Category: 50-84-0

An article TiC doped palladium/nickel foam cathode for electrocatalytic hydrodechlorination of 2,4-DCBA: Enhanced electrical conductivity and reactive activity WOS:000449127500017 published article about MODIFIED NICKEL FOAM; WASTE-WATER TREATMENT; TITANIUM CARBIDE; 2,4-DICHLOROPHENOXYACETIC ACID; REDUCTIVE DECHLORINATION; CARBON NANOTUBES; AQUEOUS-SOLUTION; ELECTROCHEMICAL DECHLORINATION; ELECTRODE; NANOPARTICLES in [Lou, Zimo; Li, Yizhou; Zhou, Jiasheng; Yang, Kunlun; Liu, Yuanli; Xu, Xinhua] Zhejiang Univ, Coll Environm & Resource Sci, Dept Environm Engn, Hangzhou 310058, Zhejiang, Peoples R China; [Baig, Shams Ali] Abdul Wali Khan Univ, Dept Environm Sci, Mardan 23200, Pakistan in 2019, Cited 77. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0. Application In Synthesis of 2,4-Dichlorobenzoic acid

Titanium carbide (TiC) with excellent electrical conductivity, chemical and thermal stabilities has been recognized as one of the most promising electrocatalysts. A novel cathode, titanium carbide doped palladium/nickel foam (TiC-Pd/Ni foam), was synthesized via electroless deposition to improve the performance of Pd/Ni foam in electrocatlytic hydrodechlorination (ECH). TiC can be co-precipitated onto the surface of cathode during galvanic replacement reaction between Pd(II) solution and Ni foam. Both constant potential and constant current tests proved that TiC-Pd/Ni foam cathode performed remarkably higher activity for 2,4-dichlorobenzoic acid (2,4-DCBA) than Pd/Ni foam cathode, owing to the excellent conductivity of TiC and enhanced water dissociation over TiC-Pd/Ni foam cathode. Under the optimized reaction conditions of -0.85 V (vs Ag/AgCl), electrolyte of 10 mM and initial pH of 4, 99.8% of aqueous 2,4-DCBA (0.2 mM) was removed within 90 min. The removal process of the aqueous 2,4-DCBA obeyed first-order decay kinetic model. Over 86.3% of 2,4-DCBA can still be removed by TiC-Pd/Ni foam cathode in the fifth consecutive run within 120 min, which was much higher than that of Pd/Ni foam cathode (37.5%). Consequently, TiC-Pd/Ni foam cathode was a promising design for enhanced ECH activity and reduced operation cost.

Application In Synthesis of 2,4-Dichlorobenzoic acid. Welcome to talk about 50-84-0, If you have any questions, you can contact Lou, ZM; Li, YZ; Zhou, JS; Yang, KL; Liu, YL; Baig, SA; Xu, XH or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Application In Synthesis of 2,4-Dichlorobenzoic acid. Authors Zhou, JS; Lou, ZM; Wang, ZN; Zhou, CC; Li, C; Baig, SA; Xu, XH in ELSEVIER SCIENCE SA published article about in [Zhou, Jiasheng; Lou, Zimo; Wang, Zheni; Zhou, Chuchen; Li, Cheng; Xu, Xinhua] Zhejiang Univ, Coll Environm & Resource Sci, Dept Environm Engn, Hangzhou 310058, Peoples R China; [Lou, Zimo] Zhejiang Univ Technol, Collaborat Innovat Ctr Yangtze River Delta Reg Gr, Hangzhou 310014, Peoples R China; [Baig, Shams Ali] Abdul Wali Khan Univ, Dept Environm Sci, Mardan 23200, Pakistan in 2021, Cited 80. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0

The CTAB-Pd/GAC catalyst was obtained by functionalizing palladium/granular activated carbon (Pd/GAC) with cetyltrimethylammonium bromide (CTAB), which was used for the electrocatalytic reductive dechlorination of 2,4-dichlorobenzoic acid (2,4-DCBA). The degradation rate of 2,4-DCBA by 40 mg g(-1) CTAB-Pd/GAC was 9.8 x 10(-3) (min(-1) g(-1) Pd), which was 11 folds than that by Pd/GAC (0.9 x 10(-3) min(-1) g(-1) Pd), and the value of q(e, 2,4-DCBA)/q(e), BA was 2.33 as compared to 0.67 for Pd/GAC. The combined result of dechlorination and adsorption experiments suggested that the functionalization by CTAB would enhance the 2,4-DCBA concentration on the surface of CTAB-Pd/GAC, and accelerate the degradation rate. However, the removal efficiency of 2,4-DCBA would decrease when the CTAB load reached 80 mg g(-1), due to the excessive adsorption capacity for dech-lorinated product. Density functional theory (DFT) calculations also proved that CTAB would increase adsorption capacity of catalyst and selective adsorption behavior of 2,4-DCBA, which accelerated the degradation rate of 2,4-DCBA.

Welcome to talk about 50-84-0, If you have any questions, you can contact Zhou, JS; Lou, ZM; Wang, ZN; Zhou, CC; Li, C; Baig, SA; Xu, XH or send Email.. Application In Synthesis of 2,4-Dichlorobenzoic acid

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Authors Mallick, S; Baidya, M; Mahanty, K; Maiti, D; De Sarkar, S in WILEY-V C H VERLAG GMBH published article about C-H CHALCOGENATION; OXIDATIVE CYCLIZATION; ALKENES; FUNCTIONALIZATION; SELENIUM; BROMOCYCLIZATION; THIOLATION; STRATEGIES; SELENATION; INDOLES in [Mallick, Samrat; Baidya, Mrinmay; Mahanty, Kingshuk; Maiti, Debabrata; De Sarkar, Suman] Indian Inst Sci Educ & Res Kolkata, Dept Chem Sci, Mohanpur 741246, W Bengal, India in 2020, Cited 66. Application In Synthesis of 2,4-Dichlorobenzoic acid. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0

The current report represents a transition-metal-free synthesis of oxazoline and isoxazoline derivatives by a tandem electro-oxidative chalcogenation-cyclization process. Both C-Se and C-S bond-forming protocols were developed without using any external oxidant and the reaction was performed at room temperature, open to the air. Using this methodology, 29 substituted oxazoline and 16 substituted isoxazoline derivatives were synthesized with up to 91% isolated yield.

Application In Synthesis of 2,4-Dichlorobenzoic acid. About 2,4-Dichlorobenzoic acid, If you have any questions, you can contact Mallick, S; Baidya, M; Mahanty, K; Maiti, D; De Sarkar, S or concate me.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Formula: C7H4Cl2O2. I found the field of Pharmacology & Pharmacy very interesting. Saw the article Acylation of 25-hydroxyprotopanaxatriol with aromatic acids increases cytotoxicity published in 2019, Reprint Addresses Piao, HR (corresponding author), Yanbian Univ, Key Lab Nat Resources Changbai Mt & Funct Mol, Minist Educ, Coll Pharm, Yanji 133002, Peoples R China.; Zhao, YQ (corresponding author), Shenyang Pharmaceut Univ, Sch Funct Food & Wine, Shenyang, Liaoning, Peoples R China.. The CAS is 50-84-0. Through research, I have a further understanding and discovery of 2,4-Dichlorobenzoic acid.

20(R)-25-hydroxyprotopanaxadiol (25-OH-PPD) is a natural compound showing a variety of anti-tumor effects. In an attempt to search for a new anti-cancer compound with higher antitumor activities, we designed and synthesized a series of 25-OH-PPD derivatives. Cytotoxicity assay of these derivatives towards MCF-7, A549, U87, HO-8901, Hela cancer cell lines and normal IOSE144 cell lines were tested by MTF assay. Results showed that compared with compound 25-OH-PPD, Compounds 4, 5, 6, 10, 11 showed strong anticancer activity, and all compounds showed low toxicity or no toxicity for normal cells. In particular, compound 6 exhibited the best anti-tumor activity in all cancer cell lines (MCF-7, A549, U87, HO-8901, and Hela) with IC50 values of 5.04 mu M, 1.36 mu M, 3.24 mu M, 3.47 mu M, 4.57 mu M, respectively. Among the five cell lines, all the compounds showed strong inhibition on A549 cells. Further studies showed that Compound 6 significantly inhibited the proliferation of A549 cells by inducing apoptosis. Our results indicate that Compound 6 is a potential anticancer inhibitor and provides a theoretical basis for further research.

About 2,4-Dichlorobenzoic acid, If you have any questions, you can contact Lv, LY; Lu, JC; Zhang, HY; Wang, XD; Su, GY; Piao, HR; Zhao, YQ or concate me.. Formula: C7H4Cl2O2

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Name: 2,4-Dichlorobenzoic acid. Mahesha, N; Sagar, BK; Yathirajan, HS; Furuya, T; Haraguchi, T; Akitsu, T; Glidewell, C in [Mahesha, Ninganayaka; Sagar, Belakavadi K.; Yathirajan, Hemmige S.] Univ Mysore, Dept Studies Chem, Mysuru 570006, India; [Furuya, Tetsundo; Haraguchi, Tomoyuki; Akitsu, Takashiro] Tokyo Univ Sci, Fac Sci, Dept Chem, Shinjuku Ku, 1-3 Kagurazaka, Tokyo 1628601, Japan; [Glidewell, Christopher] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland published Three closely related 1-[(1,3-benzodioxol-5-yl)-methyl]-4-(halobenzoyl)pinerazines: similar molecular structures but different intermolecular interactions in 2019, Cited 27. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0.

In each of the compounds 1-[(1,3-benzodioxol-5-yl)methyl]-4-(3-fluorobenzoyl)piperazine, C19H19 FN2O3 (I), 1-[(1,3-benzodioxol-5-yl)methyl]-4-(2,6-difluorobenzoyl)piperazine, C19H18F2N2O3 (II), and 1-[(1,3-benzodioxol-5-yl)methyl]-4-(2,4-dichlorobenzoyl)piperazine, C19H19Cl2N2O3 (III), the piperazine rings adopt a chair conformation with the (1,3-benzodioxol-5-yl)methyl substituent occupying an equatorial site: the five-membered rings are all slightly folded across the O center dot center dot center dot O line leading to envelope conformations. The dihedral angle between the planar amidic fragment and the haloaryl ring is 62.97 (5)degrees in (I) but 77.72 (12)degrees and 75.50 (5)degrees in (II) and (III), respectively. Despite their similarity in constitution and conformation, the supramolecular interactions in (I)-(III) differ: in (I), a combination of C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds links the molecules into a three-dimensional framework structure, but there are no hydrogen bonds of any sort in either (II) or (III), although the structure of (III) contains a short Cl center dot center dot center dot Cl contact between inversion-related pairs of molecules.

Welcome to talk about 50-84-0, If you have any questions, you can contact Mahesha, N; Sagar, BK; Yathirajan, HS; Furuya, T; Haraguchi, T; Akitsu, T; Glidewell, C or send Email.. Name: 2,4-Dichlorobenzoic acid

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Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Authors Mandal, S; Saha, S; Jana, CK in AMER CHEMICAL SOC published article about C-H FUNCTIONALIZATION; 3-COMPONENT POVAROV REACTION; MICROWAVE-ASSISTED SYNTHESIS; MULTICOMPONENT REACTIONS; TERTIARY-AMINES; STRAIGHTFORWARD ACCESS; VISIBLE-LIGHT; METAL; HETEROCYCLES; ACTIVATION in [Mandal, Sumana; Saha, Subhajit; Jana, Chandan K.] Indian Inst Technol Guwahati, Dept Chem, Gauhati 780139, Assam, India in 2020, Cited 89. Safety of 2,4-Dichlorobenzoic acid. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0

A three-component annulation reaction of N-alkyl anilines, cyclic 1,3-dicarbonyl compounds, and aryl aldehydes to julolidines and lilolidines is reported. The 6 pi-electrocyclization enabled the annulation to proceed with reversed regioselectivity as compared with the annulation that occurs in the Povarov reaction. Both cyclic and acyclic N-alkyl anilines participated in the reaction to provide a wide range of julolidines and lilolidines as the single regio- and diastereoisomers in good to excellent yields.

Welcome to talk about 50-84-0, If you have any questions, you can contact Mandal, S; Saha, S; Jana, CK or send Email.. Safety of 2,4-Dichlorobenzoic acid

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Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

An article Online clean-up setup for the determination of non-fluorescent acidic pharmaceutical drugs in complex biological samples WOS:000488136700013 published article about NONSTEROIDAL ANTIINFLAMMATORY DRUGS; PERFORMANCE LIQUID-CHROMATOGRAPHY; SENSITIVE FLUORESCENCE DETERMINATION; COLUMN-SWITCHING TECHNIQUE; TANDEM MASS-SPECTROMETRY; METAL-ORGANIC FRAMEWORK; SOLID-PHASE EXTRACTION; ION CHROMATOGRAPHY; HUMAN SERUM; HPLC in [Muhammad, Nadeem; Cui, Hairong] Wuchang Univ Technol, Dept Environm Engn, Wuhan, Hubei, Peoples R China; [Muhammad, Nadeem; Guo, Dandan; Zhang, Yun; Subhani, Qamar] Zhejiang Univ, Dept Chem, Xixi Campus, Hangzhou 310028, Zhejiang, Peoples R China; [Guo, Dandan] Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China; [Intisar, Azeem; Qadir, Muhammad Abdul] Univ Punjab, Inst Chem, Lahore, Pakistan; [Subhani, Qamar] Higher Educ Dept, Lahore, Punjab, Pakistan in 2019, Cited 46. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0. Application In Synthesis of 2,4-Dichlorobenzoic acid

Analysis of acidic pharmaceuticals in complex biological samples is a challenging and formidable task due to the existence of interfering constituents within the sample matrices. Therefore, in order to avoid analytical column clogging and suppression/enhancement of signals of the analyte of interest, herein a simple, cost-effective and quick online ion chromatography based clean-up setup was introduced. This system was further coupled with a cost-effective homemade photochemically induced fluorimetric (PIF) setup for direct online conversion of non fluorescent acidic pharmaceutical drugs into their respective fluorescent species. This advantageous system was favorably applied for the determination of four non-fluorescent acidic compounds in two complex biological samples (human serum and oral fluid) with minimum labor and organic solvent consumption. At optimized conditions, the developed method has shown good sensitivity, selectivity, satisfactory recoveries (88.68-102.14%) and low limits of detection (0.35-8.10 mu g/L) with minimum or zero matrix effect.

Application In Synthesis of 2,4-Dichlorobenzoic acid. Welcome to talk about 50-84-0, If you have any questions, you can contact Muhammad, N; Guo, DD; Zhang, Y; Intisar, A; Subhani, Q; Qadir, MA; Cui, HR or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

An article New (mu-oxo)bis(mu-carboxylato)diruthenium(III) complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane ligands WOS:000652819900005 published article about STRUCTURAL-CHARACTERIZATION; OXIDATION; OXO; RUTHENIUM in [Qian, Bing-Feng; Wang, Jun-Ling; Jia, Ai-Quan; Shi, Hua-Tian; Zhang, Qian-Feng] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China in 2021, Cited 24. Safety of 2,4-Dichlorobenzoic acid. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0

Treatment of [(Me3tacn)RuCl3 center dot H2O] (Me3tacn = 1,4,7-trimethyl-1,4,7-tri-azacyclononane) with substituted benzoic acid or phenylacetic acid, in water in the presence of potassium hexafluorophosphate gave a series of cationic dinuclear Ru(III)-Ru(III) (mu-oxo)bis(mu-carboxylato) complexes [(Me3tacn)2Ru2(mu-O)(mu-OOCR)2](PF6)2 (R = Ph, 1; -py, 2; -C6H4-2-Cl, 3; -C6H3-2,4-Cl2, 4; -CH2C6H4-2-CH3, 5; -CH2C6H4-4-CH3, 6; -CH2C6H4-4-OCH3, 7; -CH2C6H4-4-Cl, 8). All complexes are well characterized by infrared, UV/Vis and mass spectroscopies, and their electrochemical properties were also investigated. The molecular structures of 1, 2 center dot 2C3H6O, 5 center dot 2C3H6O, 7 and 8 have been also established by single-crystal X-ray diffraction. The photocatalytic properties for H2 evolution by water splitting of complexes 1, 2, 3, 5, and 7 were also investigated in the paper.

Safety of 2,4-Dichlorobenzoic acid. Bye, fridends, I hope you can learn more about C7H4Cl2O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

Name: 2,4-Dichlorobenzoic acid. Li, N; Song, XZ; Wang, L; Geng, XL; Wang, H; Tang, HY; Bian, ZY in [Li, Ning; Song, Xiaozhe; Wang, Li; Geng, Xinle; Wang, Hui] Beijing Forestry Univ, Coll Environm Sci & Engn, Beijing 00083, Peoples R China; [Tang, Hanyu; Bian, Zhaoyong] Beijing Normal Univ, Coll Water Sci, Beijing 100875, Peoples R China published Single-Atom Cobalt Catalysts for Electrocatalytic Hydrodechlorination and Oxygen Reduction Reaction for the Degradation of Chlorinated Organic Compounds in 2020, Cited 55. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0.

Electrochemical reduction-oxidation processes with the aid of cathode catalysts are promising technologies for the decomposition of organic compounds. High-efficiency and low-cost catalysts for electrochemical reductive dechlorination and two-electron oxygen reduction reaction (ORR) are vital to the overall degradation of chlorinated organic compounds. This study reports electrochemical dechlorination using a single-atom Co-loaded sulfide graphene (Co-SG) catalyst via atomic hydrogen generated from the electrochemical reduction of H2O and electrolysis of hydrogen. The Co-SG electrocatalyst exhibited a remarkable performance for H2O2 synthesis with a half-wave potential of 0.70 V (vs RHE) and selectivity over 90%. The high electrochemical performance was achieved for bifunctional electrocatalysis with regard to the smaller overpotentials, faster kinetics, and higher cycling stability compared to the noble metal-based electrocatalysts. In this study, 2,4-dichlorobenzoic acid was well degraded and the TOC concentration was effectively reduced. This work introduces the preparation of a new active site for high-performance single-atom catalysts and also promotes its application in the electrochemical degradation of chlorinated organic pollutants.

Name: 2,4-Dichlorobenzoic acid. Welcome to talk about 50-84-0, If you have any questions, you can contact Li, N; Song, XZ; Wang, L; Geng, XL; Wang, H; Tang, HY; Bian, ZY or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics

In 2019 J CELL BIOCHEM published article about IN-VITRO; BIOLOGICAL EVALUATION; ANTICANCER ACTIVITY; CERVICAL-CANCER; G2/M PHASE; DERIVATIVES; DISCOVERY; SYNTHASE; DOCKING; ARREST in [Khanam, Rashmin; Hejazi, Iram Iqbal; Athar, Fareeda] Jamia Millia Islamia, Ctr Interdisciplinary Res Basic Sci, New Delhi 110025, India; [Kumar, Raj; Meena, Ramovatar; Rajamani, Paulraj] Jawaharlal Nehru Univ, Sch Environm Sci, New Delhi, India; [Shahabuddin, Syed] Sunway Univ, RCNMET, Sch Sci & Technol, Selangor, Malaysia; [Yadav, Nitin] Indian Inst Technol, Dept Chem, New Delhi, India; [Bhat, Asif Iqbal] Cluster Univ, Dept Chem, Sri Pratap Coll, Srinagar, Jammu & Kashmir, India in 2019, Cited 43. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0. Product Details of 50-84-0

N-benzhydrylpiperazine and 1,3,4-oxadiazoles are pharmacologically active scaffolds which exhibits significant inhibitory growth effects against various cancer cells, however, antiproliferation effects and the underlying mechanism for inducing apoptosis for aforementioned scaffolds addressing HeLa cancer cells remains uncertain. In this study, N-benzhydrylpiperazine clubbed with 1,3,4-oxadiazoles (4a-4h) were synthesized, subsequently characterized using high resolution spectroscopic techniques and eventually evaluated for their antiproliferation potential by inducing apoptosis in HeLa cancer cells. The MTT assay screening results revealed that among all, compound 4d (N-benzhydryl-4-((5-(4-aminophenyl)-1,3,4-oxadiazol-2-yl)methyl)piperazine) in particular, exhibited IC (50) value of 28.13 +/- 0.21g/mL and significantly inhibited the proliferation of HeLa cancer cells in concentration-dependent manner. The in vitro anticancer assays for treated HeLa cells resulted in alterations in the cell morphology, reduction in colony formation, and inhibition of cell migration in concentration-dependent treatment. Furthermore, G2/M phase arrest, variations in the nuclear morphology, degradation of chromosomal DNA confirmed the ongoing apoptosis in treated HeLa cells. Increase in the expression of cytochrome C and caspase-3 confirmed the involvement of intrinsic mitochondrial pathway regulating the cell death. Also, elevation in reactive oxygen species level and loss of mitochondrial membrane potential signified that compound 4d induced apoptosis in HeLa cells by generating the oxidative stress. Therefore, compound 4d may act as a potent chemotherapeutic agent against human cervical cancer.

Product Details of 50-84-0. Welcome to talk about 50-84-0, If you have any questions, you can contact Khanam, R; Kumar, R; Hejazi, II; Shahabuddin, S; Meena, R; Rajamani, P; Yadav, N; Bhat, AI; Athar, F or send Email.

Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics