Category: 18987-59-2

In 2020,Chemical Communications (Cambridge, United Kingdom) included an article by Tao, Mengna; Li, Wenbo; Zhang, Junliang. Quality Control of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II). The article was titled 《Pd/Xiang-Phos-catalyzed enantioselective intermolecular carboheterofunctionalization of norbornene and norbornadiene》. The information in the text is summarized as follows:

A highly enantioselective Pd/Xiang-Phos-catalyzed carboheterofunctionalization of norbornene is described, giving a direct access to various chiral norbornane-fused dihydrofurans and dihydropyrroles. This synthetic methodol. provides the first example of asym. carboetherification of norbornene, and also tolerates norbornadiene well. The experimental part of the paper was very detailed, including the reaction process of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2Quality Control of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II))

Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. Quality Control of Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The author of 《Synthesis and characterization of a cyclometallated palladium(II) complex with (2-diphenylphosphino)ethylamine》 were Elsegood, Mark R. J.; Han, Jiabao; Smith, Martin B.; Wu, Shimeng. And the article was published in Phosphorus, Sulfur and Silicon and the Related Elements in 2019. Category: chlorides-buliding-blocks The author mentioned the following in the article:

Reaction of com. available Ph2PCH2CH2NH2 with {PdCl(C9H12N)}2 (2:1) in CH2Cl2 afforded, instead of Pd(Cl)(P-Ph2PCH2CH2NH2)(C9H12N) , the cationic complex [Pd(P,N-Ph2PCH2CH2NH2)(C9H12N)]Cl which was characterized by single crystal x-ray crystallog. The lack of reactivity of towards Rhodamine 6G can therefore be rationalized. In the part of experimental materials, we found many familiar compounds, such as Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2Category: chlorides-buliding-blocks)

Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics