Category: 4569-86-2

On June 2, 2005, Grieser, Udo; Brunner, Heiko; Dahms, Wolfgang published a patent.Recommanded Product: 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the patent was Preparation of halogenated or pseudohalogenated monomeric phenazinium compounds useful in acidic baths for electrolytically depositing copper.. And the patent contained the following:

Title compounds [I; R1, R2, R4, R7, R71, R8, R9 = H, halo, amino, aminoalkyl, OH, cyano, SCN, OCN, SH, CO2H, alkyl, (substituted) aryl, heteroaryl, etc.; R5 = alkyl, (substituted) aryl, heteroaryl; X = halo, pseudohalo; A- = acid anion], were prepared Thus, 3,7-diamino-2,8-dimethyl-5-phenylphenazinium chloride in 50% HBF4 at 50-60° was treated with aqueous NaSCN/NaNO2 over 1 h followed by stirring for an addnl. 1 h to give 64% 7-amino-2,8-dimethyl-3-thiocyanato-5-phenylphenazinium tetrafluoroborate. The latter in a Cu plating bath gave a brilliant, mirrorlike deposit without burns with invisible brush lines, indicative of an excellent leveling effect. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Recommanded Product: 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to halogenated pseudohalogenated monomeric phenazinium preparation copper electroplating additive, Heterocyclic Compounds (More Than One Hetero Atom): Pyrazines and Quinoxalines (Including Piperazines) and other aspects.Recommanded Product: 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On May 17, 1988, Anzai, Mitsutoshi; Yamaguchi, Masahiko; Utsunomiya, Akira; Gonda, Michihiro published a patent.Synthetic Route of 4569-86-2 The title of the patent was Dihydrophenazine derivatives containing amino group at 3- or 7-position for thermal recording. And the patent contained the following:

The title compounds I [R1 = electron acceptor group-containing aryl or alkyl; R2, R6 = lower alkyl; R3 = (un)substituted aryl or alkyl; R4, R5 = (un)substituted aryl or lower alkyl] are prepared I, which are thermally stable and stable under light, develop bright magenta colors on heating with inorganic nitrates or nitrites or organic nitrates. 3-Amino-7-diethylamino-5-phenylphenazonium chloride was treated with Na2S2O4 and 20% aqueous NaOH in aqueous toluene at 60°, N was introduced, the solution was adjusted to pH ∼4.0 with AcOH, treated with salicylaldehyde at 60° for 3 h, treated with 2-CF3C6H4COCl in the presence of NaOH at 20-30° for 3 h, and hydrolyzed with 1N HCl at 30-35° to give 57.7% I (R1 = 2-CF3C6H4, R2 = R6 = H, R3 = Ph, R4 = R5 = Et) (II). An acetone solution containing II, Zn(NO3)2.H2O, and poly(Me methacrylate) was coated on paper to give a thermal recording material. A bright red-purple color was developed on heating. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Synthetic Route of 4569-86-2

The Article related to aminodihydrophenazine derivative preparation thermal recording, phenazine aminodihydro derivative thermal recording, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Information Recording and Storage and other aspects.Synthetic Route of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On August 18, 2022, Knocke, Frank published a patent.HPLC of Formula: 4569-86-2 The title of the patent was Improved bleaching. And the patent contained the following:

The present invention relates to UV-vis photopolymerizable compositions and to elements produced therefrom and to their use. It specifically relates to recording materials for optical elements with refractive index modulation, in particular holograms. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).HPLC of Formula: 4569-86-2

The Article related to improved bleaching, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Information Recording and Storage and other aspects.HPLC of Formula: 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On August 17, 2022, Knocke, Frank published a patent.Related Products of 4569-86-2 The title of the patent was Improved bleaching. And the patent contained the following:

The present invention relates to UV-vis photopolymerizable compositions and to elements produced therefrom and to their use. It specifically relates to recording materials for optical elements with refractive index modulation, in particular holograms. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Related Products of 4569-86-2

The Article related to improved bleaching, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Information Recording and Storage and other aspects.Related Products of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 16, 2010, Batchelor, Stephen Norman; Bird, Jayne Michelle; Chen, Wei; Tao, Qingsheng; Wang, Jinfang published a patent.Name: 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the patent was Cationic dye polymers. And the patent contained the following:

Disclosed is a detergent composition comprising from 2 to 70 weight-% of a surfactant together with from 0.0001 to 50 weight-% of a dye-polymer of mol. weight of at least 500, wherein the dye-polymer is obtainable by polymerization of: (a) a dye monomer, the dye monomer being an alkene covalently bound to a cationic charged dye, the dye monomer having a molar extinction coefficient at a wavelength in the range 400 to 700 nm of at least 1000 mol-1Lcm-1, preferably greater than 4000 mol-1Lcm-1, and (b) one or more further alkene comonomer(s), the alkene monomer(s) having a molar extinction coefficient at a wavelength in the range 400 to 700 nm, which is less than 100 mol-1Lcm-1, preferably less than 10 mol-1Lcm-1, wherein the dye monomer is cationically charged in an aqueous solution at a pH in the range from 7 to 11. Thus, a dye monomer was prepared by the reaction of methylene violet 3 RAX and acryloyl chloride in the presence of sodium dicarbonate, the resulting dye monomer was polymerized via radical polymerization with di-Me aminoethyl methacrylate, to obtained the dye polymer, which was tested for dye deposition, the polymer was added to give 5 ppm in a wash solution, containing 15% linear alkyl benzenesulfonate (LAS) surfactant, 30% Na2CO3, 40% NaCl, remainder minors included calcite and fluorescer, the fabrics washed were; polyester (microfiber), nylon-elastane (80:20) and cotton fabric, results showed that the dye-polymer deposits to the fabrics, an added advantage is that the dye-polymer also facilitates soil removal and alter fabric feel. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Name: 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to cationic azine dye polymer laundry detergent treatment washing textile, basic violet blue derivative cationic dye polymer fabric detergent, Surface Active Agents and Detergents: Dry-Cleaning Solvents and Laundering Detergents (Cleaning Of Finished Garments) and other aspects.Name: 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 29, 2010, Batchelor, Stephen Norman; Bird, Jayne Michelle; Chen, Honggang; Meng, Sheng; Tao, Qingsheng; Wang, Jinfang published a patent.Application of 4569-86-2 The title of the patent was Dye polymers for use in laundry applications. And the patent contained the following:

The present invention provides dye polymers for use in laundry applications. The dye polymers may be used to shade textiles or provide color cues for laundry detergent and fabric conditioners. The dye polymers also provide soil removal benefits. In one aspect the present invention provides a method for obtaining a dye-polymer, the method comprising the step of reacting a polymer with a primary amine of a dye to form the dye-polymer. The polymer has a group for reacting with the primary amine, the group selected from: isocyanate; oxazolone; epoxide; ester, and anhydride, preferably epoxide or anhydride, most preferably anhydride. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Application of 4569-86-2

The Article related to dye polymer laundry detergent, Surface Active Agents and Detergents: Dry-Cleaning Solvents and Laundering Detergents (Cleaning Of Finished Garments) and other aspects.Application of 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On December 29, 2010, Batchelor, Stephen Norman; Bird, Jayne Michelle; Chen, Honggang; Meng, Sheng; Tao, Qingsheng; Wang, Jinfang published a patent.Formula: C22H23ClN4 The title of the patent was Dye polymers for use in laundry applications. And the patent contained the following:

The present invention provides dye polymers for use in laundry applications. The dye polymers may be used to shade textiles or provide color cues for laundry detergent and fabric conditioners. The dye polymers also provide soil removal benefits. In one aspect the present invention provides a method for obtaining a dye-polymer, the method comprising the step of reacting a polymer with a primary amine of a dye to form the dye-polymer. The polymer has a group for reacting with the primary amine, the group selected from: isocyanate; oxazolone; epoxide; ester, and anhydride, preferably epoxide or anhydride, most preferably anhydride. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Formula: C22H23ClN4

The Article related to dye polymer laundry detergent, Surface Active Agents and Detergents: Dry-Cleaning Solvents and Laundering Detergents (Cleaning Of Finished Garments) and other aspects.Formula: C22H23ClN4

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On July 31, 2016, Pitre, Spencer P.; McTiernan, Christopher D.; Scaiano, Juan C. published an article.Recommanded Product: 4569-86-2 The title of the article was Library of Cationic Organic Dyes for Visible-Light-Driven Photoredox Transformations. And the article contained the following:

Organic dyes can be excellent catalysts for photoredox chem., offering low price, low toxicity, and an exceptional range of available materials. Their use has been limited because in comparison to their transition-metal catalysts the spectroscopic, kinetic, and electrochem. information available is far more limited. To remediate this situation, we have determined the necessary data for 14 readily available dyes with excellent potential as photoredox catalysts. We have also demonstrated the utility of these dyes through visible-light-mediated reductive dehalogenation and Aza-Henry reactions. We envision that this collection of data will lead to an increase in the use of cationic dyes in photoredox processes because users will find the necessary information readily available. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Recommanded Product: 4569-86-2

The Article related to cationic organic dye visible light photoredox transformation, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Recommanded Product: 4569-86-2

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On May 14, 2009, Jonnalagadda, S. B.; Shezi, M. N. published an article.Quality Control of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the article was Kinetics and mechanism of the oxidation of methylene violet by bromate at acidic pH and the dual role of bromide ion. And the article contained the following:

A phenazinium-type dye during oxidation by bromate ion under acidic conditions exhibited a complex nonlinear behavior. The intricate kinetics of reaction of 3-amino-7-(dimethylamino)-5-phenylphenazium chloride (MV+) with acidic bromate was investigated using the stopped flow technique. Under excess acid and bromate concentration conditions, MV+ exhibited a very slow reaction initially but a very rapid reaction after an induction time. The reaction had first-order dependence on both H+ and BrO3- ions. The overall stoichiometric reaction is 2MV+ + 2BrO3- + H2O → 2MP + 2HONEt2 + N2O + 2H+ + 2Br-, where MP is dioxophenylphenazine. The active roles of various bromo and oxybromo species in the mechanism are discussed. The rapid kinetics of the direct reaction of bromine with MV+ is also reported. A 19-step mechanism, consistent with the exptl. data and validated by simulations using Simkine-2, is proposed. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Quality Control of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to methylene violet dye acidic bromate oxidation kinetics mechanism, Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers: Structure Correlation With Physical Properties and other aspects.Quality Control of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

On September 21, 2006, Saijo, Shingo; Yamato, Shigeru; Matsunami, Takashi; Hashimoto, Morihito published a patent.Reference of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride The title of the patent was Method for adjusting plating bath by decomposing organic component without giving adverse effect to plating ability. And the patent contained the following:

Peroxo mono-sulfate is added to the plating bath to oxidation-decompose organic compounds in the plating bath. The plating bath is halogen-containing electroplating bath or electroless plating bath. Optionally, the plating bath is a CuSO4 plating bath. The experimental process involved the reaction of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride(cas: 4569-86-2).Reference of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

The Article related to cupric sulfate copper plating bath organic component decomposition peroxosulfate, Nonferrous Metals and Alloys: Surface Treatment, Metallic and Nonmetallic Coating, Sealing, Cleaning, Polishing, Etching, and Pickling and other aspects.Reference of 3-Amino-7-(diethylamino)-5-phenylphenazin-5-ium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics