Category: 5137-55-3

Synthesis, thermal properties, vibrational spectra and computational studies of Trioctylmethylammonium bis(trifluoromethylsulfonyl)imide ionic liquid was written by Assenine, Mohammed Amin;Haddad, Boumediene;Paolone, Annalisa;Brandan, Silvia Antonia;Goussem, Mimanne;Villemin, Didier;Boumediene, Mostefa;Rahmouni, Mustapha;Bresson, Serge. And the article was included in Journal of Molecular Structure in 2021.Recommanded Product: 5137-55-3 The following contents are mentioned in the article:

In this work, Aliquat 336 ([Aliquat⁺]) based ionic liquids containing the fluorinated anion bis(trifluoromethylsulfonyl)imide [NTf^-2] was successfully prepared by the anionic exchange replacement of the chloride anion. The reaction of lithium bis(trifluoromethylsulfonyl)imide with N-methyl-N,N,N-trioctylammonium chloride ([N_1,8,8,8])[Cl] in water lead to the corresponding IL, namely ([Aliquat⁺][NTf-²]). The obtained ionic liquid was characterized by using IR and Raman spectra and its structure was confirmed by ¹H , ¹³C, and ¹⁹F NMR. The thermal properties were investigated by two complementary thermal anal. techniques: TGA and DTA. A hexadentate coordination mode between cation-anion was predicted by atoms in mols. (AIM) studies for the [Aliquat+][NTf-2] IL by using B3LYP/6-31G* calculations where three O atoms of the anion in Cis conformation are linked to six H atoms of cation by S-O•••H interactions. Changes in the bond orders of S and O atoms of the cation supported such observations. The predicted cation-anion distances were in the range 2.30-2.60 Å. The harmonic force fields of cation and anion were calculated and the complete assignments were performed for both species while the most important bands observed in the IR and Raman spectra of the IL were assigned. In addition, the scaled force constants of cation and anion of the IL were also reported. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Recommanded Product: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Insights into the Play of Novel Bronsted Acid-Based Deep Eutectic Solvents for the Conversion of Glucose into 5-Hydroxymethylfurfural without Additional Catalysts was written by Tao, Shunhui;Hu, Lei;Zhang, Xiaodong;Mai, Yinglin;Xian, Xiaoling;Zheng, Xiaojie;Lin, Xiaoqing. And the article was included in Industrial & Engineering Chemistry Research in 2022.Recommanded Product: N-Methyl-N,N-dioctyloctan-1-aminium chloride The following contents are mentioned in the article:

5-Hydroxymethylfurfural (5-HMF) is a versatile bio-platform chem. that connects biomass to a variety of different fuels, chems., and materials. In this work, novel Bronsted acid-based deep eutectic solvents (DESs) with both solvent and catalytic functionalities for glucose dehydration into 5-HMF were developed without the need of addnl. metal salt catalysts or heterogeneous catalysts. The types of hydrogen bond donor (HBD) and hydrogen bond acceptor (HBA), the ratio of HBD to HBA of the DES, heating time, reaction temperature, initial glucose concentration, and moisture content of the DES were systematically investigated to reveal the interplay of the DES in the conversion of glucose to 5-HMF. The most effective DES was found to be tri-Et benzyl ammonium chloride (TEBAC)/formic acid (FA) (molar ratio: 2:1) with a 5-HMF yield of 30.5 ± 1.0% in glucose dehydration and approx. 100% glucose conversion (initial glucose concentration: 2.5 weight %) in 60 min at 150°C. Most importantly, after five cycles, the TEBAC/FA (1:2) DES retained high stability and catalytic activity, with the yield of 5-HMF remaining 30.1 ± 0.5%. Interestingly, as the water content of the DES increased to 70%, the 5-HMF yield increased to 36.5 ± 1.0% along with an 8.01 ± 1.4% yield of levulinic acid. The finding of this study provided insights into the TEBAC/FA (1:2) DES with dual capabilities that might support more efficient bio-based commodity chem. production methods. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Recommanded Product: N-Methyl-N,N-dioctyloctan-1-aminium chloride).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Recommanded Product: N-Methyl-N,N-dioctyloctan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Tetracycline adsorption from aqueous solutions by a magnetic nanoadsorbent modified with ionic liquid was written by Kasraei, Ruhollah;Malakootian, Mohammad. And the article was included in Desalination and Water Treatment in 2021.SDS of cas: 5137-55-3 The following contents are mentioned in the article:

Removal of tetracycline (TC) by the adsorption process was investigated by using iron oxide nanoparticles (Fe₃O₄ NP) modified with the trioctylmethylammonium thiosalicylate (TOMATS) ionic liquid (IL) (Fe₃O₄ NP@TOMATS IL) as a new magnetic nanoadsorbent. The adsorbent was characterized by field-emission SEM-energy-dispersive X-ray spectroscopy, Fouriertransform IR, Brunauer-Emmett-Teller, and X-ray diffraction. Batch experiments were carried out to study the sorption kinetics, thermodn., and equilibrium isotherms of TC with Fe₃O₄ NP@TOMATS IL. The results showed that the maximum removal efficiency of TC in optimum conditions of pH (7), contact time (90 min), adsorbent dosage (0.2 mg L-1), temperature (328 K), and initial concentration of TC (30 mg L-1) was obtained 92% and 73% in the synthetic and real samples, resp. Examination of the kinetics and adsorption isotherm equations demonstrated that the adsorption process followed the pseudo-second-order and the Freundlich isotherm. Also, the amount of equilibrium adsorption capacity is 36 mg g-1 in the real sample. Investigation of thermodn. equations revealed that the adsorption by iron oxide nanoparticles modified with TOMATS IL was phys. and spontaneously endothermic. The results obtained from the experiments also indicated that the synthesized nanocomposite has high reusability and recyclability after four periodic cycles. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3SDS of cas: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Separation of Hf(IV) from Zr(IV) in thiocyanate medium with ionic liquid Aliquat 336 was written by Wu, Ming;Dong, Panfei;Wu, Chenjie;Zhang, Zhenyue;Chi, Ruan;Xu, Zhigao. And the article was included in Hydrometallurgy in 2022.Application In Synthesis of N-Methyl-N,N-dioctyloctan-1-aminium chloride The following contents are mentioned in the article:

Solvent extraction is the key tech. link for the preparation of nuclear-grade Hf and Zr for advanced nuclear reactors. In this study, the separation of Hf(IV) over Zr(IV) from the highly concentrated aqueous feed by solvent extraction with ionic liquid Aliquat 336 was investigated. The results indicated that thiocyanate forms of the ionic liquid dissolved in amyl acetate were more conducive to selective extraction of Hf(IV). Under the selected conditions, optimal extraction efficiency of Hf(IV) could be up to 94.5%. The separation factor of Hf(IV) to Zr(IV) was found to be 19.4. The extraction mechanism of Hf(IV) was revealed by slope anal. and FTIR anal. The extracted complex of Hf(IV) was determined as [(A336⁺)₁₂(HfO²⁺)₃(H⁺)(_12x-2)(SCN^–)(_16+12x)]. The extraction isotherm indicated that nuclear-grade Zr(IV) could be recovered from the raffinate via a two-stage extraction The sulfuric acid solution showed appreciable selectivity in scrubbing of Zr(IV) from the loaded organic phase. The Hf(IV) species in the remaining loaded organic phase could be effectively stripped by 3.0 M (NH₄)₂CO₃ solution Accordingly, a recyclable process flowsheet for the separation of Hf(IV) from Zr(IV) using Aliquat 336 was developed. It is believed that this process is a promising way for the preparation of enriched Hf and high purity Zr. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Application In Synthesis of N-Methyl-N,N-dioctyloctan-1-aminium chloride).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Application In Synthesis of N-Methyl-N,N-dioctyloctan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Environmentally benign hydrophobic deep eutectic solvents for palladium(II) extraction from hydrochloric acid solution was written by Tang, Nian;Liu, Lingli;Yin, Chun;Zhu, Guiping;Huang, Qilan;Dong, Jieru;Yang, Xiangjun;Wang, Shixiong. And the article was included in Journal of the Taiwan Institute of Chemical Engineers in 2021.COA of Formula: C25H54ClN The following contents are mentioned in the article:

Hydrophobic deep eutectic solvents (DESs) are considered to be clean and green alternatives to traditional organic solvents for metal ion extraction Herein, a series of novel hydrophobic DESs were synthesized via the combination of methyltrioctylammonium chloride ([N₈₈₈₁]Cl) as hydrogen bond acceptors (HBAs) and saturated fatty acids or saturated fatty alcs. as hydrogen bond donors (HBDs). Then, the DESs were used for palladium(II) recovery from acid solution The factors that affect palladium(II) extraction (including the DES species, contact time, DES dose, solution pH, and temperature) were extensively investigated. The DESs exhibit excellent performance for extracting palladium(II) from hydrochloric acid media, and more than 99% of palladium(II) was extracted under optimal conditions. UV-vis, ¹H NMR, and FTIR spectral characterizations confirm that the extraction mechanism of palladium(II) involves an anion exchange reaction whereby PdCl₂^-4 anions in the aqueous phase replace Cl- anions in DES to form ion-pairs with [N⁺₈₈₈₁] via electrostatic interactions. Meanwhile, N₈₈₈₁:1-hexanol (1:1) and N₈₈₈₁:hexanoic acid (1:2) exhibit excellent selectivity for palladium(II) over other impurity metal ions. Also, palladium(II) in the loaded DES phase was efficiently recovered as elemental palladium via the hydrazine hydrate reduction method; thus, the DES could be reused for at least 5 cycles. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3COA of Formula: C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.COA of Formula: C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Thermodynamic Modeling of Salting Effects in Solvent Extraction of Cobalt(II) from Chloride Media by the Basic Extractant Methyltrioctylammonium Chloride was written by Lommelen, Rayco;Binnemans, Koen. And the article was included in ACS Omega in 2021.HPLC of Formula: 5137-55-3 The following contents are mentioned in the article:

The design and optimization of solvent extraction processes for metal separations are challenging tasks due to the large number of adjustable parameters. A quant. predictive solvent extraction model could help to determine the optimal parameters for solvent extraction flow sheets, but such predictive models are not available yet. The main difficulties for such models are the large deviations from ideal thermodn. behavior in both the aqueous and organic phases due to high solute concentrations We constructed a mol. thermodn. model for the extraction of CoCl₂ from different chloride salts by 0.2 mol L^-1 trioctylmethylammonium chloride in toluene using the OLI mixed-solvent electrolyte (OLI-MSE) framework. This was accomplished by analyzing the water and hydrochloric acid content of the organic phase, measuring the water activity of the system, and using metal complex speciation and solvent extraction data. The full extractant concentration range cannot be modeled by the OLI-MSE framework as this framework lacks a description for reversed micelle formation. Nevertheless, salting effects and the behavior of hydrochloric acid can be accurately described with the presented extraction model, without determining specific Co(II)-salt cation interaction parameters. The resulting model shows that the salting effects originate from indirect salt cation-solvent interactions that influence the availability of water in the aqueous and organic phases. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3HPLC of Formula: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.HPLC of Formula: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Do hydrothermal aging and microwave sterilization affect the trueness of milled, additive manufactured and injection molded denture bases was written by Wemken, Gregor;Spies, Benedikt Christopher;Pieralli, Stefano;Adali, Ufuk;Beuer, Florian;Wesemann, Christian. And the article was included in Journal of the Mechanical Behavior of Biomedical Materials in 2020.Recommanded Product: 5137-55-3 The following contents are mentioned in the article:

To assess trueness of IM, MIL, and stereolithog. printed denture bases after manufacturing, hydrothermal cycling, and microwave sterilization. 16 Edentulous maxillary plaster models were poured using silicone mold and digitized by means of desktop scanner. For group IM, 16 denture bases were injection molded. MIL and SLA, denture bases were virtually designed and manufactured referring to digitized data. A total of 48 samples were scanned 1) after manufacturing, 2) after hydrothermal cycling three as well as 4) six cycles of microwave sterilization for 6 min each at 640 W. The 3D surface deviation of the total intaglio surface, the palate, the alveolar ridge, and the border seal region was evaluated on basis of RMSE and pos. and neg. mean deviations with inspection software. In comparison, IM showed increased, mainly pos., deviations at border seal. SLA presented highest total RMSE with increased neg. deviations, likewise at the border seal. In contrast to SLA, no differences between IM and MIL were measured after hydrothermal cycling. Following microwave sterilization, the trueness of SLA was higher compared to IM and MIL with no differences between MIL and IM. Distortion of IM and MIL was measured after the 3rd cycle with no further changes observed Subtractive manufacturing of denture bases results in the highest trueness, followed by IM and SLA. IM and SLA, hydrothermal cycling did not affect MIL. SLA printed denture bases remained dimensionally stable after microwave sterilization. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Recommanded Product: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Recommanded Product: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Breaking the Corona Symmetry of Vesicles was written by Wei, Ping;Cornel, Erik Jan;Du, Jianzhong. And the article was included in Macromolecules (Washington, DC, United States) in 2021.HPLC of Formula: 5137-55-3 The following contents are mentioned in the article:

It is very challenging to completely break the corona symmetry of polymer vesicles as usually their inner and outer coronas have the same constituents. Herein, we propose a novel micelle-to-vesicle strategy to achieve this goal. First, a poly(ethylene oxide)₁₁₃-b-poly[N-iso-Pr acrylamide₄₅-stat-7-(2-methacryloyloxyethoxy)-4-methylcoumarin₁₀]-b-poly(2-(diethylamino)ethyl methacrylate)₂₈ [PEO₁₁₃-b-P(NIPAM₄₅-stat-CMA₁₀)-b-PDEA₂₈] triblock copolymer was synthesized and self-assembled into micelles, which were then transformed into asym. vesicles. The PEO block formed the outer corona of the vesicles, the PDEA block formed the inner corona of the vesicles (initially acted as the core-forming block of micelles), and the P(NIPAM-stat-CMA) block formed the membrane of vesicles (initially acted as the middle corona or the shell of micelles). Symmetry breaking was achieved during the micelle-to-vesicle transition where the locations of the inner and the outer coronas of vesicles were predetermined This asym. structure was confirmed by selective decoration with gold nanoparticles on the PDEA inner coronas. Furthermore, the inner coronas could efficiently prevent unwanted doxorubicin (DOX) leakage at physiol. conditions by turning themselves into an inner wall. Overall, we have hereby demonstrated a novel approach to prepare well-defined asym. vesicles through a finely controlled micelle-to-vesicle transition. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3HPLC of Formula: 5137-55-3).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).HPLC of Formula: 5137-55-3

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Use of Ionic Liquid Pretreated and Fermented Sugarcane Bagasse as an Adsorbent for Congo Red Removal was written by Ejaz, Uroosa;Wasim, Agha Arslan;Khan, Muhammad Nasiruddin;Alzahrani, Othman M.;Mahmoud, Samy F.;El-Bahy, Zeinhom M.;Sohail, Muhammad. And the article was included in Polymers (Basel, Switzerland) in 2021.Formula: C25H54ClN The following contents are mentioned in the article:

A large amount of industrial wastewater containing pollutants including toxic dyes needs to be processed prior to its discharge into the environment. Biol. materials such as sugarcane bagasse (SB) have been reported for their role as adsorbents to remove the dyes from water. In this study, the residue SB after fermentation was utilized for the dye removal. A combined pretreatment of NaOH and methyltrioctylammonium chloride was given to SB for lignin removal, and the pretreated SB was utilized for cellulase production from Bacillus aestuarii UE25. The strain produced 118 IU mL^-1 of endoglucanse and 70 IU mL^-1 of β-glucosidase. SEM and FTIR spectra showed lignin and cellulose removal in fermented SB. This residue was utilized for the adsorption of an azo dye, congo red (CR). The thermodn., isotherm and kinetics studies for the adsorption of CR revealed distinct adsorption features of SB. Untreated SB followed Langmuir isotherm, whereas pretreated SB and fermented SB obeyed the Freundlich isotherm model. The pseudo-second-order model fitted well for the studied adsorbents. The results of thermodn. studies revealed spontaneous adsorption with neg. standard free energy values. Untreated SB showed a 90.36% removal tendency at 303.15 K temperature, whereas the adsorbents comprised of pretreated and fermented SB removed about 98.35% and 97.70%, resp. The study provided a strategy to utilize SB for cellulase production and its use as an adsorbent for toxic dyes removal. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Formula: C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Formula: C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Flame atomic absorption spectrometric determination of total chromium and cadmium in bean samples after ultrasonic-assisted microextraction using ionic liquid Aliquat-336 was written by Elik, Adil;Karakoy, Tolga;Cilesiz, Yeter;Altunay, Nail. And the article was included in Journal of the Iranian Chemical Society in 2021.Synthetic Route of C25H54ClN The following contents are mentioned in the article:

Abstract: A new and rapid microextraction approach termed as ultrasonic-assisted ionic liquid-based microextraction (UA-ILME) was developed using ionic liquid Aliquat-336 as extraction solvent for the extraction of chromium and cadmium in bean samples collected from different regions in Turkey. The total amounts of analytes in the samples were measured by flame at. absorption spectrophotometry. The basis of the extraction step is based on the complexation of Cr(III) and Cd(II) with diethyldithiocarbamate at pH 4.0. The hydrophobic ternary complexes containing analytes were then rapidly extracted from the sample solution to the ionic phase under the ultrasonic effect using tricaprylylmethylammonium chloride (Aliquat-336). Some exptl. variables (pH, ligand amount, extraction solvent volume, ultrasound time, extraction temperature and sample volume) were optimized in detail. Following the optimization steps, the limits of detection (LODs, 3Sblank/m) for Cr(III) and Cd(II) were calculated as 0.45 ng mL-1 with linear range of 1.5-380 ng mL-1 and 0.25 ng mL-1 with linear range of 0.8-220 ng mL-1, resp. Enrichment factors and average recoveries were ranged from 125.8-96.4 to 92.7-106.5%, resp. The accuracy and precision of the method were validated by analyzing a certified reference material and spiked recovery tests. The UA-ILME method was successfully applied to the determination of Cd and Cr in the samples, highlighting that the matrix ions under consideration do not affect the extraction and determination steps. This study involved multiple reactions and reactants, such as N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3Synthetic Route of C25H54ClN).

N-Methyl-N,N-dioctyloctan-1-aminium chloride (cas: 5137-55-3) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Synthetic Route of C25H54ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics