Category: 7447-41-8

Flexible self-powered integrated sensing system based on a rechargeable zinc-ion battery by using a multifunctional polyacrylamide/carboxymethyl chitosan/LiCl ionic hydrogel was written by Li, Yueqin;Yang, Yong;Liu, Xiaohui;Yang, Yiwen;Wu, Yiyang;Han, Lin;Han, Qiangshan. And the article was included in Colloids and Surfaces, A: Physicochemical and Engineering Aspects in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Wearable smart sensors based on conductive hydrogels have attracted intensive research interest due to their high comfort and accurate detection of physiol. signals. However, most reported hydrogel sensors cannot work independently and require external power. Herein, we report a novel electrochem.-driving self-powered strain sensor based on a multifunctional polyacrylamide/carboxymethyl chitosan/LiCl (PAAM/CMC/LiCl) hydrogel. This hydrogel was facilely prepared by one-step UV-initiated polymerization strategy and integrated high stretchability (a large strain of 640% with a tensile strength of 67 kPa), anti-drying and anti-freezing (-48.27°C) properties, self-healing ability, as well as good elec. conductivity (0.56 S/m). As an effective electrolyte material, the PAAM/CMC/LiCl hydrogel is directly assembled with Zn and MnO₂ electrodes to form a flexible zinc-ion battery (ZIB), from which a decent specific capacity and desirable stable power output are found even under various mech. stimuli. Taking advantage of the high strain sensibility of the PAAM/CMC/LiCl hydrogel, a closed loop consisting of the ZIB and a fixed resistor can realize the function of strain sensing and energy storage capabilities simultaneously. This self-powered sensing system has demonstrated high sensitivity, good stability and strong power-generating performance during the real-time monitoring of human activities, which are highly anticipated in the wearable electronics. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Fabrication of positively charged nanofiltration membrane with uniform charge distribution by reversed interfacial polymerization for Mg²⁺/Li⁺ separation was written by Li, Yunhao;Wang, Shuhao;Wu, Wenyuan;Yu, Haijun;Che, Ruxin;Kang, Guodong;Cao, Yiming. And the article was included in Journal of Membrane Science in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

Nanofiltration is considered a promising technol. for separation of multivalent/monovalent ions such as extracting lithium from Salt Lake brine with high Mg²⁺/Li⁺ ratio. However, the nanofiltration membranes fabricated via conventional interfacial polymerization process generally possess neg. charged surface and have low Mg²⁺/Li⁺ selectivity. Herein, we proposed a new and facile method, i.e., reversed interfacial polymerization (RIP), to prepare nanofiltration membranes with pos. charged surface and uniform charge distribution. The sequence of amine (polyethyleneimine, PEI) and acyl chloride (trimesoyl chloride, TMC) monomers on polysulfone support was reversed compared to the conventional interfacial polymerization (IP) process. Moreover, the solvent of amine monomer was acetone instead of water. The nanofiltration membranes fabricated by this method exhibited higher water flux (from 4.88 to 22.25 Lm^-2h^-1) and MgCl₂ rejection (from 84.36% to 97.71%). Meanwhile, LiCl/MgCl₂ separation factor in single salt solution reached up to 13.93, which was almost quadruple compared to the conventional control membrane. In addition, the developed nanofiltration membrane also exhibited an excellent separation selectivity (S_Li, Mg = 9.22) in mixture system (Mg²⁺/Li⁺ mass ratio of 20), which had good application potential in extracting lithium resources from Salt Lake brine. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

An integrated Si photocathode with lithiation-activated molybdenum oxide nanosheets for efficient ammonia synthesis was written by Mao, Yuyin;Zhang, Haona;Jiang, Weiyi;Zhao, Renna;Liu, Yuanyuan;Wang, Zeyan;Wang, Peng;Zheng, Zhaoke;Song, Kepeng;Wei, Wei;Dai, Ying;He, Jr-Hau;Cheng, Hefeng;Huang, Baibiao. And the article was included in Nano Energy in 2022.Recommanded Product: Lithium chloride The following contents are mentioned in the article:

As an alternative to the conventional industrial Haber-Bosch process, photoelectrochem. (PEC) routes that are powered by renewable solar energy hold great promise for N₂ reduction reaction (NRR) towards NH₃ synthesis at ambient conditions. However, great challenges remain in promoting NH₃ production rate for the PEC NRR devices, especially with the earth-abundant catalysts. Here we report an integrated LixMoO₃/n+np+-Si photocathode could achieve an unprecedented PEC NH₃ yield rate of 8.7 μg cm^-2h^-1, which is among the highest PEC NRR systems ever reported. With an optically and electrocatalytically decoupled configuration, the integrated PEC photocathode could harvest the sunlight sufficiently and simultaneously promote the catalytic kinetics, thus leading to the improved NH3 synthesis. More importantly, such high PEC NRR performance is derived from earth-abundant elements without precious noble metals. Verified by the electrochem. experiments and d. functional theory (DFT) calculations, the lithiation strategy gives rise to dramatic structural distortion accompanying the abundant oxygen vacancies and Mo⁵⁺ ions, which results in faster NRR kinetics and activates inert MoO₃ into efficient LixMoO₃ electrocatalyst towards NH₃ synthesis. This work holds great promise in constructing monolithic PEC device to directly harvest solar light for artificial ammonia photosynthesis. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Recommanded Product: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Self-growing graphite felt/vanadium pentoxide/polyindole ternary composite as binder-free electrode for supercapacitor with 1.8 V operating potential window and excellent electrochemical performance was written by Zhang, Wenjing;You, Mingyu;Yan, Xuehua;Zhang, Mengyang;Huang, Xinpeng;Wu, Sutang;Shahnavaz, Zohreh;Pan, Jianmei;Li, Tie;Zuo, Zhihua. And the article was included in Applied Surface Science in 2022.Application of 7447-41-8 The following contents are mentioned in the article:

Vanadium pentoxide and conducting polymers have promising applications in the field of elec. energy storage devices and combine flexible substance to form binder-free ternary electrodes, which would pave a new way for designing supercapacitors. Herein, graphite felt (GF)@V₂O₅ nanosheets is synthesized by hydrothermal and calcinating treatment, on the surface of which polyindole (PIn) nanospheres are anchored orderly using electrochem. deposition to obtain GF@V₂O₅@PIn ternary electrode material. The pseudocapacitive properties of both V₂O₅ nanosheets and PIn nanospheres are fully demonstrated through the synergistic effect of them, enabling ternary composite GVP-3 to exhibit superior electrochem. properties than two binary materials. The area capacitance of GVP-3 reaches 2254 mF/cm², which is significantly higher than that of GF@V₂O₅ with 1431 mF/cm² and GF@PIn with 647 mF/cm². The flexible quasi-solid-state asym. supercapacitor (FASC) can be operated at the potential window of 1.8 V with a significant energy d. of 1.423 mWh/cm³ (64.404Wh/kg) The excellent elec. capacitance and prominent energy d. of our device endow it with an overall improvement of elec. performance from 25% to 30%, which is compared to present researches. Two devices connected in series are able to make a 3.5 V LED bump light up normally for 2 min, illustrating desirable practicality. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ion partitioning and ion size effects on streaming field and energy conversion efficiency in a soft nanochannel was written by Kundu, Dipankar;Bhattacharyya, S.;Gopmandal, Partha P.. And the article was included in Colloid and Polymer Science in 2022.Recommanded Product: Lithium chloride The following contents are mentioned in the article:

Numerical modeling on streaming field and electroviscous effect in a soft nanochannel is made by considering the finite ion size and ion partitioning effects. The standard electrokinetic model is modified by incorporating the finite ion size effect and the effect of ion partitioning, which arises due to the difference in dielec. permittivity between the electrolyte and wall grafted polyelectrolyte layer (PEL). Such modification in the ion transport equations enable us to consider higher range of wall charge d. as well as higher volumetric charge d. of the PEL. The dielec. permittivity of the PEL may become lower due to the large accumulation of counterions drawn by the PEL immobile charges. The ion steric repulsion is taken into account through the BMCSL (Boublik-Mansoori-Carnahan-Starling-Leland) equation based on the hard-sphere model of ions. This enables to consider different ion sizes, which arise when a mixture of different salts is considered. The governing equations are solved numerically and the streaming field is determined iteratively. We find that the ion steric interactions and ion partitioning effects create a counterion saturation This leads to a reduction in the counterion condensation of the PEL when the PEL and wall are similarly charged, which results in higher streaming field and energy conversion efficiency. The diffuse PEL of pore size in the order of the channel half height creates higher energy efficiency compared to the channel consisting of rigid walls. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Recommanded Product: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chemically-Crosslinked Xylan/Graphene Oxide Composite Hydrogel for Copper Ions Removal was written by Sun, Xiao-Feng;Xie, Yangyang;Shan, Shuang;Li, Wenbo;Sun, Le. And the article was included in Journal of Polymers and the Environment in 2022.Category: chlorides-buliding-blocks The following contents are mentioned in the article:

The chem.-crosslinked composite hydrogel based on acylated xylan and silanized graphene oxide was prepared via free radical polymerization as a novel adsorbent for the removal of Cu²⁺ ions from aqueous solution The chem. structures and morphologies of the silanized graphene oxide and acylated xylan as well as the prepared hydrogels were characterized by FT-IR, XPS, SEM and TEM. The swelling ratios of the prepared hydrogels were determined, and the results showed that the chem.-crosslinked hydrogel was pH-sensitive, and the swelling kinetics of the hydrogels followed Schott second-order kinetic. The optimum pH for the adsorption of Cu²⁺ ions onto the chem.-crosslinked composite hydrogel was found at the value of 5 and the maximum adsorption amount of Cu²⁺ ions was evaluated to be 228 mg/g. The adsorption isotherm accorded with the Freundlich model, and the pseudo-second order kinetic model was suitable to describe the adsorption process. The study of adsorption thermodn. indicated that the adsorption of Cu²⁺ ions onto the chem.-crosslinked composite hydrogel was endothermal and spontaneous, and the adsorption amount rose with an increase in temperature In addition, higher desorption percentages of Cu²⁺ ions from the used hydrogel were also achieved (77.3% after recycling for 6 times). All obtained results indicated that the prepared chem.-crosslinked hydrogel is promising for water treatment and collection of metal ions. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Category: chlorides-buliding-blocks).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Dry chlorination of spent nickel metal hydride battery waste for water leaching of battery metals and rare earth elements was written by Peramaki, Siiri;Tiihonen, Antti;Rajahalme, Joona;Larsson, Sylva;Lahtinen, Elmeri;Niskanen, Joni;Budhathoki, Roshan;Vaisanen, Ari. And the article was included in Journal of Environmental Chemical Engineering in 2022.Reference of 7447-41-8 The following contents are mentioned in the article:

An efficient leaching process was developed for nickel, cobalt, and the rare earth elements (REEs) from spent nickel metal hydride (NiMH) battery waste. The process involves dry chlorination with ammonium chloride in low temperature to produce water-soluble chlorinated compounds, followed by simple water leaching. The factors affecting the conversion and solubilization were studied, including the amount of ammonium chloride, residence time and temperature in dry chlorination, and solid to liquid ratio, time and temperature in water leaching. As a result, the dry chlorination process was found to produce ammonium and chloride containing products, depending on the temperature of the process: ammonium metal chlorides were produced in temperatures of 250-300 °C, while increasing the temperature to 350 °C resulted in formation of metal chlorides. Overall, highest metal recoveries were achieved during 60 min residence time at a temperature of 350 °C, where ammonium is no longer present and ammonium metal chlorides and metal chlorides have formed. Water leaching was found to proceed rapidly, especially for REEs, and yields of 87% for Ni, 98% for Co, 94% for Ce, and 96% for La were attained during 60 min of leaching in room temperature This study introduces a process, which is considered as an environmentally more benign alternative to traditional mineral acid leaching, resulting in high metal leaching efficiencies with neutral leachates, requiring no chem.-intensive neutralization steps in the following processing. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Reference of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Reference of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

A novel, non-GMO surface display in Limosilactobacillus fermentum mediated by cell surface hydrolase without anchor motif was written by Vasquez, Robie;Bagon, Bernadette B.;Song, Ji Hoon;Han, Nam Soo;Kang, Dae-Kyung. And the article was included in BMC Microbiology in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

Recent studies have demonstrated the potential of surface display technol. in therapeutic development and enzyme immobilization. Utilization of lactic acid bacteria in non-GMO surface display applications is advantageous due to its GRAS status. This study aimed to develop a novel, non-GMO cell wall anchoring system for lactic acid bacteria using a cell-surface hydrolase (CshA) from Lactiplantibacillus plantarum SK156 for potential industrial and biomedical applications. Anal. of the CshA revealed that it does not contain any known classical anchor domains. Although CshA lacks a classical anchor domain, it successfully displayed the reporter protein superfolder GFP on the surface of several lactic acid bacteria in host dependent manner. CshA-sfGFP fusion protein was displayed greatest on Limosilactobacillus fermentum SK152. Pretreatment with trichloroacetic acid further enhanced the binding of CshA to Lm. fermentum. The binding conditions of CshA on pretreated Lm. fermentum (NaCl, pH, time, and temperature) were also optimized, resulting in a maximum binding of up to 106 CshA mols. per pretreated Lm. fermentum cell. Finally, this study demonstrated that CshA-decorated pretreated Lm. fermentum cells tolerates gastrointestinal stress, such as low pH and presence of bile acid. To our knowledge, this study is the first to characterize and demonstrate the cell-surface display ability of CshA. The potential application of CshA in non-GMO antigen delivery system and enzyme immobilization remains to be tested. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Experimental analysis of a high-performance open sorption thermal storage system with absorption-crystallization-adsorption processes was written by Mehari, Abel;Wang, R. Z.;Xu, Z. Y.. And the article was included in Energy Conversion and Management in 2022.SDS of cas: 7447-41-8 The following contents are mentioned in the article:

Sorption thermal energy storage is one of the promising solar thermal energy storage considering its long-term storage ability. Since the common sorption thermal storage suffers from low sorption capacity, a high energy storage d. enhancement mechanism is always essential for a cost-effective and compact storage system. With three-phase sorption thermal storage, high energy storage d. from the crystallization sorption process can be achieved. However, such a sorption process brings significant challenges, including crystal blockage issues in absorption system or solution leakage handling problems in adsorption system, which need to be resolved. Here, we showed a high-performance sorption thermal storage that can attain high energy storage d. via a full liquid-to-solid state sorption process. Such a process is achieved by adopting moist air as heat and mass transfer media, which enables liquid absorption, crystallization, and solid adsorption in a simple configuration simultaneously. The lab-scale model achieved high energy storage d. in the range of 333-405 kWh/m3 resulting from the heat of absorption and crystallization of LiCl, which is the record value for liquid absorption systems. The energy storage d. obtained from the dual liquid and solid sorption processes is enhanced by 278% compared with that of the conventional cycle at 70% RH (relative humidity) and temperature lift of 10°C. With simple construction and high energy storage d., the proposed system has great potential in real applications. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8SDS of cas: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).SDS of cas: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Tailoring shape and exposed crystal facet of single-crystal layered-oxide cathode particles for all-solid-state batteries was written by Jeon, Hoyeol;Kwon, Deok-Hwang;Kim, Hyoungchul;Lee, Jong-Ho;Jun, Yongseok;Son, Ji-Won;Park, Sangbaek. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2022.Synthetic Route of ClLi The following contents are mentioned in the article:

The design of composite cathode microstructures is important for improving the performance of all-solid-state batteries (ASSBs). The microstructural properties can provide efficient ionic/electronic percolation, good cathode/solid electrolyte (SE) contact, and minimal void spaces. Although the effects of the size of cathode and SE particles have been extensively investigated, the shape effects of cathode particles remain unexplored. Here, we demonstrate that the shape and exposed crystal facet of cathode particles affect the electrochem. performance of ASSBs using crack-free single-crystalline LiNi₀.₆Co₀.₂Mn₀.₂O₂ (NCM) as the cathode and oxidation-tolerant Li₃YCl₆ as the SE. Systematic studies using five particle shapes (octahedra, plates, rods, spherical single crystals, and spherical polycrystals) reveal the important effects of the shape and exposed facets on the solid-solid contact as well as Li⁺ ion diffusion in composite cathodes. Single-crystalline octahedral NCM particles have a higher rate capability than that of their counterparts because their wide planar surface promoted plane-to-plane contact with the SE and the (0 1 2) facets provided straightforward 3D Li⁺ transfer channels between the surface and the center. These results suggest that single-crystal NCM cathodes with advanced shapes and exposed facets can enable the fabrication of ASSBs with superior performance. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Synthetic Route of ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Synthetic Route of ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics