Category: 13820-53-6

Polar bonds induced strong Pd-support electronic interaction drives remarkably enhanced oxygen reduction activity and stability was written by Li, Qiaoling;Wang, Xuewei;Xie, Zhi;Peng, Xingkai;Guo, Lingli;Yu, Xiaofei;Yang, Xiaojing;Lu, Zunming;Zhang, Xinghua;Li, Lanlan. And the article was included in Applied Catalysis, B: Environmental in 2022.Quality Control of Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

The strong metal-support interaction (SMSI) effect is attractive for improving the activity and durability of metal catalyst. Here, we uncovered that the strong polar bond in support can significantly boost the electrocatalytic oxygen reduction activity and durability of Pd nanoparticles (NPs). The mass-specific activity and surface-specific activity of optimized Pd/p-BNO at 0.90 V (vs.RHE) is almost 1.9 and 2.2 times higher than that of com. Pt/C catalyst, resp. By means of a joint exptl. and computational study, the enhanced activity of Pd/p-BNO stems from the electron directly transfer through the strong polar O-B bonds from support to Pd NPs leading to the electron-rich Pd surface. Moreover, the strong bonding effect of the caused by polarity bond effectively improves the stability of Pd/p-BNO. This progress demonstrates the vital role of polar chem. bonds in support on inducing SMSI effect, which might open up new opportunities in designing superior heterogeneous catalysts. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Quality Control of Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Quality Control of Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

N-doping induced lattice-strained porous PdIr bimetallene for pH-universal hydrogen evolution electrocatalysis was written by Mao, Qiqi;Deng, Kai;Wang, Wenxin;Wang, Peng;Xu, You;Wang, Ziqiang;Li, Xiaonian;Wang, Liang;Wang, Hongjing. And the article was included in Journal of Materials Chemistry A in 2022.Application of 13820-53-6 The following contents are mentioned in the article:

Porous Pd-based metallene with highly curved, ultrathin and porous architectural features is a promising candidate for the hydrogen evolution reaction (HER), and structural design and component modification can effectively enhance its performance. Herein, we present a powerful approach to boost the HER performance of porous PdIr bimetallene through N-doping, which can effectively modulate the electronic structure and induce the strain effect of the designed N-doped porous PdIr bimetallene (N-PdIr bimetallene). The porous N-PdIr bimetallene exhibits superior all-pH HER activity and stability. To generate a cathodic c.d. of 10 mA cm^-2, the required overpotential for the porous N-PdIr bimetallene is 26, 34 and 59 mV in 0.5 M H₂SO₄, 1 M KOH and 1 M phosphate buffer solution (PBS), resp., which outperform those of com. Pt/C. The proposed N-doping approach is a very powerful strategy for boosting metallene electrocatalytic performance, beyond the HER. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Application of 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Application of 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Mesoporosity-Enabled Selectivity of Mesoporous Palladium-Based Nanocrystals Catalysts in Semihydrogenation of Alkynes was written by Lv, Hao;Qin, Huaiyu;Sun, Mingzi;Jia, Fengrui;Huang, Bolong;Liu, Ben. And the article was included in Angewandte Chemie, International Edition in 2022.Computed Properties of Cl4Na2Pd The following contents are mentioned in the article:

We reported mesoporosity engineering as a general strategy to promote semihydrogenation selectivity of palladium (Pd)-based nanobundles catalysts. The best mesoporous PdP displayed full conversion, remarkable activity, excellent selectivity, and high stability in semihydrogenation of 1-phenyl-1-propyne, all of which are remarkably better than com. Lindlar catalysts. Mechanistic investigations ascribed high semihydrogenation selectivity to the continuous crystalline framework and penetrated mesoporous channel of catalysts that weakened the adsorption and interaction capacity of alkenes and thus inhibited over-hydrogenation of alkenes to industrially unfavorable alkanes. D. functional theory calculations further demonstrated that convex crystalline mesoporosity of nanobundles catalysts electronically optimized the coordination environment of Pd active sites and energetically changed hydrogenation trends, resulting in a superior semihydrogenation selectivity to targeted alkenes. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Computed Properties of Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Computed Properties of Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Highly efficient and recyclable amorphous Pd(II)/crystal Pd(0) catalyst for boosting Suzuki reaction in aqueous solution was written by Zhao, Yong;Huang, Zhongning;Wang, Lianmeng;Chen, Xiangyu;Zhang, Yan;Yang, Xiuqin;Pang, Dawei;Kang, Jianxin;Guo, Lin. And the article was included in Nano Research in 2022.Recommanded Product: 13820-53-6 The following contents are mentioned in the article:

Ultrafine and highly dispersed Pd nanoparticles have drawn considerable attention with high activity, selectivity and at. efficiency. In this paper, amorphous Pd(II)-complex solid spheres with ≈ 5 nm Pd nanoparticles loaded on were successfully achieved through a simple and gentle one-pot solution method with vitamin B1 simultaneously as complexing agent and reducing agent. An ultrathin mesoporous SiO₂ shell was then coated at the surface of Pd(II-0) spheres as the armor which could prevent the dissolution of Pd(II) during the catalytic process. The combination of Pd(II) and Pd(0) endowed Pd(II-0)/m-SiO₂ catalyst an excellent performance in eco-friendly aqueous media Suzuki reactions. The high activity, productivity and recyclability were all comparable with the best Pd catalysts ever reported. The ingenious formation of amorphous Pd(II)/crystal Pd(0) with enhanced catalytic performances provides a new, scalable strategy to practical promotion of Suzuki cross-coupling reactions. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Recommanded Product: 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Recommanded Product: 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Trimethyl chitosan coated palladium nanoparticles as a photothermal agent and its in vitro evaluation in 2D and 3D model of breast cancer cells was written by Bangde, Prachi;Pant, Tejal;Gaikwad, Ganesh;Jain, Ratnesh;Dandekar, Prajakta. And the article was included in Colloids and Surfaces, B: Biointerfaces in 2022.Related Products of 13820-53-6 The following contents are mentioned in the article:

The potential of palladium has been scantily explored in biomedical applications. In the present study, palladium nanoparticles (PdNPs) were synthesized and were successfully coated with trimethyl-chitosan (TMC) to improve their biocompatibility. Coating with TMC improved the nanoparticle accumulation in MDAMB231 breast cancer cells, compared to nanoparticles coated with native chitosan. The TMC coated palladium nanoparticles (TMC/PdNPs) exhibited good biocompatibility and physiol. stability, as compared to the plain(uncoated) PdNPs. TMC coated PdNPs resulted in photothermal therapeutic effect, when irradiated with a near-IR (NIR) laser having the wavelength of 808-nm. The TMC/PdNPs resulted in good cytotoxic effect upon laser treatment in both, 2D monolayers and 3D spheroids of MDAMB231 cells, the latter mimicking the tumor microenvironment. These results clearly indicated that TMC/PdNPs acted as ideal photothermal agents for anti-cancer therapy in combination with a non-invasive near-IR laser. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Related Products of 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Related Products of 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Ultrasonic assisted preparation of ultrafine palladium supported on NiFe-layered double hydroxides for p-nitrophenol degradation was written by Zhou, Xuan;Shi, Jiaming;Bai, Xuefeng. And the article was included in Environmental Science and Pollution Research in 2022.Reference of 13820-53-6 The following contents are mentioned in the article:

NiFe-layered double hydroxide (NiFe-LDH)-loaded ultrafine Pd nanocatalysts (Pd/NiFe-LDHs) were prepared by a facile ultrasonic-assisted in situ reduction technol. without any stabilizing agents or reducing agents. Pd/NiFe-LDHs were characterized by FT-IR, XRD, XPS, and TEM. PdNPs are uniformly dispersed on NiFe-LDHs with a particle size distribution of 0.77-2.06 nm and an average particle size of 1.43 nm. Hydroxyl groups in Fe-OH and Ni-OH were dissociated into hydrogen radicals (·H) excited by ultrasound, and ·H reduced Pd²⁺ to ultrafine PdNPs. Then, Pd was coordinated with O in Ni-O and Fe-O, which improved the stability of the catalysts. Pd/NiFe-LDHs completely degraded 4-NP in 5 min, and the TOF value was 597.66 h^-1, which was 16.7 times that of com. Pd/C. The 4-NP conversion rate remained at 98.75% over Pd/NiFe-LDHs after 10 consecutive catalytic cycles. In addition, the catalyst also has high catalytic activity for the reduction of Congo red, methylene blue, and methyl orange by NaBH4. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Reference of 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Reference of 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Precisely deposited Pd on ZnO (002) facets derived from complex reduction strategy for methanol steam reforming was written by Chen, Yue;Dai, Qiguang;Zhang, Qiyao;Huang, Yongmin. And the article was included in International Journal of Hydrogen Energy in 2022.Name: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

Pd/ZnO catalysts are promising for onboard hydrogen production through methanol steam reforming (MSR), but their selectivity still requires improving. In this research, a flower-like spherical ZnO material with mainly exposed (002) facet was prepared through surfactant-assisted hydrothermal method. The surfactant tartaric groups also serve as coordinating groups to adsorb Pd²⁺ to form a complex, which is further reduced to metallic Pd. By virtue of preferential adsorption of the surfactant on (002) facet, Pd particles are confined to (002) facet. The calcined PdO-ZnO-T-X catalyst shows highly dispersed PdO nanoparticles. Characterization results suggest that strong interaction between ZnO (002) facet and small PdO particles can facilitate complete PdO reduction and PdZn formation, and can effectively retard PdZn decomposition under oxidizing atm. This research discloses structure-performance relationship of Pd/ZnO catalysts and provides a novel strategy for further improving their MSR performance. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Name: Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Name: Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Dual cocatalyst modified CdS achieving enhanced photocatalytic H₂ generation and benzylamine oxidation performance was written by Sun, Binshu;Zheng, Jianhong;Yin, Dewu;Jin, Huile;Wang, Xin;Xu, Quanlong;Liu, Aili;Wang, Shun. And the article was included in Applied Surface Science in 2022.Product Details of 13820-53-6 The following contents are mentioned in the article:

Cocatalyst can greatly facilitate the charge separation efficiency and decrease the activation barrier of a specific reaction, thus contributing the improved photocatalytic performance. Herein, PdS/CdS/MoS₂ was synthesized via a facile microwave-assisted approach. Owing to the coexistence of PdS and MoS₂, resp. serving as oxidation and reduction cocatalyst, PdS/CdS/MoS₂ displayed enhanced photocatalytic performance in both hydrogen production (6610 μmol·g^-1·h^-1) and benzylamine oxidation (87% conversion) in comparison with the individual and binary composite counterparts. The improved photocatalytic activity was mainly attributed to the high charge separation efficiency and lowed activation barrier. Furthermore, the introduction of PdS can timely extract photogenerated holes from CdS, which effectively inhibits the photo-corrosion of CdS, endowing it with high stability. This work paves the way for developing efficient chalcogenide photocatalysts. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Product Details of 13820-53-6).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Product Details of 13820-53-6

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Palladium(II) 2-mercaptobenzamide (o-SC₆H₄CONH₂) complexes: Crystal structure of trans-[Pd(o-SC₆H₄CONH₂)₂(PPh₃)₂] was written by Al-Jibori, Subhi A.;Al-Jibori, Ghassan H. H.;Saleh, Syran S.;Al-Janabi, Ahmed S. M.;Laguna, Mariano;Wagner, Christoph. And the article was included in Polyhedron in 2022.COA of Formula: Cl4Na2Pd The following contents are mentioned in the article:

The reaction of [Hg(mbm)₂] (mbm = o-SC₆H₄CONH₂) with Na₂S releases Na[mbm] which reacts with Pd(II) salts to give [Pd(mbm)₂]. While its precise mol. structure is unknown, [Pd(mbm)₂] reacts with two equivalent of PPh₃ to afford trans-[Pd(κ¹-mbm)₂(PPh₃)₂] in which the mbm ligands bind through a sulfur atom. With dppf, a similar complex, [Pd(κ¹-mbm)₂(κ²-dppf)], is formulated with the mbm ligands being forced into a relative cis orientation. With dppm, a mixture of mononuclear [Pd(κ¹-mbm)₂(dppm)] and binuclear [Pd(κ¹-mbm)₂(μ-dppm)]₂ results. The new complexes have been characterized by IR, ¹H and ³¹P{¹H} NMR, molar conductivity and elemental anal., and in addition, the mol. structure of trans-[Pd(κ²-mbm)₂(PPh₃)₂] was confirmed by x-ray diffraction. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6COA of Formula: Cl4Na2Pd).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.COA of Formula: Cl4Na2Pd

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Triclosan detoxification through dechlorination and oxidation via microbial Pd-NPs under aerobic conditions was written by Chen, Yuan;Chen, Yuancai;Jia, Jianbo;Yan, Bing. And the article was included in Chemosphere in 2022.Recommanded Product: Sodium tetrachloropalladate(II) The following contents are mentioned in the article:

The present study focuses on the successful preparation of microbial palladium nanoparticles (Pd-NPs). The even distribution of Pd in the periplasmic space of B. megaterium Y-4 cells is characterized using a transmission electronic microscopy (TEM) and scanning electron microscope (SEM). XPS and X-ray diffraction (XRD) revealed the domination of Pd (0) in Pd-NPs. The microbial Pd-NPs were selected to detoxify triclosan (TCS). Liquid chromatog.-mass spectrometry (LC-MS) was used to analyze the intermediate products of dechlorination and oxidization. Free radicals quenching and 5,5-dimethyl-1-pyrroline N-oxide (DMPO) capturing experiments confirmed the crucial contribution of at. H• and O·-2 to TCS degradation Besides, TCS degradation by microbial Pd-NPs could alleviate the cytotoxicity of TCS polluted water. Meanwhile, great circulating utilization of microbial Pd-NPs was obtained in degrading TCS. Corresponding findings in the present study could provide new insight into the role of microbial Pd-NPs in detoxifying pollutants. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Recommanded Product: Sodium tetrachloropalladate(II)).

Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Recommanded Product: Sodium tetrachloropalladate(II)

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics