Category: 5137-55-3

Recovery of Cobalt, Nickel and Copper Compounds from UHT Processed Spent Lithium-ion Batteries by Hydrometallurgical Process was written by Tran, Thanh Tuan;Moon, Hyun Seung;Lee, Man Seung. And the article was included in Mineral Processing and Extractive Metallurgy Review in 2022.HPLC of Formula: 5137-55-3 The following contents are mentioned in the article:

Lithium-ion batteries (LIBs) are employed in various electronic devices and industries. The recovery of valuable metals from spent LIBs has attracted much interest due to potential environmental issues and economic values. Metallic alloys can be obtained from the UHT process of spent LIBs. In this study, a hydrometallurgical process was developed for the recovery of metal compounds from synthetic metallic alloys containing Co, Ni, and Cu. This process consisted of leaching, solvent extraction, stripping and precipitation First, the metallic mixtures were completely leached by the mixture of 2.0 moL·L^-1 HCl and 10%(volume/volume) H₂O₂ solutions at 60°C. Metal ions in the leachate were sequentially separated by solvent extraction with 0.7 moL·L^-1 Cyanex301 and 1.0 moL·L^-1 Aliquat 336 for Cu(II) and 1.0 moL·L^-1 ALi-SCN for Co(II), whereas Ni(II) was remained in the final raffinate. The compounds of Cu(II) and Co(II) were recovered from the resp. loaded organics by precipitation stripping method, while Ni(II) compounds were recovered by precipitation from the final raffinate without changing its acidity. Mass balance of the whole process indicated that the recovery percentage of metal compounds such as CuC₂O₄, CoCO₃, and NiC₂O₄ · 2 H2O was 98.6, 99.4, 99.8% from the leaching solution and the purity of the compounds was higher than 99.9%. A process was proposed for the recovery of pure metal compounds from spent LIBs. The advantages of this process are the possibility that metal compounds with high purity can effectively be synthesized and the aqueous raffinates and the stripped organic solutions after each step can be recycled. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3HPLC of Formula: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.HPLC of Formula: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Combining of modified QuEChERS and dispersive liquid-liquid microextraction as an efficient sample preparation method for extraction of acetamiprid and imidacloprid from pistachio samples was written by Khanehzar, Hasan;Faraji, Mohammad;Nezhadali, Azizollah;Yamini, Yadollah. And the article was included in Journal of the Iranian Chemical Society in 2021.Recommanded Product: 5137-55-3 The following contents are mentioned in the article:

In this research, for the first time, the QuEChERS was combined with the dispersive liquid-liquid microextraction based on deep eutectic solvent (QuEChERS-DES-DLLME). The method was developed for efficient extraction, clean-up and preconcentration of acetamiprid (ACE) and imidacloprid (IMI), two commonly used pesticides, from pistachio samples before their determination by HPLC-UV. The pesticides were firstly extracted from pistachio samples and cleaned-up by QuEChERS, and then their supernatant was used as a dispersant in following DLLME in order to further purification and preconcentration The extraction solvent used in DLLME was based on deep eutectic solvents (DESs). Preparation of hydrophobic DES was done by mixing amyl alc. as hydrogen bond donor and trioctylmethylammonium chloride (TOMAC) as hydrogen bond acceptor. Different parameters that affect the efficiency of the two steps were evaluated and optimized. Under optimal conditions, the limit of detections was 1.5 and 3.0μg kg-1 for ACE and IMI and the limit of quantification was 1.5 and 4.5μg kg-1 for ACE and IMI, resp. Calibration curves were linear in the range 5.0-500μg kg-1 with correlation coefficients higher than 0.99. Preconcentration factor for ACE and IMI was 16 and 13, resp. The intraday and interday precisions at concentration levels of 10 and 100μg kg-1 were less than 7.0%. Finally, applicability of the suggested method was investigated through anal. of the analytes in some pistachio samples, and the obtained relative recoveries (95.6-99.4%) were acceptable. The good sensitivity and suitable purification in the anal. of the pistachio samples, as a complex food matrix, are obtained using the proposed method by combining the advantages of QuEChERS and DLLME. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Recommanded Product: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

High-Crystallinity Covalent Organic Framework Synthesized in Deep Eutectic Solvent: Potentially Effective Adsorbents Alternative to Macroporous Resin for Flavonoids was written by Gao, Manjie;Wang, Dandan;Deng, Linlin;Liu, Shaochi;Zhang, Kailian;Quan, Tian;Yang, Lijuan;Kang, Xun;Xia, Zhining;Gao, Die. And the article was included in Chemistry of Materials in 2021.Safety of N-Methyl-N,N-dioctyloctan-1-aminium chloride The following contents are mentioned in the article:

A critical challenge in the enrichment of active ingredients in natural medicines is the design of adsorbents with high selectivity and adsorption capacity. Covalent organic frameworks (COFs), which have adjustable pores and high sp. surface areas, could be effective as adsorbents for active ingredients. This study used an environmentally friendly deep eutectic solvent (DES) instead of organic solvents as the reaction solvent, and high-crystallinity COF-DES was successfully prepared The COF-DES fabricated using 1,3,5-tris(4-aminophenyl)benzene and 2,5-dihydroxyterephthalaldehyde as building blocks showed good dispersibility, large surface area (444.56 m²·g^-1), and suitable pore size (25.9 Å). Owing to its unique structure and functional group properties, COF-DES can prevent interferences from other compounds such as alkaloids, resulting in outstanding selective adsorption performance for flavonoids. Furthermore, under optimized adsorption conditions, the adsorption effects of the COF-DES on flavonoids were much better than those of the effects of macroporous resins, indicating the potential of the COF-DES as a selective adsorbent for flavonoids. Finally, a flavonoid-possessing rich natural medicine, Abelmoschus manihot (Linn.) Medicus flower, was used as a sample to study the application potential of the COF-DES. The results showed that the COF-DES had good adsorption and selection capability for flavonoids in actual samples. Moreover, compared with solid-phase extraction (SPE) columns based on macroporous resins, a COF-DES based SPE column showed superior adsorption performance for an actual complex sample, indicating the potential to COF-DES as an effective adsorbent alternative to macroporous resins. Addnl., the COF-DES had great com. value as an adsorbent for SPE flavonoid columns. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Safety of N-Methyl-N,N-dioctyloctan-1-aminium chloride).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Safety of N-Methyl-N,N-dioctyloctan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Separation of Re(VII) from Mo(VI) using biomaterial-based ionic gel adsorbents: Extractive adsorption enrichment of Re and surface blocking of Mo was written by Li, Wenjing;Dong, Xuelin;Zhu, Lihua;Tang, Heqing. And the article was included in Chemical Engineering Journal (Amsterdam, Netherlands) in 2020.Formula: C25H54ClN The following contents are mentioned in the article:

It is urgently needed to develop highly efficient and selective adsorbents for enrichment and separation of Re(VII) from Mo(VI) to obtain metallic rhenium. By tuning cross-link of chitosan, ionic gel capsules (CSN) were prepared, which had a core-shell structure and wrapped N263 (Me trioctyl ammonium chloride) as an extractant. After being characterized, the CSN capsules were used as a green adsorbent for separation of ReO^–₄ from MoO^2-₄. It was found that the gel yielded good adsorption capacities for Re(VII) in a wide pH range from pH 2 to 12. The adsorption of Re(VII) on the gel followed the Langmuir model, exhibiting a maximum adsorption capacity of 222 mg g^-1 for Re. The adsorbent showed good adsorption capacities for Mo(VI) at pH < 2, but little at pH > 3.5. Therefore, the enrichment and separation of Re(VII) from Mo(VI) could be easily achieved by using the gel adsorbent in a wide pH range from 4 to 12, showing a separation factor β_Re/Mo with values of 10³-5 × 10⁴. A mechanism was proposed for the selective adsorption of Re(VII). The extractant N263 wrapped in the capsule core provides excellent extractive adsorption ability for Re(VII) through ion association extraction, generating ion association complex R₄N⁺•ReO^–₄ in the adsorbent. The gel shell was composed of cross-linked chitosan induced by sodium tripolyphosphate, and functioned as a blocking layer for the adsorption of Mo(VI), being possibly related to a special interaction between Mo and P as observed in the formation of phosphorus molybdenum heteropolyacid and/or the crosslinking with Mo and chitosan. The CSN gel was successfully applied to sep. ReO^–₄ from a practical alk. solution This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Formula: C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Formula: C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Guest Transition Metals in Host Inorganic Nanocapsules: Single Sites, Discrete Electron Transfer, and Atomic Scale Structure was written by Haviv, Eynat;Chen, Bo;Carmieli, Raanan;Houben, Lothar;Cohen, Hagai;Leitus, Gregory;Avram, Liat;Neumann, Ronny. And the article was included in Journal of the American Chemical Society in 2020.Synthetic Route of C25H54ClN The following contents are mentioned in the article:

Host-guest solution chem. with a wide range of organic hosts is an important and established research area, while the use of inorganic hosts is a more nascent area of research. In the recent past in a few cases, Keplerate-type molybdenum oxide-based porous, spherical clusters, shorthand notation {Mo₁₃₂}, have been used as hosts for organic guests. Here, authors demonstrate the synthetically controlled encapsulation of first-row transition metals (M = Mn, Fe, and Co) within a Keplerate cluster that was lined on the inner core with phosphate anions, {Mo₁₃₂PO₄}. The resulting M²⁺_x⊂{Mo₁₃₂PO₄} host-guest complexes were characterized by ³¹P NMR and ENDOR spectroscopy that substantiated the encapsulation of the first-row transition metal guest. Magnetic susceptibility measurements showed that the encapsulation of up to 10 equiv showed little magnetic interaction between the encapsulated metals, which indicated that each guest atom occupied a single site. Visualization of the capsules and differentiation of the Mo atoms of the capsule framework and the encapsulated transition metal were possible using spherical and chromatic double aberration-corrected electron microscopy combined with energy-filtered TEM (EFTEM) elemental maps. In addition, use of visible light-induced XPS for chem. resolved elec. measurements (CREM) confirmed the successful encapsulation of M within {Mo₁₃₂PO₄} and furthermore showed photoinduced electron transfer from M to Mo. In the future, such targeted electron transfer between host {Mo₁₃₂} and a transition metal guest could be used as photoinitiated switches using inorganic compounds and for single site photocatalytic reactions in confined space. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Synthetic Route of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Synthetic Route of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The effect of solvent on the binding of anions and ion-pairs with a neutral [2]rotaxane was written by Molina-Muriel, Ricardo;Romero, J. Ramon;Li, Yifan;Aragay, Gemma;Ballester, Pablo. And the article was included in Organic & Biomolecular Chemistry in 2021.Safety of N-Methyl-N,N-dioctyloctan-1-aminium chloride The following contents are mentioned in the article:

In this work we report the binding properties of rotaxane 1 towards a series of tetraalkylammonium salts of Cl^–, OCN^– and NO₃^– anions in acetone and a CHCl₃/MeOH solvent mixture We used ¹H NMR titrations and Isothermal Titration Calorimetry (ITC) experiments to monitor and analyze the binding processes. We compared the obtained results with those previously described by us in chloroform solution In acetone solution, the determined binding constants for the 1:1 complexes were 1 to 3 orders of magnitude larger than those measured in chloroform, a less competitive solvent for hydrogen-bonding. The thermodn. signatures of the binding processes in acetone, determined by ITC experiments, revealed favorable enthalpic and entropic contributions having similar magnitudes. These results suggested that solvation/desolvation processes in acetone play a significant role in the binding processes. Conversely, the addition of just 5% of methanol to chloroform solutions of 1 significantly reduces the magnitude of the binding constants of all studied ion-pairs. In this solvent mixture, the entropy term is also favorable but it does not compensate the experienced loss of binding enthalpy. Moreover, in acetone solution, the addition of the Cl^– and OCN^– tetraalkylammonium salts in excess (more than 1 equivalent) led to the immediate appearance of 2:1 complexes. Related high-stoichiometry complexes are not observed in the solvent mixture (CHCl₃/MeOH 95/5). In chloroform, a large excess of the salt (> 6 equivalent) is required for its formation. From the anal. of the obtained binding data we infer that, in acetone and in CHCl₃/MeOH mixture, the formed complexes are mainly anionic. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Safety of N-Methyl-N,N-dioctyloctan-1-aminium chloride).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Safety of N-Methyl-N,N-dioctyloctan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Tunable Nitrogen Defects on Graphitic Carbon Nitride toward the Visible-Light-Induced Reversible-Deactivation Radical Polymerization was written by Han, Shiwei;Qiu, Teng;Xiong, Chongwen;Li, Xiaoyu;Guo, Longhai. And the article was included in Macromolecules (Washington, DC, United States) in 2022.Electric Literature of C25H54ClN The following contents are mentioned in the article:

Introducing nitrogen defects has been confirmed to improve the photoactivity of graphitic carbon nitride, but this strategy is far from being employed in the field of photo-polymerization Here, the nitrogen-deficient graphitic carbon nitride (g-C₃N_x) is proposed as an effective photocatalyst for photoinduced electron/energy transfer reversible addition-fragmentation chain transfer (PET-RAFT) polymerization under visible light. The g-C₃N_x was prepared through the thermal polymerization of melamine with the pre-treatment by using the different kinds of preparation tailoring agents (PTAs). It has been revealed that both the amount and the type of the PTA have a profound impact on the reaction rate and the induction period of this visible-light-driven PET-RAFT polymerization, attributed to modulating the optical absorption boundary and the carrier transport efficiency of g-C₃N_x by the introduced defects of nitrogen vacancies and cyano groups. Under the optimal condition with 0.5 g of NaOH being employed as the PTA, a monomer conversion higher than 90% was obtained in the PET-RAFT polymerization, almost doubled in comparison to the conversion catalyzed by pristine g-C₃N₄ under the parallel 10 h of blue light (λ_max = 465 nm) irradiation, and the induction period was also dramatically shortened. The as-synthesized polymers exhibit a kinetically controlled mol. weight with low dispersity (PDI < 1.2). Moreover, high end-group fidelity, universal monomer/chain transfer agent adaptation, and reliable reused capability are shown on the 2D sheets of g-C₃N_x being applied as the potential semiconductor catalyst for PET-RAFT polymerization under visible light. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Electric Literature of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Electric Literature of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Au₃Pd₁ Nanodendrites with Hyperbranched Architectures: Green Synthesis at Room Temperature and Highly Selective Hydrogenation for 4-Nitrophenylacetylene was written by Yao, Kaisheng;Li, Tianjin;Zhao, Chenchen;Lu, Weiwei;Zhao, Shuang;Wang, Jianji. And the article was included in ACS Sustainable Chemistry & Engineering in 2020.Recommanded Product: N-Methyl-N,N-dioctyloctan-1-aminium chloride The following contents are mentioned in the article:

Conceiving a simple, green, and mild one-pot route to grow and construct anisotropic bimetallic 3D architectures with multilevel structures and promising functions is highly desirable and tech. important in many applications. Herein, a facile ionic liquid-modulated strategy is presented for the preparation of hyperbranched Au₃Pd₁ bimetallic nanodendrites (NDs) in aqueous solution at room temperature To implement this protocol, HAuCl₄ and Na₂PdCl₄ are used as precursors and ascorbic acid as a reductant, and a common ionic liquid 1-butyl-3-methylimidazolium chloride ([C₄mim]Cl) is utilized to direct the anisotropic growth of 3D Au₃Pd₁ NDs, which exhibits an eco-friendly feature. It is shown that the alloy Au₃Pd₁ NDs possess multilevel architectures, i.e., primary 3D large flowers (with diameters of about 2.5-4.0μm), secondary 2D leaves, tertiary sym. branches, and quaternary sym. petals. A series of factors influencing morphologies and properties of the products are investigated, and the results indicate that both [C₄mim]Cl and Au/Pd at. ratios are crucial to the formation of 3D Au₃Pd₁ NDs. Owing to the well-defined morphol. and probable electronic effects between Au and Pd, the 3D Au₃Pd₁ NDs display high catalytic selectivity and good durability toward stepwise hydrogenation of 4-nitrophenylacetylene with a 100% conversion and 99.5% selectivity to 4-nitrostyrene in the first step and then 100% conversion from 4-nitrostyrene and 96.7% selectivity to 4-nitroethylbenzene in the second step. It is believed that the well-defined 3D Au₃Pd₁ NDs would also exhibit promising applications in other catalysis and eletrocatalysis applications. The [C₄mim]Cl-modulated 3D Au₃Pd₁ nanodendrites exhibited high selectivity in stepwise hydrogenation of 4-nitrophenylacetylene to 4-nitrostyrene and then to 4-nitroethylbenzene. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Recommanded Product: N-Methyl-N,N-dioctyloctan-1-aminium chloride).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: N-Methyl-N,N-dioctyloctan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Treatment of cyanide-bearing wastewater by the N263-TBP synergistic extraction system was written by Song, Yonghui;Li, Yifan;He, Xihong;Zeng, Xinhui;Zhou, Min;Liu, Gang;Zhou, Jiameng. And the article was included in Chemosphere in 2022.Application of 5137-55-3 The following contents are mentioned in the article:

In this study, a trioctylmethylammonium chloride (N263)- tri-Bu phosphate (TBP)-n-octanol-sulfonated kerosene (N263-T) synergistic extraction system and an N263-n-octanol-sulfonated kerosene (N263-O) system were used to treat cyanide (CN)-bearing wastewater. The extraction saturation capacity of the two systems was measured. The influences of the initial pH and phase ratio (O/A) of the two systems on extraction were compared and analyzed. Fourier transform IR (FTIR) spectroscopy, UV-visible (UV-Vis) spectroscopy, and slope methods were used to analyze the characteristic functional groups in the loaded organic phase, the compositions of the extracted compounds in the extraction reactions and the reaction mechanism. The results indicated that the saturated extraction capacity of the N263-T system, which was much larger than that of the N263-O system, for metal CN complex ions was 4354.31 mg/L. In addition, the N263-T system operated over a wider pH range. The extraction rates of copper (Cu), zinc (Zn), and iron (Fe) ions at pH 14 were 97.4%, 99.1%, and 87.2%, resp. There was a strong compatibilization effect of TBP on the extraction system. The extraction efficiency of the N263-T system for metal CN complex ions was higher than that of the N263-O system when O/A = 0.4. The saturated loaded N263-T and N263-O systems were stripped by 1 mol/L NaOH +2 mol/L NaSCN solution at O/A = 3. The metal ion concentration in the stripping solution could be enriched to 11996.6 and 8913.3 mg/L for the N263-T and N263-O systems, resp. During the extraction process, the binding ratios of N263 cations to Cu(CN)2-3, Zn(CN)2-4, and Fe(CN)3-6 were 2:1, 2:1, and 3:1, resp. The binding ratios of TBP to Cu(CN)2-3, Zn(CN)2-4, and Fe(CN)3-6 in wastewater were 3:1, 4:1, and 6:1, resp. The P=O group in TBP was linked to the CN group of the metal CN complex ion by hydrogen bonds using the water mol. as a bridge to form a supramol. anion group, which entered into the organic phase and combined with the N263 cation under the action of ion association This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Application of 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application of 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Design and evaluation of polarity controlled and recyclable deep eutectic solvent based biphasic system for the polarity driven extraction and separation of compounds was written by Tang, Weiyang;Row, Kyung Ho. And the article was included in Journal of Cleaner Production in 2020.Computed Properties of C25H54ClN The following contents are mentioned in the article:

Deep eutectic solvent (DES) based extraction methods have promising applications in extracting and separating compounds from plants. In this study, a polarity controlled biphasic extraction system consisting of a hydrophilic DES phase (Hexafluoroisopropanol-choline chloride: HFIP-ChCl) and a hydrophobic DES phase (Menthol-tricaprylylmethylammonium chloride: Menthol-N8881Cl) was constructed. The DES based biphasic system was successful in the simultaneous extraction and separation of high polarity compounds, such as chlorogenic acid (CHA), quercetin (QUE) and anthocyanidins (ANT), and a low polarity compound artemisinin(ART), from Artemisia annua Leaves in a single step by the polarity driven recognition targets. By adjusting the mole ratio of the component in each DES phase, the HFIP-ChCl(1:1)/Menthol-N8881Cl(2:1) biphasic system showed the best extraction and separation performance. A conductor-like screening model for real solvents (COSMO-RS) was used to monitor and analyze the changes in the surface polarity dynamics of each DES. The results showed that the non-polar intensity increased from 11.89 to 21.06 Å2 with increasing proportion of HFIP in HFIP-ChCl and the non-polar intensity weakened from 16.47 to 10.01 Å2 with increasing proportion of Menthol in Menthol-N8881Cl. This model can be efficient for screening suitable DESs in a DES based biphasic extraction system to accommodate compounds with a range of polarities. Supported by the model and exptl. data of the DES based biphasic system, 6.21 mg/g ART was transferred to the upper layer (Menthol-N8881Cl with 2:1 mol ratio) and 7.89 mg/g CHA, 5.5 mg/g QUE, and 8.9 mg/g ANT were transferred to the lower layer (HFIP-ChCl with 1:1 mol ratio) under the optimal condition (15/1 solvent/solid ratio, 40°C extraction temperature, 1:1 vol ratio and 30 min extraction time). Therefore, the polarity controlled DES based biphasic extraction system was used to expand the application of DESs in the extraction and separation of bioactive compounds with various polarities. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Computed Properties of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Computed Properties of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics