Category: 122-18-9

The Use of AOBH-DEHP Molecular Probe to Characterize BHDC Reverse Micelles Interfaces. Insights on the Interfacial Water Structure was written by Crosio, Matias A.;Silber, Juana J.;Moyano, Fernando;Correa, N. Mariano;Falcone, R. Dario. And the article was included in ChemistrySelect in 2017.Synthetic Route of C25H46ClN The following contents are mentioned in the article:

This work presents the use of the mol. probe: 3,6-bis(dimethylamino) acridinium bis-(2-ethylhexyl) phosphate salt, AOBH-DEHP. This probe is used to gain insights into the properties of the benzene/benzyl-n-hexadecyldimethylammonium chloride (BHDC)/water reverse micelles (RMs) interfaces. The techniques employed were absorption and emission spectroscopy in addition to the steady-state and, time-resolved fluorescence emission. For BHDC RMs without water addition, AOBH-DEHP can be used to determine the critical micellar concentration, CMC. Upon addition of water, we detect, at concentrations of BHDC lower < 1×10^-2 M, a proton transfer process from the AOBH⁺ cation to the DEHP^– anion producing AOB species. However, for [BHDC] > 10^-2 M, when the RMs is completely formed this process is reverted because water mols. at the interface interact with the cationic polar head of BHDC through the oxygen non-bonding electron pair enhancing their hydrogen bond ability and acidity, hence it can easily transfer a proton to AOB species to form AOBH⁺. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Synthetic Route of C25H46ClN).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Synthetic Route of C25H46ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Successive Resonances for Ion Ejection at Arbitrary Frequencies in an Ion Trap was written by Snyder, Dalton T.;Cooks, R. Graham. And the article was included in Journal of the American Society for Mass Spectrometry in 2016.Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride The following contents are mentioned in the article:

The use of successive resonances for ion ejection is demonstrated here as a method of scanning quadrupole ion traps with improvement in both resolution and sensitivity compared with single frequency resonance ejection. The conventional single frequency resonance ejection waveform is replaced with a dual-frequency waveform. The two included frequencies are spaced very closely and their relative amplitudes are adjusted so that the first frequency that ions encounter excites them to higher amplitudes where space charge effects are less prominent, thereby giving faster and more efficient ejection when the ions come into resonance with the second frequency. The method is applicable at any arbitrary frequency, unlike double and triple resonance methods. However, like double and triple resonance ejection, ejection using successive resonances requires the radiofrequency and AC waveforms to be phase-locked to retain mass accuracy and mass precision. The improved performance is seen in mass spectra acquired by radiofrequency amplitude scans (resonance ejection) as well as by secular frequency scans. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Spontaneous catanionic vesicles formed by the interaction between an anionic β-cyclodextrins derivative and a cationic surfactant was written by Silva, O. Fernando;de Rossi, Rita H.;Correa, N. Mariano;Silber, Juana J.;Falcone, R. Dario. And the article was included in RSC Advances in 2018.Synthetic Route of C25H46ClN The following contents are mentioned in the article:

The present work shows the synthesis of a new type of catanionic surfactant, ModCD14-BHD, which involves an anionic amphiphilic cyclodextrin and the cationic benzyl-n-hexadecyldimethylammonium (BHD). It is obtained from the simple association of the cationic surfactant benzyl-n-hexadecyldimethylammonium chloride (BHDC) and β-cyclodextrin (β-CD) monosubstituted with an alkenyl succinate group (Mod-β-CD14). ModCD14-BHD form unilamellar vesicles spontaneously in water, while the individual components (BHDC and Mod-β-CD14) do not. The vesicles were character-ized by dynamic light scattering (DLS), transmission electron microscopy (TEM), SEM (SEM) and ¹H NMR techniques. We suggest that the formation of an inclusion complex between some of the cyclodextrins units and the long hydrocarbon moiety of the cationic surfactant play a crucial role in the vesicles formation. Besides, some or the cavities are available to interact with an external guest. We think that the new surfactant mol. has properties that may lead to important applications in biomedical and pharmaceutical sciences. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Synthetic Route of C25H46ClN).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.Synthetic Route of C25H46ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Rapid analysis of anionic and cationic surfactants in water by paper spray mass spectrometry was written by Min, Ke;Yang, Qinglan;Zhong, Xiangjing;Yan, Donglan;Luo, Wei;Fang, Zhengfa;Xiao, Jing;Ma, Ming;Chen, Bo. And the article was included in Analytical Methods in 2021.Safety of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride The following contents are mentioned in the article:

The discharge of wastewater containing surfactants and other industrial pollutants is contaminating the world’s water resources which should be taken seriously. This paper describes a paper spray mass spectrometric (PS-MS) method for rapid and quant. anal. of anionic and cationic surfactants in water samples. Eight cationic surfactants and four anionic surfactants can be simultaneously determined in pos. or neg. mode without sample pretreatment and chromatog. separation The PS-MS anal. time was only 10 s. Under optimized conditions, the method presented a suitable linear range (1-80μg mL-1, linear regression coefficients (R2) higher than 0.995 for cationic surfactants, R2 higher than 0.990 for anionic surfactants), a low limit of detection (0.05-0.35μg mL-1 for cationic surfactants and 0.20-0.35μg mL-1 for anionic surfactants), and satisfactory recovery values (97.3-106.1%). The method validation indicated that the method precision and accuracy were satisfactory. The results demonstrated that PS-MS is especially suitable for the high-throughput anal. of surfactants in water samples. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Safety of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Safety of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Extended delivery of non-steroidal anti-inflammatory drugs through contact lenses loaded with Vitamin E and cationic surfactants. was written by Torres-Luna, Cesar;Hu, Naiping;Tammareddy, Tejaswi;Domszy, Roman;Yang, Jeffrey;Wang, Nam Sun;Yang, Arthur. And the article was included in Contact lens & anterior eye in 2019.Computed Properties of C25H46ClN The following contents are mentioned in the article:

The purpose of this study is to extend drug release from ACUVUE Oasys® and ACUVUE TruEye® silicone hydrogel contact lenses by incorporation of vitamin E in conjunction with a cationic surfactant. In ACUVUE Oasys® and ACUVUE TruEye®, the release of ketorolac tromethamine and flurbiprofen sodium is extended from hours to several days for 11% and 21% vitamin E, (weight of vitamin E / weight of dry lens) but with a considerable reduction in the amount of drug released. Cetalkonium chloride and stearylamine increased the drug loading capacity which was otherwise compromised by the addition of vitamin E in the contact lenses. In the case of diclofenac sodium, a sustained release over 150 h for both contact lenses can be achieved. It was found that the release-time-increase factor due to vitamin E has a linear dependence with the octanol-water partition coefficient of the drug in ACUVUE Oasys®. The results in this study show that contact lenses loaded with vitamin E in conjunction with cationic surfactants achieved sustained release of non-steroidal anti-inflammatory drugs (NSAIDs) within the therapeutic window. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Computed Properties of C25H46ClN).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Computed Properties of C25H46ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Surface tensiometry study of the interfacial phenomena in the mixed surfactant solutions of sodium di-2-ethylhexylsulfosuccinate (AOT) and hexadecyl benzylammonium chloride (HDBAC) was written by Omer, Maab K.;Ali, Inaam H.;Kareem, Sameer H.. And the article was included in Chemical Papers in 2022.Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride The following contents are mentioned in the article:

Surface behavior and interfacial mixing properties of the cationic surfactant hexadecyl benzylammonium chloride (HDBAC) and anionic one sodium di-2-ethylhexylsulfosuccinate (AOT) were studied at four temperatures (288-318 K) in an aqueous solution using tensiometry method. The critical micelle concentration (CMC) for individual and binary mixture was evaluated to gain the interfacial parameters such as surface excess concentration, min. area per mols. of single and mixture system, and interfacial free energy. The results show expansion of min. area per mols. of binary mixture (about 1000-2500 Ų) compared with that of single surfactants (about 100-250 Ų). Based on Rosen′s model, the synergism parameters were calculated and the data obtained show that neg. values of mol. interaction parameter (β^σ ) indicate an attractive interaction between the surfactants, where the more neg. value was – 7.63146 for the mixture of 90% AOT and 10% HDBAC. Also, the values of activity coefficients less than unity indicate a strong synergistic interaction between the two surfactants. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Application In Synthesis of N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The effects of polymeric molar mass, concentration, and adding of different surfactants on the electrospun poly(vinyl alcohol) nanofibers was written by Eren Boncu, Tugba;Ozdemir, Nurten. And the article was included in Latin American Journal of Pharmacy in 2019.SDS of cas: 122-18-9 The following contents are mentioned in the article:

The aim of the study is to produce nanofibers using electrospinning with aqueous poly(vinyl alc.)(PVA) solutions Effect of PVA molar mass and concentration and effect of surfactants on the properties of PVA solutions and on the diameter size of electrospun PVA nanofibers were examined It was shown that the viscosity of the polymer solution was increased by increasing PVA molar mass and concentration To obtain the nanofiber structure, optimum PVA_18.000 (molar mass = 18,000 g/mol) and PVA_50.000 (molar mass = 50,000 g/mol) concentrations were found to be 30% weight/weight and 20% weight/weight, resp. With the addition of anionic and cationic surfactants, the viscosity and the elec. conductivity of the polymer solutions were increased while the surface tension and fiber diameters of the nanofibers were decreased (p < 0.05). However, nonionic surfactants have shown no statistically significant effect (p > 0.05). As a result, electrospun nanofibers were produced using PVA and water and the diameters and properties of nanofibers can be modified by controlling the parameters examined in the study. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9SDS of cas: 122-18-9).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.SDS of cas: 122-18-9

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Tailored Nanoscale Plasmon-Enhanced Vibrational Electron Spectroscopy was written by Tizei, Luiz H. G.;Mkhitaryan, Vahagn;Lourenco-Martins, Hugo;Scarabelli, Leonardo;Watanabe, Kenji;Taniguchi, Takashi;Tence, Marcel;Blazit, Jean-Denis;Li, Xiaoyan;Gloter, Alexandre;Zobelli, Alberto;Schmidt, Franz-Philipp;Liz-Marzan, Luis M.;Garcia de Abajo, F. Javier;Stephan, Odile;Kociak, Mathieu. And the article was included in Nano Letters in 2020.Related Products of 122-18-9 The following contents are mentioned in the article:

Atomic vibrations and phonons are an excellent source of information on nanomaterials that the authors can access through a variety of methods including Raman scattering, IR spectroscopy, and EELS. In the presence of a plasmon local field, vibrations are strongly modified and, in particular, their dipolar strengths are highly enhanced, thus rendering Raman scattering and IR spectroscopy extremely sensitive techniques. Exptl. the interaction between a relativistic electron and vibrational modes in nanostructures is fundamentally modified in the presence of plasmons. The authors finely tune the energy of surface plasmons in metallic nanowires in the vicinity of hexagonal BN, making it possible to monitor and disentangle both strong phonon-plasmon coupling and plasmon-driven phonon enhancement at the nanometer scale. Because of the near-field character of the electron beam-phonon interaction, optically inactive phonon modes are also observed Besides increasing the understanding of phonon physics, the results hold great potential for studying sensing mechanisms and chem. in complex nanomaterials down to the mol. level. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Related Products of 122-18-9).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Related Products of 122-18-9

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Gold Nanoearbuds: Seed-Mediated Synthesis and the Emergence of Three Plasmonic Peaks was written by Roy, Debashree;Xu, Yi;Rajendra, Ranguwar;Wu, Lin;Bai, Ping;Ballav, Nirmalya. And the article was included in Journal of Physical Chemistry Letters in 2020.Electric Literature of C25H46ClN The following contents are mentioned in the article:

We demonstrate the first successful synthesis of reasonably monodisperse and single-crystalline gold nanoearbuds (Au NEBs) using a binary surfactant mixture of cetyltrimethylammonium chloride (CTAC) and benzyldimethylhexadecylammonium chloride (BDAC) in seed-mediated growth method. We have focused on the key chem. parameters behind the formation and growth of Au NEBs to result in tunable dimensions (length, 37-77 nm; width, 4-6 nm; aspect ratio, 7-19), as a consequence of which the longitudinal surface plasmon resonance (LSPR) peak could be tuned beyond 1200 nm. The achievement of LSPR beyond 1200 nm while maintaining the dimension well below 100 nm is a challenging accomplishment in the realm of one-dimensional (1D) Au nanostructures. This earbud-like morphol. addnl. exhibits three plasmonic peaks, rather uncommon for 1D nanostructures, which were analyzed theor. based on the finite element method. The new resonance peak of the Au NEB was assigned as an addnl. longitudinal mode intensified by the bulbous ends as well as the high aspect ratio, thereby providing conclusive evidence that it is indeed a new morphol. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Electric Literature of C25H46ClN).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Electric Literature of C25H46ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends was written by Agazzi, Federico M.;Falcone, R. Dario;Silber, Juana J.;Correa, N. Mariano. And the article was included in Colloids and Surfaces, A: Physicochemical and Engineering Aspects in 2016.Electric Literature of C25H46ClN The following contents are mentioned in the article:

We present results on a new system that forms non-aqueous reverse micelles (RMs) created with a cationic surfactant, benzyl-n-hexadecyldimethylammonium chloride (BHDC), encapsulating ethylene glycol (EG), in different nonpolar solvents blends of n-heptane:benzene. It is shown that a cationic surfactant forms RMs using EG as polar solvent without the addition of a co-surfactant. In particular, we analyzed the EG solubilization capacity, the droplet size values and the interface composition of EG/BHDC/n-heptane:benzene RMs, using dynamic light scattering (DLS) and the solvatochromic behavior of 1-methyl-8-oxyquinolinium betaine (QB) as mol. dye. The EG solubilization capacity depends on the external phase composition decreasing when the n-heptane content increases. Using DLS technique, we demonstrate the formation of RMs, and observe that for the same [EG]/[BHDC] ratio, the micellar size increases when n-heptane content increases. Using QB it was found that EG penetrates into the micellar interface changing dramatically the composition and the droplet-droplet interaction, in comparison when water is encapsulated. This study involved multiple reactions and reactants, such as N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9Electric Literature of C25H46ClN).

N-Benzyl-N,N-dimethylhexadecan-1-aminium chloride (cas: 122-18-9) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Electric Literature of C25H46ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics