Category: 5034-06-0

On February 28, 1983, Fray, M. Jonathan; Thomas, Eric J.; Wallis, John D. published an article.HPLC of Formula: 5034-06-0 The title of the article was On the stereoselectivity of epoxide formation using dimethyloxosulfonium methylide. X-ray structure of (5SR)-5-[(1RS)-1-methyl-2-oxacyclopropyl]pyrrolidin-2-one. And the article contained the following:

Epoxidation of 5-acetylpyrrolidin-2-one with dimethyloxosulfonium methylide in THF at 20° for 2 h and then 55° for 1 h gave a 78:22 mixture of epoxides I (α-Me, β-Me) (II and III, resp.) whereas in the presence of ZnCl2 a 23:77 mixture of II and III was obtained. The configuration of these epoxides was determined from the NMR spectra of the corresponding carbonate derivatives IV and by x-ray crystallog. anal. of III. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).HPLC of Formula: 5034-06-0

The Article related to epoxidation acetylpyrrolidinone stereoselectivity, pyrrolidinone acetyl epoxidation stereoselectivity, methyloxiranylpyrrolidinone preparation configuration crystal structure, oxiranylpyrrolidinone methyl structure and other aspects.HPLC of Formula: 5034-06-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On February 28, 1990, Lin, Ivan J. B.; Lai, J. S.; Liu, C. W. published an article.COA of Formula: C3H9ClOS The title of the article was Phase-transfer-catalyzed phosphorus-carbon bond cleavage in platinum bis(diphenylphosphino)methane complexes under exceedingly mild conditions. And the article contained the following:

The reaction of [Pt(dppm)Cl2] (dppm = Ph2PCH2PPh2) with [S(O)Me3]Cl under basic phase-transfer-catalyzed conditions gave the complex {Pt(PPh2Me)[PPh2(OH)][(CH2)2S(O)Me]}Cl, which contains a bidentate sulfur ylide and two monodentate phosphine ligands. The latter was produced by the facile base hydrolysis of the dppm ligand, a reaction that is general for other Pt-dppm complexes. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).COA of Formula: C3H9ClOS

The Article related to carbon phosphorus bond cleavage bisdiphenylphosphinomethane, platinum bisdiphenylphosphinomethane ligand base hydrolysis, sulfur ylide platinum complex, phase transfer catalysis bisdiphenylphosphinomethaneplatinum and other aspects.COA of Formula: C3H9ClOS

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On November 7, 2007, Kakei, Hiroyuki; Sone, Toshihiko; Sohtome, Yoshihiro; Matsunaga, Shigeki; Shibasaki, Masakatsu published an article.HPLC of Formula: 5034-06-0 The title of the article was Catalytic Asymmetric Cyclopropanation of Enones with Dimethyloxosulfonium Methylide Promoted by a La-Li3-(Biphenyldiolate)3 + NaI Complex. And the article contained the following:

Catalytic asym. cyclopropanation of enones with dimethyloxosulfonium methylide using a La-Li3-(biphenyldiolate)3 + NaI complex is described. The present method is complementary to the previously reported catalytic enantioselective methods in terms of ylides used, and trans products, e.g., I, were exclusively obtained in good yield (96-73%) and high enantioselectivity (99-84% ee). Use of biphenyldiol and NaI additive was essential to achieve high enantioselectivity. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).HPLC of Formula: 5034-06-0

The Article related to enone dimethyloxosulfonium methylide lanthanium chiral biphenyldiol complex asym cyclopropanation, cyclopropyl ketone derivative stereoselective preparation, asym cyclopropanation catalyst lanthanium chiral biphenyldiol complex and other aspects.HPLC of Formula: 5034-06-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 31, 1979, Corley, L. S.; Vogl, O. published an article.Application In Synthesis of trimethyloxosulphonium chloride The title of the article was Haloaldehyde polymers. 16. Stabilization of anionically-prepared polychloral by end-capping with decomposable cations and other additives. And the article contained the following:

Completely or partially stable polychloral [25154-92-1] was obtained by anionic cryotachensic polymerization of Cl3CCHO in the presence of alkylating or acylating agents, e.g. Me2SO4 [77-78-1]. Stabilization was also effected by polymerization using salts with easily decomposed cations as anionic initiators. Sulfonium salts, e.g. Me3S+Cl- [3086-29-1] and [Me2S+CH2Ph]Br- [14182-15-1], and iodonium salts, e.g. Ph2I+Cl- [1483-72-3], were effective although quant. stabilization was not achieved. Polychloral with improved stability was also obtained using certain amide acetals, e.g. Me2NCH(OMe)2 [4637-24-5], as initiators. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Application In Synthesis of trimethyloxosulphonium chloride

The Article related to polychloral stabilization, chloral anionic polymerization stability, sulfonium catalyst chloral polymerization, iodonium initiator chloral polymerization, amide acetal chloral polymerization, end capping polychloral stability and other aspects.Application In Synthesis of trimethyloxosulphonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ladelta, Viko; Zapsas, George; Abou-hamad, Edy; Gnanou, Yves; Hadjichristidis, Nikos published an article in 2019, the title of the article was Tetracrystalline Tetrablock Quarterpolymers: Four Different Crystallites under the Same Roof.Recommanded Product: trimethyloxosulphonium chloride And the article contains the following content:

Multicrystalline block polymers having three or more crystalline segments are essential materials for the advancement of physics in the field of crystallinity. The challenging synthesis of multicrystalline polymers has resulted in only a limited number of tricryst. terpolymers having been reported to date. We report, for the first time, the synthesis of polyethylene-b-poly(ethylene oxide)-b-poly(ε-caprolactone)-b-poly(L-lactide) (PE-b-PEO-b-PCL-b-PLLA), a tetracryst. tetrablock quarterpolymer, by combining polyhomologation, ring-opening polymerization, and an organic/metal “catalyst switch” strategy. 1H NMR spectroscopy and gel-permeation chromatog. confirmed the formation of the tetrablock quarterpolymer, while differential scanning calorimetry, X-ray diffraction, and wide-line separation solid-state NMR spectroscopy revealed the existence of four different crystalline domains. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Recommanded Product: trimethyloxosulphonium chloride

The Article related to polyethylene oxide polycaprolactone polylactide tetrablock quarterpolymer synthesis characterization, catalyst switch, multicrystalline polymers, polyhomologation, ring-opening polymerization, tetrablock quarterpolymers and other aspects.Recommanded Product: trimethyloxosulphonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Seno, Manabu; Tsuchiya, Shinji published an article in 1977, the title of the article was Preparation, properties, and x-ray photoelectron spectra of palladium(II) and platinum(II) complexes of amine imides aminimides and sulfur ylides.Synthetic Route of 5034-06-0 And the article contains the following content:

Amine imides RMe2N+N-COR1 (R = PhCH2, p-O2NC6H4CH2; R1 = Me, Et, Ph) and the S ylides Me2S+(O)C-HCOPh with Pd(II) and Pt(II) halides gave ylide-metal complexes PdCl2L2 (L = amine imide), PtCl2[Me2S+(O)C-HCOPh]SEt2, and MCl2[Me2S+(O)C-HCOPh]2 (M = Pd, Pt). IR, 1H and 13C NMR, and x-ray photoelectron spectra indicated that the coordination of the ylide to the metal was through the nucleophilic N+ or C- atom as simple terminal ligands. Cis-PtCl2[Me2S+(O)C-HCOPh]SEt2 released SEt2 in Me2SO giving PtCl2[Me2S+(O)C-HCOPh] which was chelated through the carbanion C and the sulfonium O of the ylide. The thermal properties of the complexes were examined by thermal gravimetric anal. and the nature of the bonding was discussed. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Synthetic Route of 5034-06-0

The Article related to amine imide metal complex, sulfur ylide metal complex, palladium amine imide ylide complex, platinum sulfur ylide complex, ir metal ylide complex, nmr metal ylide complex, photoelectron spectra metal ylide, elec conductivity metal ylide, coordination metal ylide complex and other aspects.Synthetic Route of 5034-06-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On October 18, 1985, Nagao, Yoshimitsu; Ikeda, Takao; Inoue, Takehisa; Yagi, Masahiro; Shiro, Motoo; Fujita, Eiichi published an article.Reference of trimethyloxosulphonium chloride The title of the article was Utilization of sulfur-containing leaving group. 7. Highly selective nonenzymic chiral induction into 3-methylglutaric acid and cis-4-cyclohexen-1,2-ylenebis(acetic acid) utilizing a functional five-membered heterocycle 4(R)-MCTT. And the article contained the following:

Diamide I, prepared by treatment of 3-methylglutaric acid with 4(R)-(methoxycarbonyl)-1,3-thiazolidine-2-thione [4(R)-MCTT] in the presence of DCC in pyridine, was subjected to aminolysis with 1 equiv of piperidine in CH2Cl2 at -30° to give a mixture of diastereomers II [R2N = piperidino, R12N = MCTT moiety (III)] and II (R2N = MCTT moiety, R12N = piperidino) in a 88:12 ratio. III was separated by silica gel column chromatog. and treated with various nucleophiles to give optically pure bifunctional synthons (II; R2N and R12N = nucleophilic group) in high yields. Highly selective chiral induction into cis-4-cyclohexen-1,2-ylenebis(acetic acid) was also performed. Aminolysis of IV (R2N and R12N = MCTT moiety) (V) with 1 equiv of piperidine gave 94% diastereomer IV (R2N = piperidino, R12N = MCTT moiety). Similar chiral induction into cis-cyclohexan-1,2-xylenebis(acetic acid) and aminolysis of its 4(R)-MCTT diamide (VI) with piperidine were also carried out; opposite selectivity was obtained. The conformations of V and VI in a solvent, the relationship between the susceptibility of their conformations and environmental temperature, and the diastereoselectivity of the reaction are discussed on the basis of the 400-MHz 1H NMR spectra. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Reference of trimethyloxosulphonium chloride

The Article related to chiral induction methylglutaric cyclohexenebisacetic acid, thiazolidinethionecarboxylate amidation methylglutaric cyclohexenebisacetic acid, conformation thiazolidinethionecarboxylate diamide, aminolysis thiazolidinethionecarboxylate diamide stereochem and other aspects.Reference of trimethyloxosulphonium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Seno, Manabu; Tsuchiya, Shinji published an article in 1977, the title of the article was Preparation, properties, and x-ray photoelectron spectra of palladium(II) and platinum(II) complexes of amine imides aminimides and sulfur ylides.Synthetic Route of 5034-06-0 And the article contains the following content:

Amine imides RMe2N+N-COR1 (R = PhCH2, p-O2NC6H4CH2; R1 = Me, Et, Ph) and the S ylides Me2S+(O)C-HCOPh with Pd(II) and Pt(II) halides gave ylide-metal complexes PdCl2L2 (L = amine imide), PtCl2[Me2S+(O)C-HCOPh]SEt2, and MCl2[Me2S+(O)C-HCOPh]2 (M = Pd, Pt). IR, 1H and 13C NMR, and x-ray photoelectron spectra indicated that the coordination of the ylide to the metal was through the nucleophilic N+ or C- atom as simple terminal ligands. Cis-PtCl2[Me2S+(O)C-HCOPh]SEt2 released SEt2 in Me2SO giving PtCl2[Me2S+(O)C-HCOPh] which was chelated through the carbanion C and the sulfonium O of the ylide. The thermal properties of the complexes were examined by thermal gravimetric anal. and the nature of the bonding was discussed. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Synthetic Route of 5034-06-0

The Article related to amine imide metal complex, sulfur ylide metal complex, palladium amine imide ylide complex, platinum sulfur ylide complex, ir metal ylide complex, nmr metal ylide complex, photoelectron spectra metal ylide, elec conductivity metal ylide, coordination metal ylide complex and other aspects.Synthetic Route of 5034-06-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On February 7, 2020, Yuen, Tsz Ying; Brown, Christopher J.; Tan, Yaw Sing; Johannes, Charles W. published an article.Application of 5034-06-0 The title of the article was Synthesis of chiral alkenyl cyclopropane amino acids for incorporation into stapled peptides. And the article contained the following:

α,α’-Disubstituted amino acids serve as important non-proteinogenic amino acids in the construction of stabilized helical peptides. To expand the repertoire of α,α’-disubstituted amino acids, chiral alkenyl-containing cyclopropane amino acids were synthesized via a two-step olefination and cyclopropanation procedure. Herein, we report the first example of the use of alkenyl cyclopropane building blocks to constrain MDM2-targeting helical peptides. The increased potency and efficacy associated with C-terminal cyclopropane substitution is postulated to be driven by a combined effect of net hydrophobicity and enhanced protein association rates. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Application of 5034-06-0

The Article related to chiral cyclopropane alkenyl amino acid synthesis stapled peptide, solid phase peptide synthesis macrocyclization conformation helix, mdm2 binding fluorescence md simulation enthalpy free energy cluster, glycine derivative horner wadsworth emmons olefination alkenyl aldehyde, condensation reaction stereoselective cyclopropanation and other aspects.Application of 5034-06-0

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 31, 1998, Kawanishi, Hiroyuki; Morimoto, Hiroshi; Nakano, Takao; Watanabe, Tatsuya; Oda, Kuniyuki; Tsujihara, Kenji published an article.Category: chlorides-buliding-blocks The title of the article was Stereoselective synthesis of antifungal sulfoximines, novel triazoles II. And the article contained the following:

Novel triazole derivatives I (R = H, MeCO, MeNHCO, Me, MeO2CCH2) with an N-substituted sulfoximine moiety were synthesized and evaluated for antifungal activity. These compounds showed significantly weaker activity than I (R = H); the N-H moiety of the sulfoximine was extremely important for the activity. A practical and effective stereoselective synthesis of (-)-I (R = H), considered to be the most promising antifungal compound, has been developed. (-)-I (R = H) is prepared in seven steps, including two resolution steps, from the methylthiodifluoropropiophenone II, by epoxidation with Me3SO+ Cl-, diastereoselective sulfimine formation with chloramine T, addition of 1,2,4-triazole to the epoxide, oxidation of the sulfimine, acid hydrolysis of toluenesulfonyl group of the sulfoximine, and resolution with the novel resolving agent 1-(2,3,4-trichlorophenyl)ethanesulfonic acid [(+)-TCPES] III. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Category: chlorides-buliding-blocks

The Article related to triazole sulfoximine derivative preparation, sulfoximine triazole prospective antifungal agent nonracemic stereoselective practical preparation, stereoselective synthesis antifungal sulfoximine novel triazole, antifungal activity triazole sulfoximine nitrogen substitution, chlorophenylethanesulfonic acid tcpes novel resolving agent sulfoximine triazole and other aspects.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics