Category: 7447-41-8

Synthesis and characterization of low-temperature lithium-ion conductive phase of LiX (X = Cl, Br)-Li₃PS₄ solid electrolytes was written by Tsujimura, Tomoyuki;Ito, Seitaro;Yoshida, Koji;Higashiyama, Yuki;Aihara, Yuichi;Machida, Nobuya;Park, Youngsin;Im, Dongmin. And the article was included in Solid State Ionics in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

A new class of sulfide electrolytes, (1-x)LiCl-xLiBr-2Li₃PS4 (x = 0, 0.25, 0.50, 0.75, and 1.0), was synthesized, and characterized their stable temperature range, ionic-conductivity and applicability for all-solid-state lithium metal battery. The optimal heat-treatment temperature of the synthesis process is relatively low, i.e., 200 °C. Ionic conductivity of the electrolyte increases with increasing LiBr ratio, and maximum ionic conductivity at 25 °C is 1.7 mScm^-1 with x = 0.75. At higher heat-treatment temperature, above 250 °C, a low-ionic-conduction crystalline phase appears in the electrolyte, and at that time, ionic conductivity decreases to a similar value to that of the amorphous precursor used in the synthesis process. Since the electrolyte does not contain a transition metal, it is applicable to the lithium-metal secondary system. A reversible lithium deposition-stripping reaction was demonstrated by cyclic voltammogram, the results of which indicate that the electrolyte is applicable to a typical 4-V rechargeable lithium-metal secondary system. The Coulombic efficiency of the first charge-discharge cycle is approx. 75%, and reversible capacity of 185 mAhg-1 was verified by a Li/0.25LiCl-0.75LiBr-2Li₃PS₄/NCA pelletized-cell test. It is concluded from these results that the proposed low-temperature-synthesized sulfide electrolytes will reduce energy consumption for material production, and such a low-carbon-footprint process meets the demand of the future sustainable society. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Effect of chronic lithium on mechanical sensitivity and trabecular bone loss induced by type-1 diabetes mellitus in mice was written by Graniel-Amador, Mayra Alejandra;Torres-Rodriguez, Hector Fabian;Martinez-Mendoza, Ruth Elena;Vargas-Munoz, Virginia Margarita;Acosta-Gonzalez, Rosa Issel;Castaneda-Corral, Gabriela;Munoz-Islas, Enriqueta;Jimenez-Andrade, Juan Miguel. And the article was included in BioMetals in 2022.Product Details of 7447-41-8 The following contents are mentioned in the article:

Type-1 diabetes mellitus (T1DM) is a chronic condition characterized by long-term hyperglycemia that results in several complications such as painful peripheral neuropathy, bone deterioration, and increased risk of bone fractures. Lithium, a first-line therapy for bipolar disorder, has become an attractive agent for attenuating peripheral neuropathy and menopause-induced bone loss. Therefore, our aim was to determine the effect of chronic lithium treatment on mech. hypersensitivity and trabecular bone loss induced by T1DM in mice. T1DM was induced in male C57BL/6J mice by i.p. injection of streptozotocin (STZ, 50 mg/kg/day, for 5 consecutive days). 12 wk after T1DM-induction, mice received a daily i.p. injection of vehicle, 30 or 60 mg/kg lithium (as LiCl) for 6 wk. Throughout the treatment period, blood glucose levels and mech. sensitivity were evaluated every 2 wk. After lithium treatment, the femur and L5 vertebra were harvested for microcomputed tomog. (microCT) anal. T1DM mice showed significant hyperglycemia, mech. hypersensitivity, and significant trabecular bone loss as compared with the control group. Chronic lithium treatment did not revert the hindpaw mech. hypersensitivity nor hyperglycemia associated to T1DM induced by STZ. In contrast, microCT anal. revealed that lithium reverted, in a dose-dependent manner, the loss of trabecular bone associated to T1DM induced by STZ at both the distal femur and L5 vertebra. Lithium treatment by itself did not affect any trabecular bone parameter in non-diabetic mice. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Product Details of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Product Details of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Effect of hydrothermal carbonization and eutectic salt mixture (KCl/LiCl) on the pyrolysis of Kraft lignin as revealed by thermal analysis coupled to advanced high-resolution mass spectrometry was written by Friederici, Lukas;Mesceriakove, Sara-Maaria;Neumann, Anika;Sermyagina, Ekaterina;Mesceriakovas, Arunas;Laehde, Anna;Grimmer, Christoph;Streibel, Thorsten;Rueger, Christopher P.;Zimmermann, Ralf. And the article was included in Journal of Analytical and Applied Pyrolysis in 2022.Application of 7447-41-8 The following contents are mentioned in the article:

The production of graphite requires high temperatures, and fossil petroleum, coal, or nutshells are frequently used as a carbon source. As a replacement, Kraft lignin, a byproduct of the pulp and paper industry, is a promising carbon source. Biomass-based feedstocks with improved characteristics can be obtained by hydrothermal carbonization, but the chem. nature of this process is not fully understood yet. Moreover, adding a eutectic salt mixture (LiCl/KCl) to the pyrolysis of kraft lignin and HTC lignin can improve the graphitization at lower temperatures In this study, thermal anal. with online mass spectrometric detection of evolved gas mixture was applied to explore the influence of the eutectic salt mixture on the char conversion process. Aside from classical pyrolysis gas chromatog. mass spectrometry, thermogravimetry coupled with soft photoionization mass spectrometry allowed to identify phenol, hydrogen sulfide, di-Me sulfide, and various larger lignin fragments. These larger dimeric/trimeric methoxyphenol derivatives were successfully validated by means of high-resolution mass spectrometry equipped with soft atm. pressure chem. ionization. The investigations indicated the catalytic influence of the salt mixture on the production process of the biochars, achieving partially graphitization already at relatively low temperatures On the morphol., Raman spectroscopy and electron microscopy revealed the evolution of the carbon structures and revealed that the materials have typical features for amorphous carbon. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Application of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Roles of Anion-Cation Coupling Transport and Dehydration-Induced Ion-Membrane Interaction in Precise Separation of Ions by Nanofiltration Membranes was written by Zhai, Xiaohu;Wang, Yong-Lei;Dai, Ruobin;Li, Xuesong;Wang, Zhiwei. And the article was included in Environmental Science & Technology in 2022.COA of Formula: ClLi The following contents are mentioned in the article:

Nanofiltration (NF) membranes are playing increasingly crucial roles in addressing emerging environmental challenges by precise separation, yet understanding of the selective transport mechanism is still limited. In this work, the underlying mechanisms governing precise selectivity of the polyamide NF membrane were elucidated using a series of monovalent cations with minor hydrated radius difference. The observed selectivity of a single cation was neither correlated with the hydrated radius nor hydration energy, which could not be explained by the widely accepted NF model or ion dehydration theory. Herein, we employed an Arrhenius approach combined with Monte Carlo simulation to unravel that the transmembrane process of the cation would be dominated by its pairing anion, if the anion has a greater transmembrane energy barrier, due to the constraint of anion-cation coupling transport. Mol. dynamics simulations further revealed that the distinct hydration structure was the primary origin of the energy barrier difference of cations. The cation having a larger incompressible structure after partial dehydration through subnanopores would induce a more significant ion-membrane interaction and consequently a higher energy barrier. Moreover, to validate our proposed mechanisms, a membrane grafting modification toward enlarging the energy barrier difference of dominant ions achieved a 3-fold enhancement in ion separation efficiency. Our work provides insights into the precise separation of ionic species by NF membranes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8COA of Formula: ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.COA of Formula: ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Interfacial and cycle stability of sulfide all-solid-state batteries with Ni-rich layered oxide cathodes was written by Wang, Jiacheng;Zhang, Zhenyu;Han, Jiufang;Wang, Xuefeng;Chen, Liquan;Li, Hong;Wu, Fan. And the article was included in Nano Energy in 2022.COA of Formula: ClLi The following contents are mentioned in the article:

The interfacial compatibility between sulfide solid electrolyte (SSE) and Ni-rich layered oxide (NRLO) cathode is critical for high-performance sulfide all-solid-state Li-ion batteries (SASSLIBs). However, the reasons for interfacial/capacity degradation of SASSLIBs are not yet clearly resolved. Herein, the impacts of surface structures and chem. environments of LiNi_0.83Co_0.11Mn_0.06O₂ (NCM83) on SASSLIB performances are systematically investigated. Surface lithium vacancies of NCM83 facilitate Li ion migration from SSE to NCM83 side, suppressing the H1 phase transformation of NCM83 and expanding the space charge layer. Surface Li_xNi_1-xO type rock salt phases inhibit oxygen-participating interfacial reactions at high voltages due to their low susceptibility to oxygen evolutions, enhancing the H2/H3 phase transformation of NCM83. Surface Li₂O and Li₂CO₃ mitigate the space charge layer effect and interfacial reactions at high voltages, activating H1 and H2/H3 phase transformations of NCM83. On the other hand, the combination of LiOH and Li₂CO₃ causes severe side reactions with SSE, resulting in escalated interfacial resistance and drastic capacity fading over cycling. Importantly, while the suppression of H1 and H2/H3 transformations reduces the reversible capacity, it mitigates the internal stress and micro-cracks in NCM83 particles, contributing to superior cycling stability of NCM83-sulfide ASSLIBs (94.1% capacity retention over 500 cycles). This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8COA of Formula: ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.COA of Formula: ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Dual-electric layer nanofiltration membranes based on polyphenol/PEI interlayer for highly efficient Mg²⁺/Li⁺ separation was written by Chen, Kuo;Zhao, Shengchao;Lan, Hongling;Xie, Tengteng;Wang, Hao;Chen, Yuhao;Li, Peng;Sun, Haixiang;Niu, Q. Jason;Yang, Chaohe. And the article was included in Journal of Membrane Science in 2022.Recommanded Product: 7447-41-8 The following contents are mentioned in the article:

In recent years, the global demand for lithium resources has grown substantially due to the rapid development of the new energy industry. The nanofiltration (NF) technique is a feasible method to extract lithium from salt-lake brine, and the high Mg²⁺/Li⁺ separation selectivity of the NF membrane is the crucial factor in the NF separation process. In this work, the polyamide (PA) layer was prepared on the polyphenol/PEI interlayer-modified polysulfone (PSF) substrate to endow the NF membrane with decreased pore size and weakened electronegativity. Enhanced steric hindrance effect and reduced electrostatic attraction between Mg²⁺ and PA layer increased the Mg²⁺ rejection, thereby improving the Mg²⁺/Li⁺ separation factor of the NF membrane. Furthermore, the pos. charged polyphenol/PEI interlayer hindered the permeation of Mg²⁺ through the Donnan effect, further enhancing the Mg²⁺/Li ⁺ separation factor. A separation factor up to 50.7 for Mg²⁺/Li⁺ was achieved by extracting lithium from simulated brine using the obtained NF membrane. In addition, the NF membrane exhibited a permeability of 18.6 L m^-2 h^-1·bar^-1 and excellent long-term stability, which greatly improved the Mg²⁺/Li⁺ separation efficiency and reduced energy consumption. Therefore, this work provides a simple strategy for preparing NF membranes with high Mg²⁺/Li⁺ separation factor and permeability. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Recommanded Product: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Novel magnetic iron-nickel/poly(ethersulfone) mixed matrix membranes for oxygen separation potential without applying an external magnetic field was written by Nady, Norhan;Salem, Noha;Kandil, Sherif H.. And the article was included in Scientific Reports in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

This work presents novel magnetic mixed matrix poly(ethersulfone) (PES) membranes that combine the advantages of low-cost common PES polymer and low-cost iron-nickel magnetic alloys. Moreover, the presented magnetic mixed matrix PES membranes were fabricated and used without applying an external magnetic field during either the membrane casting or the separating process. The fabricated magnetic membranes were prepared using the phase inversion technique and N-methylpyrrolidone and N,N-dimethylformamide solvents mixture with volumetric ratio 1:9 and Lithium chloride as an additive. The used iron-nickel magnetic alloys were prepared by a simple chem. reduction method with unique morphologies (Fe₁₀Ni₉₀; starfish-like and Fe₂₀Ni₈₀; necklace-like). The fabricated membranes were characterized using SEM and Scanning-Transmission Electron Microscope (STEM) imaging, energy dispersive X-ray (EDX), TGA, and XRD. Also, static water contact angle, membrane thickness, surface roughness, membrane porosity, membrane tensile strength as well as Vibrating Sample Magnetometer (VSM) anal. and oxygen transition rate (OTR) were determined Moreover, the effect of alloy concentration and using Lithium chloride as an additive on the properties of the fabricated blank PES and magnetic mixed matrix PES membranes were studied. The presented novel magnetic mixed matrix PES membranes have high coercivity up to 106 (emu/g) with 3.61 x 10^-5 cm³/cm².s OTR compared to non-oxygen permeable blank PES membranes. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ultralarge Flakes of Ti₃C₂T_x MXene via Soft Delamination was written by Shekhirev, Mikhail;Busa, Jeffrey;Shuck, Christopher E.;Torres, Angel;Bagheri, Saman;Sinitskii, Alexander;Gogotsi, Yury. And the article was included in ACS Nano in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

Two-dimensional (2D) titanium carbide MXene (Ti₃C₂T_x) has attracted significant attention due to its combination of properties and great promise for various applications. The size of the 2D sheets is a critical parameter affecting multiple properties of assembled films, fibers and 3D structures. The increased lateral size of MXene flakes can benefit not only their assemblies by improving the interflake contacts and alignment but also fundamental studies at the individual flake level, allowing for facile patterning and investigation of intrinsic phys. properties of MXenes. Increasing the average size of the parent MAX phase is one of the strategies previously used to increase the flake size of the resultant MXene. Here, we show that the protocol used for the next step of the synthesis procedure, delamination of multilayer MXene into individual nanosheets, significantly affects the lateral size of the resultant flakes. We developed a soft delamination approach, which prevents fracture of flakes and preserves their size. Combining this approach with the large-grain Ti₃AlC₂ MAX phase precursor, we achieved individual flakes of up to 40μm in lateral size. These flakes can be used for patterning multiple contacts and fabrication of field-effect transistors for multiprobe elec. characterization and other measurements. These findings indicate the importance of controlling the delamination process in order to achieve large MXene flakes and improve properties of MXene-based materials and devices. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Solid-Liquid Phase Equilibria and Boron Species Distribution in the Quaternary System LiCl-LiBO₂-Li₂B₄O₇-H₂O at T = 323.15 K and P = 0.1 MPa was written by Zhang, Tao;Zhuang, Liwei;Li, Dan;Meng, Lingzong;Deng, Tianlong;Guo, Yafei;Ma, Yong. And the article was included in Journal of Chemical & Engineering Data in 2022.SDS of cas: 7447-41-8 The following contents are mentioned in the article:

The solubilities of salts, refractive indexes, and pH values of the equilibrium liquid phases in the quaternary system LiCl-LiBO₂-Li₂B₄O₇-H₂O at 323.15 K were investigated by the isothermal dissolution method for the first time. The dry-salt diagram of the quaternary system consisted of one invariant point, three univariant curves and three crystallization fields corresponding to LiCl·H₂O, LiBO₂·2H₂O, and Li₂B₄O₇·3H₂O. The solution refractive indexes and pH values change regularly with the changing of concentration Combining the equilibrium constants for different boron species, the distributions of six boron species in the mixed solution in the systems LiCl-LiBO₂-H₂O, LiBO₂-Li₂B₄O₇-H₂O, and LiCl-Li₂B₄O₇-LiBO₂-H₂O were calculated with the total boron concentration and pH values. The main boron species in the mixed solution of the quaternary system are B₃O₃(OH)₄^–, B₄O₅(OH)₄^2-, B(OH)₃, and B₅O₆(OH)₄^–. The boron species distributions are mainly affected by the pH values and the concentration of total boron and LiCl in the solution The results of phase diagram and boron species distribution in the quaternary system can supply foundation data for separating lithium borate from brines. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8SDS of cas: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.SDS of cas: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Towards Ni-rich layered oxides cathodes with low Li/Ni intermixing by mild molten-salt ion exchange for lithium-ion batteries was written by Luo, Yu-hong;Pan, Qing-lin;Wei, Han-xin;Huang, Ying-de;Tang, Lin-bo;Wang, Zhen-yu;He, Zhen-jiang;Yan, Cheng;Mao, Jing;Dai, Ke-hua;Zhang, Xia-hui;Zheng, Jun-chao. And the article was included in Nano Energy in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:

In the conventional synthesis of layered transition metal oxides, the high-temperature process not only causes lithium loss due to evaporation, but also facilitate the inevitable cation mixing of Li⁺ and Ni²⁺, resulting in severe shifts in their stoichiometric ratios and thus structure instability. Herein, we report a universal ion-exchange method to prepared Ni-rich layered oxide materials LiNi₀.₈₅Co₀.₀₆Mn₀.₀₉O₂ (NCM85) with low Li/Ni intermixing at a low reaction temperature of 300C, where sodium-based layered oxides (NaNi₀.₈₅Co₀.₀₆Mn₀.₀₉O₂) were used as precursors for ion exchange with Li⁺ ion in lithium molten salts. By studying the effects of ion-exchange time and addnl. heat treatment on the structure and performance of the layered oxide materials, we established the processing-structure-performance relationships for Ni-rich NCM85 materials. Moreover, we further demonstrated the universality of this ion-exchange method and processing-structure-performance relationships for other layered oxide materials including LiNi0. ₅Co₀.₂Mn₀.₃O₂ and LiNi₀.₅Mn₀.₅O₂. We anticipate that such universal method of ion exchange and universal processing-structure-performance relationships can guide the rational design and synthesis of other layered oxide materials for lithium-ion batteries. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Synthetic Route of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics