy and SEM (SEM), combined with d. functional theory (DFT) computation. The mechanism anal. indicated that the charge transfer occurred between the surface functional groups and metal ions in the adsorption process. The electrons mainly transferred from the P and O atoms of the functional groups to the 3p orbit of Li(I) to form coordinate bonds, which finally achieved the goal of oriented capture of Li(I). The polyacrylonitrile (PAN)/ion-imprinted polymer (IIP) composite nanofiber is a novel, high-efficiency adsorbing material for recovering Li(I) from salt-lake brine. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Reference of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Reference of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Lithium hydroxide dehydration behavior influences lithium ion adsorption on hydrogen titanium oxide with different facets exposed was written by Zhao, Bing;Qian, Zhiqiang;Qiao, Yinjun;Li, Jun;Wu, Zhijian;Liu, Zhong. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2023.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

In this study, octahedrons assembled nanospheres Li₄Ti₅O₁₂ (LTO-OS) with dominant (111) facet and nanosheets assembled microspheres Li₄Ti₅O₁₂ (LTO-NS) with dominant (01-1) facet precursors were synthesized. Then, these corresponding H₄Ti₅O₁₂ adsorbents (HTO-OS and HTO-NS) were obtained via acid treatment and used to recover lithium from aqueous solutions The systematic adsorption tests show that HTO-NS possesses higher adsorption uptake (35.5 mg/g) and faster adsorption rate (equilibrium time: <2 h) than HTO-OS (31.2 mg/g), owing to the role of different dehydration processes and exposed facets. With the help of DFT calculation analyses, the dehydration of Li(H₂O)⁺₄ on HTO (01-1) and (111) were partially dehydrated Li(H₂O)⁺ and Li(H₂O)⁺₂ in the adsorption process, owing to crystal channel and surface at. arrangement. In addition, the anal. of the adsorption mechanism indicates that the Li⁺ exist in the form of hydrated lithium ions in the initial adsorption solution, and the dehydration processes occur during Li(H₂O)⁺₄ move to the surface of the adsorbent, then an ion exchange reaction has happened between the dehydrated Li⁺ and H⁺. These results reveal the adsorbents with different facets exposed indeed influence the surface dehydration processes and Li⁺ adsorption behaviors, which are favorable to better understand the interfacial interactions between adsorbents and adsorbates. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Volume properties of the ternary systems (LiCl + LiB₅O₈ + H₂O) and (Li₂SO₄ + LiB₅O₈ + H₂O) from 283.15 to 363.15 K and 101.325 kPa was written by Yuan, Fei;Li, Hua;Li, Long;Wang, Shiqiang;Guo, Yafei;Deng, Tianlong. And the article was included in Journal of Chemical Thermodynamics in 2022.Electric Literature of ClLi The following contents are mentioned in the article:

In this study, densities of the two ternary aqueous solution systems (LiB₅O₈ + LiCl + H₂O) and (LiB₅O₈ + Li₂SO₄ + H₂O) were measured using an accurate digital vibrating-tube densimeter from 283.15 to 363.15 K at an interval of 5 K and 101.325 kPa. B₅O^–₈ in aqueous solution was in the form of [B₅O₆(OH)₄]^–. Therefore, the complex aqueous solution of LiB₅O₈ is in the form of Li[B₅O₆(OH)₄]. Subsequently, the mean apparent molar volume (V^θ_Φ) and mixing ion-interaction parameters (θ^v_a,a’ and ψ^v_c,a,a’, c = Li⁺, a = B₅O₆(OH)^–₄, a’= Cl^– or SO^2-₄) against temperature were obtained using the Pitzer equation for the first time. And then, the temperature-dependence equations for the Pitzer mixing ion-interaction parameters and the relevant temperature correlation coefficients of the equation a_j, i.e. [f (a_i, T) = a₁ + a₂ln(T/298.15) + a₃(T – 298.15) + a₄/(620 – T) + a₅/(T – 227)] were also obtained through the least square fitting. These volumetric properties and parameterization Pitzer parameters obtained in this work could hopefully be used for the quant. predictive calculation of the physicochem. properties of the mixed electrolytes containing lithium, chloride, and sulfate ions at any temperature This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Electric Literature of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Electric Literature of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Inkjet printed Ta₂O₅ on a flexible substrate for capacitive pH sensing at high ionic strength was written by Beale, Christopher;Altana, Antonio;Hamacher, Stefanie;Yakushenko, Alexey;Mayer, Dirk;Wolfrum, Bernhard;Offenhaeusser, Andreas. And the article was included in Sensors and Actuators, B: Chemical in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

Many pH sensors on the market today have specific limitations, such as the large and fragile construction of glass electrodes, or the complicated manufacturing processes of silicon-based devices including ion-sensitive field-effect transistors (ISFETs). Furthermore, most pH sensors require a stable reference electrode, which is difficult to miniaturize. In applications where the solution properties are largely understood, the use of an impedimetric sensor without a reference electrode may be sufficient, thereby simplifying the manufacturing of such sensors. In this work, inkjet printed and flash lamp annealed Ta₂O₅. On interdigitated electrodes, with an approx. sensor area of 4 mm x 4 mm, is investigated as a capacitive pH sensing layer in 0.5 M alkali chloride buffer solutions By using the equivalent circuit of the insulator-electrolyte interface, the double layer capacitance is shown to decrease with an increase in pH within the range of pH 2 to pH 9, and agrees with prior results for anodic Ta2O5. When using the device as a sensor in both 0.5 M NaCl and 0.5 M LiCl aqueous solutions, the change in capacitance at 100 Hz is approx. – 110 nF/pH. Apart from pH sensing, these results may also prove informative in other applications, such as electrolytic capacitors, electrophysiol., and battery anodes in aqueous electrolyte. Moreover, the use of flexible, gold metalized polyethylene terephthalate (PET) foils as the sensor substrate potentially allows for large-scale production via roll-to-roll manufacturing, and further permits for use of the sensor in flexible applications such as goods packaging. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

New nonmagnetic aliovalent dopants (Li⁺, Cu²⁺, In³⁺ and Ti⁴⁺): Optical and strong intrinsic room temperature ferromagnetism of perovskite BaSnO₃ was written by Sharmoukh, Walid;Hameed, Talaat A.;Yakout, Saad Mabrouk. And the article was included in Journal of Alloys and Compounds in 2022.HPLC of Formula: 7447-41-8 The following contents are mentioned in the article:

Nonmagnetic Li+, Cu2+, In3+ and Ti4+ ions were employed to induce robust room temperature ferromagnetism in perovskite BaSnO3 for advanced spintronics applications. New BaSn0.96M0.04O3 (M = Li+, Cu2+, In3+ and Ti4+) compositions were synthesized by modified Pechini method. In all compositions, single phase of cubic BaSnO3 was detected in the XRD patterns without any impurities. The FTIR spectra displayed the distinctive vibrational absorption band of BaSnO3 and verified the absence of any impurities. The SEM images evidently showed a decrement of grain size alongside morphol. changes for doped BaSnO3 compositions compared to the pure one. The band gap energy of BaSnO3 was considerably influenced by the incorporation of Li+, Cu2+, In3+ and Ti4+ dopants. BaSn0.96Cu0.04O3 sample exhibited the highest refractive index value and the min. value was obtained for BaSn0.96Ti0.04O3. Remarkably, at equal concentration two of the used nonmagnetic elements showed the ability to induce room temperature ferromagnetism in BaSnO3 lattice. Herein, BaSn0.96Cu0.04O3 exhibits a robust and sym. ferromagnetic hysteresis loop with complete saturation magnetization (Ms) of 0.158 emu/g and coercivity (Hc) of 42 Oe. BaSn0.96Ti0.04O3 composition revealed a ferromagnetic behavior within magnetic field of± 5000 Oe and the trend was reversed for higher values to show a diamagnetic performance. The interaction between the 3d orbitals of Cu2+ (3d9) or Ti4+ (d0) with the trapped electrons in the oxygen vacancies encourage a ferromagnetic coupling in BaSnO3 structure. The outer shell orbitals of Cu2+ and Ti4+ dopants and the oxygen vacancies seem to play a significant role in the magnetic properties. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8HPLC of Formula: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.HPLC of Formula: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Exploring the Li⁺ transporting mutant of NCX_Mj for assigning ion binding sites of mitochondrial NCLX was written by Giladi, Moshe;Mitra, Sunayana;Simhaev, Luba;Hiller, Reuben;Refaeli, Bosmat;Strauss, Tali;Baiz, Carlos R.;Khananshvili, Daniel. And the article was included in Cell Calcium in 2022.Quality Control of Lithium chloride The following contents are mentioned in the article:

The plasma membrane (NCX) and mitochondrial (NCLX) Na⁺/Ca²⁺ exchangers are structurally related proteins, although they operate under strictly different ionic conditions and membrane potentials. In contrast with NCX, NCLX can transport either Li⁺ or Na⁺ in exchange for Ca²⁺. Whereas the crystal structure of the archaeal NCX (NCX_Mj) describes the binding sites for alternative binding of 3Na⁺ or 1Ca²⁺, these features remain elusive for NCLX due to the lack of structural information. To elucidate the ion-binding features of mitochondrial NCLX, we analyzed here the Li⁺-transporting NCLX_Mj mutant, produced by replacing the ion-coordinating residues in the archaeal NCX (NCX_Mj) to match the ion-coordinating residues of human NCLX. The NCLX_Mj-mediated Na⁺/Ca²⁺ or Lia⁺/Ca²⁺ exchange rates are insensitive to varying voltage, consistent with an electroneutral ion exchange. Mol. dynamics (MD) simulations revealed that NCLX_Mj contains two novel Li⁺ binding sites with four ion-coordinating residues, derived from the three Na⁺ binding sites of NCX_Mj. The ion-coordination modes, observed in the MD simulations, were further supported by two-dimensional IR (2D IR) spectroscopy and by testing the mutational effects on the ion fluxes. Collectively, our results revealed a structural basis for Li+ binding and electroneutral transport (2Na+/Li+:1Ca²⁺) by NCLX_Mj, meaning that the NCLX-mediated electroneutral transport may predefine mitochondrial Ca²⁺ and Na⁺signaling to modulate cellular functions. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Quality Control of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Quality Control of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Energetic and exergetic analysis of a solar-driven single-effect absorption refrigeration system using LiBr+LiCl/H₂O solution mixture was written by Aktemur, Cenker;Ozturk, Ilhan Tekin. And the article was included in Journal of Solar Energy Engineering in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Comprising an eco-friendly blueprint, absorption refrigeration systems have attracted a lot of interest as they can use biomass, solar and geothermal energy sources which can mitigate climate change. The current study presents a methodol. based on energy and anal. for solar-driven single-effect absorption refrigeration systems, which offer a 50-kW cooling capacity. This study proposes a new mixture ratio of LiBr+LiCl (mass ratio of 2:1)/H₂O solution and compared it to LiBr/H₂O thermodynamically. Based on the climate data of Kocaeli province in Turkey, an evacuated tube collector is employed to benefit from solar energy to meet the generator heat load of the system. Although at an evaporator temperature of 5 °C, enhanced thermodn. performance is evident with the use of the LiBr +LiCl/H₂O system, and a diminished solar collector area is required compared to the system utilizing LiBr/H₂O; there is a level of attrition relating to the impact of the former with a single degree rise in evaporator temperature However, this remained at a greater value than for the latter system. The final results pointed out that LiBr+LiCl/H₂O has a 48.93% lower circulation ratio, 8.81% higher coefficient of performance (COP) of chiller, 8.88% higher solar COP, 8.96% higher exergy efficiency of chiller, 8.90% higher exergy efficiency of solar-driven system, 8.92% lower solar collector area, and 8.91% lower storage tank volume than LiBr/H₂O system in the investigated operating temperature ranges. The final results of the present study can be safely tested in the exptl. design of single-effect absorption chillers. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Performance assessment of novel liquid desiccant drying/air conditioning cum desalination system by incorporating M-cycle based dehumidification process was written by Pandey, Tryambke;Tejes, P. K. S.;Naik, B. Kiran. And the article was included in Desalination in 2022.HPLC of Formula: 7447-41-8 The following contents are mentioned in the article:

In this study, a novel liquid desiccant air conditioning/drying cum desalination system is proposed employing Maisotsenko cycle-based indirect contact cooler in the dehumidifier and membrane-based indirect contact regenerator instead of the conventional structured packing-based dehumidifier and structured packing based direct contact regenerator. The liquid desiccant selected for the present investigation is lithium chloride (LiCl). A thermal model is developed to predict the performance of the above-mentioned conventional and novel systems. The developed model has been validated with the exptl. data available in the literature and found to match well with a maximum possible error of ±9.7%. Depending upon the developed model, a performance comparison of conventional and novel systems and performance assessment of novel air conditioning/drying cum desalination system is carried out. From the performance assessment, it is observed that for the given operating range, coefficient of performance (COP) varies from 0.75-0.81 and 0.85-0.92 for conventional and novel systems, resp. that are intended for air conditioning application whereas system efficiency varies from 50%-55% and 70%-75% for conventional and novel systems, resp. which are meant for drying application. Further, it is also found that the novel system has 18% more COP and 27% higher system efficiency compared to the conventional system designated for air conditioning and drying applications, resp. Moreover, from the novel air conditioning/drying cum desalination system, the maximum amount of freshwater obtained as a byproduct from the atm. air is about 4.62 LPM. The proposed system has multipurpose applications such as building space cooling, drying food products, and extraction of pure water from ambient air. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8HPLC of Formula: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).HPLC of Formula: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics