Category: 7447-41-8

Highly Porous Self-Supporting Graphene Oxide-Based Membranes for the Selective Separation of Lithium Ions was written by Cheng, Mengmeng;Chu, Tianfei;Yin, Xiaolu;Hou, Shifeng;Yang, Yanzhao. And the article was included in ACS Sustainable Chemistry & Engineering in 2022.Related Products of 7447-41-8 The following contents are mentioned in the article:

Facilitating the accurate recognition of lithium ions (Li⁺) by filtration membranes is of great significance for the efficient and selective separation of Li⁺ from saline lake brine and seawater. Herein, a highly porous self-supporting graphene oxide-based (GCS) membrane modified by single-walled carbon nanotubes (SWCNTs) and 4-aminobenzo-12-crown-4 (AB12C4) was fabricated via a facile and versatile vacuum filtration method. The highly porous structure constructed with polystyrene microspheres as a self-sacrificial template could provide a larger contact area at the solid-liquid interface. Moreover, the addition of elec. SWCNTs endows the GCS membrane with a tunable adsorption behavior by an external elec. field. Meanwhile, the decoration of AB12C4 on the multilayered GCS membrane realizes a specific recognition of Li⁺ with an excellent adsorption capacity of 37.0 mg g^-1, exhibiting considerably high separation factors against Na⁺ (18.97), K⁺ (26.19), Mg²⁺ (16.67), and Ca²⁺ (19.64). According to the d. functional theory calculations, the adsorption of GCS membrane for Li⁺ is more thermodynamically favorable than that of the contrast ions. This work demonstrates an effective approach with the convenient vacuum filtration technol. for the selective adsorption of Li⁺, which could alleviate the shortage of lithium resources. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Related Products of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Related Products of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

In-situ Raman investigation and application of phenazine-based organic electrode in aqueous proton batteries was written by Shi, Minjie;He, Jing;Zhao, Yue;Zhao, Liping;Dai, Kun;Yan, Chao. And the article was included in Materials & Design in 2022.Safety of Lithium chloride The following contents are mentioned in the article:

Aqueous proton batteries (APBs) have aroused attention because of the proton as charge carrier with smaller ionic size and faster kinetics when compared to the metallic ions in aqueous solutions Although phenazine-based organic compounds with available redox-active sites are considered as promising organic electrode materials, the comprehensive study of their proton-storage behaviors and APB applications is still lacking so far. Herein, a rod-like diquinoxalino-phenazine (DPZ) organic compound is designed and synthesized via a facile dehydration approach. In-situ Raman investigation and theor. calculation are conducted to probe into the proton redox process of DPZ organic electrode for the first time. It is demonstrated that three C=N electroactive regions in each DPZ mol. unit could be simultaneously coordinated with two protons and the redox reaction between C=N and C-N bonds is highly reversible upon proton insertion/extraction As expected, the DPZ organic electrode delivers a large proton-storage capacity of ∼ 218 mAh/g and long-term cycle performance without obvious dissoly. in acidic aqueous electrolyte. For real applications, soft-package and wire-shaped APBs based on such DPZ organic electrode are constructed, and they both achieve outstanding electrochem. characteristics, revealing their great potential applications in low-cost, high-safety, and high-performance energy technologies and portable/wearable electronics. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Safety of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Safety of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Design of metal salt/amide-based deep eutectic monomers toward sustainable production of ion-conductive polymers by radical polymerization was written by Tanaka, Y.;Ajino, K.;Ogawa, H.;Mori, H.. And the article was included in Materials Today Chemistry in 2022.Recommanded Product: 7447-41-8 The following contents are mentioned in the article:

We herein describe a solvent-free synthetic route to ion-conductive polymers from metal salt/amide-based deep eutectic monomers (DEMs), which were prepared by mixing amido-containing solid monomers with metal salts under suitable feed ratios. N-Iso-Pr acrylamide (NIPAM) and N-vinylacetamide (NVA) were selected as vinyl monomers bearing an amido functional group that can act as a hydrogen bond donor. Lithium chloride (LiCl), zinc chloride (ZnCl2), and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), which can act as hydrogen bond acceptors, were employed as metal salts. The simple mixing of NIPAM with solid LiTFSI in a 5:1 M ratio at 60°C for 0.5 h afforded liquid NIPAM/0.2LiTFSI, which exhibited the characteristic eutectic effect. By mixing NIPMA with ZnCl₂ in a suitable feed ratio, NIPAM/0.25ZnCl₂ was obtained as a white turbid liquid at room temperature Similarly, NVA/0.2LiCl and NVA/0.2LiTFSI were obtained as transparent liquids from solid NVA. In addition, the thermally-induced free-radical polymerization of the metal salt/amide-based DEMs in the bulk and in solution resulted in the formation of the corresponding polymers. Poly(NVA/0.2LiTFSI) exhibited the highest ionic conductivity of 2.83 x 10-6 S/cm at 50°C. These results reveal that the DEMs developed in this study can provide a green and sustainable process for the radically-induced production of novel ion-conductive polymers in air. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Recommanded Product: 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Fabrication of thin film composite polyamide membrane for water purification via inkjet printing of aqueous and solvent inks was written by Park, Myoung Jun;Wang, Chen;Gonzales, Ralph Rolly;Phuntsho, Sherub;Matsuyama, Hideto;Drioli, Enrico;Shon, Ho Kyong. And the article was included in Desalination in 2022.Related Products of 7447-41-8 The following contents are mentioned in the article:

Thin film composite (TFC) polyamide (PA) membranes are typically prepared using the interfacial polymerization (IP) method, which synthesizes the PA layer by soaking in aqueous diamine and organic acyl chloride solutions and allowing the occurrence of amidation. The conventional IP process has been used over several decades in the industrial production of TFC membranes for water purification and excess amounts of monomer solutions are used for PA thin film layer synthesis, generating a lot of chem. wastes. In this work, we first demonstrated the TFC PA membrane fabrication using simple inkjet printing of aqueous and organic inks to effectively prepare a PA layer with no chem. wastes. The organic acyl chloride ink was newly formulated by the combination of dodecane and toluene solvents to allow printability. Precise and uniform depositions of monomer inks via the inkjet printing approach were able to coat a dense and defect-free PA film onto the support membrane using only small volumes of chems. After multiple printing numbers of inks, the PA layer was optimized with two printing cycles (30.17 mL m^-2) and three printing cycles (8.36 mL m^-2) of diamine and triacyl chloride inks, resp., followed by heat treatment. The inkjet-printed TFC-M2T3-15 membrane exhibited a high salt rejection (95.33%) which showed higher performance compared to that of the conventional IP-prepared TFC membrane (89.64%). This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Related Products of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Related Products of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Development and enhancement strategy of MoSe₂ based anodes for aqueous Li-ion battery was written by Ji, Xu;Li, Man;Guo, Jianjun;Pan, Yunying;Meng, Lijun;Cheng, Shuang. And the article was included in Journal of Science: Advanced Materials and Devices in 2022.Application In Synthesis of Lithium chloride The following contents are mentioned in the article:

Durability and capacity of electrode materials, especially the anodes, are the main challenges for aqueous Li-ion batteries. In work here, MoSe₂ micron flowers have been synthesized and investigated as anodes for Li⁺ storage in LiCl aqueous-based electrolytes. In the LiCl solution, the working potential of the MoSe₂ anode can reach -1.0 V (vs Ag/AgCl). Yet, its reversible capacity is only ∼14 mAh g^-1 (50 C g^-1), owing to the absence of Faradaic reactions and the fast deformation of MoSe₂. After gelation of the LiCl solution using poly vinyl alc. (PVA), the activity of water is largely inhibited, and the operating potential is broadened to -1.2 V. In this gel system, the Faradaic reaction of the MoSe₂ anode is triggered, and hence its capacity is largely enhanced. With a suitable amount of PVA (LiCl/PVA-20), the MoSe₂ electrode can deliver reversible capacities of high as 157 mAh g^-1 at 1 A g^-1, and 139 mAh g^-1 at 2 A g^-1, and still high as 100 mAh g^-1 after 50 cycles, indicating relative good stability. Using com. LiMn₂O₄ as cathode, a full aqueous Li-ion battery was assembled, and a high discharge voltage of ∼1.8 V can be achieved. It is found that not only the activity of water but also the morphol. change of the MoSe₂ during cycling is inhibited in the gel electrolyte. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Application In Synthesis of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Application In Synthesis of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Phase separation induced binary core-shell alloy nanoparticles embedded in carbon sheets for magnesium storage was written by Chen, Chen;Huang, Huawen;Hu, Renzong;Bi, Ran;Zhang, Lei. And the article was included in ACS Applied Materials & Interfaces in 2022.Recommanded Product: Lithium chloride The following contents are mentioned in the article:

Magnesium-ion batteries (MIBs) have aroused widespread interest in large-scale applications due to their low cost, high volumetric capacity, and safety. However, magnesium (Mg) metals are incompatible with conventional electrolytes, making it difficult to plate and strip reversibly. Therefore, developing novel Mg²⁺ host anodes remains a huge challenge. Herein, we present a rational design and fabrication of binary Bi@Sn alloy nanoparticles embedded in carbon sheets (Bi@Sn-C) as a superior anode for MIBs employing phase separation during the annealing of bimetallic MOFs. The Bi@Sn-C simultaneously integrates the nanostructure design and multi-element coordination strategies which is favorable to improve the overall structural stability and Mg²⁺ diffusion kinetics. Benefiting from the aforementioned features, the Bi@Sn-C electrodes deliver good cycling stability of 214 mA h g^-1 at 100 mA g^-1 after 100 cycles and rate capability with 200 mA h g^-1 at 500 mA g^-1. And when using all-Ph complex with lithium chloride (LiCl-APC) dual-salt electrolyte, the electrochem. performance of Bi@Sn-C is further optimized and shows enhanced rate performance (238 mA h g^-1 at 500 mA g^-1) and reversible capacity (308 mA h g^-1 at 100 mA g^-1 after 100 cycles). This novel strategy holds great promise for designing efficient alloy electrode materials for MIBs. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Recommanded Product: Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Multifunctional graphene heterogeneous nanochannel with voltage-tunable ion selectivity was written by Su, Shihao;Zhang, Yifan;Peng, Shengyuan;Guo, Linxin;Liu, Yong;Fu, Engang;Yao, Huijun;Du, Jinlong;Du, Guanghua;Xue, Jianming. And the article was included in Nature Communications in 2022.COA of Formula: ClLi The following contents are mentioned in the article:

Ion-selective nanoporous two-dimensional (2D) materials have shown extraordinary potential in energy conversion, ion separation, and nanofluidic devices; however, different applications require diverse nanochannel devices with different ion selectivity, which is limited by sample preparation and exptl. techniques. Herein, we develop a heterogeneous graphene-based polyethylene terephthalate nanochannel (GPETNC) with controllable ion sieving to overcome those difficulties. Simply by adjusting the applied voltage, ion selectivity among K⁺, Na⁺, Li⁺, Ca²⁺, and Mg²⁺ of the GPETNC can be immediately tuned. At neg. voltages, the GPETNC serves as a mono/divalent ion selective device by impeding most divalent cations to transport through; at pos. voltages, it mimics a biol. K⁺ nanochannel, which conducts K⁺ much more rapidly than the other ions with K⁺/ions selectivity up to about 4.6. Besides, the GPETNC also exhibits the promise as a cation-responsive nanofluidic diode with the ability to rectify ion currents. Theor. calculations indicate that the voltage-dependent ion enrichment/depletion inside the GPETNC affects the effective surface charge d. of the utilized graphene subnanopores and thus leads to the elec. controllable ion sieving. This work provides ways to develop heterogeneous nanochannels with tunable ion selectivity toward broad applications. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8COA of Formula: ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.COA of Formula: ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

High performance liquid chromatography-based method to analyze activity of GABA transporters in central nervous system was written by Rogerio da Silva Moraes, Edinaldo;Santos-Silva, Mateus;Grisolia, Alan Araujo;Braga, Danielle Valente;Reis Leao, Luana Ketlen;Bahia, Carlomagno Pacheco;Soares de Moraes, Suellen Alessandra;Passos, Adelaide Fonseca;de Jesus Oliveira Batista, Evander;Herculano, Anderson Manoel;Matos Oliveira, Karen Renata Herculano. And the article was included in Neurochemistry International in 2022.Quality Control of Lithium chloride The following contents are mentioned in the article:

The GATs are the membrane proteins responsible for the uptake of GABA in the central nervous system. Alterations in GAT activity are implicated in several neurol. diseases, including retinopathies. The present study describes an alternative method to determine GAT activity in tissue preparations of the central nervous system, using high performance liquid chromatog. (HPLC) with fluorescence detection. The GABA concentration in the medium was determined using the o-phthaldehyde (OPA)-derivation protocol validated by the Brazilian Health Regulatory Agency (ANVISA) and the United States Food and Drug Administration (US-FDA). The GAT activity in the retinal preparations was determined through the evaluation of the GABA uptake, which was measured by assessing the difference between the initial and final concentrations of GABA in the incubation medium. The evaluation of the GAT kinetics returned values of Km = 382.5 ± 32.2μM and Vmax = 34 nmol/mg of protein. The data also demonstrated that the GABA uptake was predominantly Na+- and temperature-dependent, and was also inhibited by incubation with nipecotic acid, a substrate of GABA transporters. Taken together, these findings confirm that our approach provided a specific measure of GAT activity in retinal tissue. The data presented here thus validate, for the first time, an alternative, simple and sensitive method for the evaluation of GAT activity using high performance chromatog. on preparations of the central nervous system. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Quality Control of Lithium chloride).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Quality Control of Lithium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

An integrated smart thermo-chemical energy network was written by Giampieri, A.;Roy, S.;Shivaprasad, K. V.;Smallbone, A. J.;Roskilly, A. P.. And the article was included in Renewable & Sustainable Energy Reviews in 2022.Reference of 7447-41-8 The following contents are mentioned in the article:

Managing the intermittency of renewable sources together with transient (hourly to daily to seasonal) energy demands is one of the principal challenges of delivering a net-zero energy system. Smart multifunctional thermo-chem. energy networks represent an alternative energy network and storage system, a solution based on the distribution of energy via thermo-chem. material rather than thermal energy, gas, fuels or electricity- an option that has scope for integrated short- and long-term energy storage. This is the first research work to realize such a system and demonstrate how it might operate using smart control strategies and how thermo-chem. fluids (TCFs) can be used as a medium for timely energy storage and distribution. The exptl. study also describes the effect of steady and variable heat sources on TCF regeneration performance and estimates the potential of thermo-chem. energy networks, which would be particularly beneficial in buildings with high energy consumption for humidity control. This research proves the practicality of the design idea for such a network, which would be governed by centralised control, regenerated by steady or transient heat loads and capable of supplying a variety of demands in an exptl. setting. The energy and economic potential of the network were also assessed, identifying temperature and humidity control application scenarios with energy savings of more than 60% compared to conventional operation and payback periods of 6.6-9.7 years. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Reference of 7447-41-8).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Reference of 7447-41-8

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Zinc oxide nanoparticles inhibit osteosarcoma metastasis by downregulating β-catenin via HIF-1α/BNIP3/LC3B-mediated mitophagy pathway was written by He, Guanping;Nie, Jing-Jun;Liu, Xiao;Ding, Zihao;Luo, Peng;Liu, Yu;Zhang, Bo-Wen;Wang, Renxian;Liu, Xiaoguang;Hai, Yong;Chen, Da-Fu. And the article was included in Bioactive Materials in 2023.Formula: ClLi The following contents are mentioned in the article:

Osteosarcoma (OS) therapy faces many challenges, especially the poor survival rate once metastasis occurs. Therefore, it is crucial to explore new OS treatment strategies that can efficiently inhibit OS metastasis. Bioactive nanoparticles such as zinc oxide nanoparticles (ZnO NPs) can efficiently inhibit OS growth, however, the effect and mechanisms of them on tumor metastasis are still not clear. In this study, we firstly prepared well-dispersed ZnO NPs and proved that ZnO NPs can inhibit OS metastasis-related malignant behaviors including migration, invasion, and epithelial-mesenchymal transition (EMT). RNA-Seqs found that differentially expressed genes (DEGs) in ZnO NP-treated OS cells were enriched in wingless/integrated (Wnt) and hypoxia-inducible factor-1 (HIF-1) signaling pathway. We further proved that Zn2+ released from ZnO NPs induced downregulation of β-catenin expression via HIF-1α/BNIP3/LC3B-mediated mitophagy pathway. ZnO NPs combined with ICG-001, a β-catenin inhibitor, showed a synergistic inhibitory effect on OS lung metastasis and a longer survival time. In addition, tissue microarray (TMA) of OS patients also detected much higher β-catenin expression which indicated the role of β-catenin in OS development. In summary, our current study not only proved that ZnO NPs can inhibit OS metastasis by degrading β-catenin in HIF-1α/BNIP3/LC3B-mediated mitophagy pathway, but also provided a far-reaching potential of ZnO NPs in clin. OS treatment with metastasis. This study involved multiple reactions and reactants, such as Lithium chloride (cas: 7447-41-8Formula: ClLi).

Lithium chloride (cas: 7447-41-8) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Formula: ClLi

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics