Category: 104-86-9

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Category: chlorides-buliding-blocks.

Liu, Gang;Liu, Sen;Li, Zhen;Chen, Hengyu;Li, Jiashuai;Zhang, Yalin;Shen, Guodong;Yang, Bingchuan;Hu, Xiude;Huang, Xianqiang research published 《 Metal- and oxidant-free electrochemically promoted oxidative coupling of amines》, the research content is summarized as follows. The selective oxidation of amines into imines is a priority research topic in organic synthesis and has attracted much attention over the past few decades. However, the oxidation of amines generally suffers from the drawback of transition-metal, even noble-metal catalysts. Thus, the strategy of metal- and oxidant-free selective synthesis of imines is highly desirable yet largely unmet. This paper unravels a metal-free and external oxidant-free electrochem. strategy for the oxidative coupling methodol. of amines. This general transformation is compatible with various functional amines and led to functionalized imines in moderate to satisfactory yields.

104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., Category: chlorides-buliding-blocks

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chlorinated organic compounds are found in nearly every class of biomolecules. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Formula: C7H8ClN.

Liu, Lang;Zhang, Jun research published 《 KI/K₂S₂O₈ Mediated Cascade C(sp³)-H/C(sp²)-H Thiolation for the Synthesis of Multi-Substituted Thiazoles》, the research content is summarized as follows. Designing and synthesis of carbonyl-containing thiazoles are of great importance for related fields, hence, a simple and practical method was developed using com. xanthates, benzylamine, and readily available alkynones as substrates. The reaction was achieved using one-pot Michael addition and cascade iodine mediated C-H thiolation under mild conditions. This method features a broad substrate scope with high yield. Remarkably, the obtained carbonyl substituted thiazoles bearing electronic-donating substituents exhibit promising performance for aggregation-induced emission (AIE) and have been successfully used in biol. imaging.

104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., Formula: C7H8ClN

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Electric Literature of 104-86-9.

Liu, Shufang;Su, Qing;Qi, Wei;Luo, Kexin;Sun, Xiaoman;Ren, Hao;Wu, Qiaolin research published 《 Highly hydrophilic covalent organic frameworks as efficient and reusable photocatalysts for oxidative coupling of amines in aqueous solution》, the research content is summarized as follows. Three hydrophilic two-dimensional (2D) COFs achieved by a polycondensation reaction of 2,5-dimethoxyterephthalohydrazide (DMTH), 1,3,5-triformylbenzene (TFB) and 2-hydroxy-1,3,5-benzene tricarbaldehyde (SOH) under solvothermal conditions was reported. The resulted COF materials, TFB-XX-DMTH (XX = 33, 50 and 66, corresponding to a molar ratio of TFB/SOH = 1 : 2, 1 : 1 and 2 : 1), were successfully constructed by a three-component in-situ assembly strategy and thus exhibited high crystallinity, large surface areas (up to 1808 m² g^-1) and good thermal and chem. stability. Moreover, benefiting from the enhanced charge separation efficiency and high hydrophilicity, the TFB-XX-DMTH materials were employed as photocatalysts for visible-light-driven oxidative coupling reactions of benzylamines in aqueous solution The photocatalytic performance with high conversion, selectivity and recyclability could be attributed to a combined result of efficient generation, migration and separation of photogenerated carriers in such a platform. This results provide insights into the structure-function correlation of COF photocatalysts and also highlight their potential in developing photofunctional COFs for sustainable organic transformations.

Electric Literature of 104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., 104-86-9.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chlorinated organic compounds are found in nearly every class of biomolecules. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. COA of Formula: C7H8ClN.

Liu, Yanan;Ji, Kaihui;Wang, Jing;Li, Huafeng;Zhu, Xueyu;Ma, Pengtao;Niu, Jingyang;Wang, Jingping research published 《 Enhanced Carrier Separation in Visible-Light-Responsive Polyoxometalate-Based Metal-Organic Frameworks for Highly Efficient Oxidative Coupling of Amines》, the research content is summarized as follows. Photocatalytic technol. is widely studied, while it comes with drawbacks such as low sunlight utilization efficiency and high carrier recombination rates. Herein, for the first time, we present two crystalline polyoxometalate (POM)-based metal-organic frameworks (POMOFs), {[Cd(DMF)₂Ru(bpy)₂(dcbpy)]₂(POMs)(DMF)₂} xDMF (PMo-1, POMs = [PMo^VI₁₁Mo^VO₄₀]^4-, x = 5; SiW-2, POMs = [SiW₁₂O₄₀]^4-, x = 4) through assembling the photosensitizer [Ru(bpy)₂(H₂dcbpy)]Cl₂ and POMs into a single framework. The assembly not only enhances light absorption in the visible light regime but also improves carrier separation efficiency; atop of that, both POMOFs demonstrate activities in the photocatalytic oxidative coupling of amines. Particularly, PMo-1 enables the quant. completion of oxidative coupling of benzylamine reaction within 30 min (yield = 99.6%) with a high turnover frequency (TOF = 6631.6 h^-1). To our knowledge, the PMo-1 catalyst outperforms any other photocatalysts previously reported in similar use cases where TOF values were usually obtained <2000 h^-1.

COA of Formula: C7H8ClN, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., 104-86-9.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chloride substituents modify the physical properties of organic compounds in several ways. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. Recommanded Product: (4-Chlorophenyl)methanamine.

Li, Zhen;Ye, Shan;Qiu, Ping;Liao, Xiaoyuan;Yao, Yue;Zhang, Jingzhao;Jiang, Yan;Lu, Shuxiang research published 《 An S-scheme α-Fe₂O₃/Cu₂O photocatalyst for an enhanced primary amine oxidative coupling reaction under visible light》, the research content is summarized as follows. Here, an S-scheme α-Fe₂O₃/Cu₂O heterojunction photocatalyst was designed and fabricated for the primary amines oxidative coupling reaction to give aryl imines. On account of that, the S-scheme structure effectively separated the photogenerated electron-hole pairs and enhanced the photoredox ability of the photocatalytic system. The α-Fe₂O₃/Cu₂O composite could also enhance the reactivity to a large extent. This work will provide new insight into the design of photocatalysts with a more reasonable structure and higher performance.

Recommanded Product: (4-Chlorophenyl)methanamine, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., 104-86-9.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. SDS of cas: 104-86-9.

Lian, Chengxi;Zhang, Chaoying;Zhao, Yingchun;Wang, Hui;Li, Xiufen;Huang, Longjiang research published 《 Oxidative coupling of primary amines to imines catalyzed by CoCl₂·6H₂O》, the research content is summarized as follows. A high-performance, readily available and eco-friendly cobalt catalyst has been suggested for the first time for the additive-free oxidative coupling of primary amines RCHR¹NH₂ (R = Ph, 4-chlorophenyl, thiophen-2-yl, etc.; R¹ = H, Me) to imines RC(R¹)=NCHRR¹. Different substituted benzylamine and heteroaryl methanamine compounds could be transformed into their corresponding imines in good to excellent yields over this catalyst. Meanwhile, it has been demonstrated that this catalyst can also afford the oxidative coupling of various benzylamines R²CH₂NH₂ (R² = Ph, 3-fluorophenyl, thien-2-yl, etc.) with o-phenylenediamine to produce benzimidazole derivatives I in medium to good yields.

104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., SDS of cas: 104-86-9

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Safety of (4-Chlorophenyl)methanamine.

Lillich, Felix F.;Willems, Sabine;Ni, Xiaomin;Kilu, Whitney;Borkowsky, Carmen;Brodsky, Mirko;Kramer, Jan S.;Brunst, Steffen;Hernandez-Olmos, Victor;Heering, Jan;Schierle, Simone;Kestner, Roxane-I.;Mayser, Franziska M.;Helmstaedter, Moritz;Goebel, Tamara;Weizel, Lilia;Namgaladze, Dmitry;Kaiser, Astrid;Steinhilber, Dieter;Pfeilschifter, Waltraud;Kahnt, Astrid S.;Proschak, Anna;Chaikuad, Apirat;Knapp, Stefan;Merk, Daniel;Proschak, Ewgenij research published 《 Structure-Based Design of Dual Partial Peroxisome Proliferator-Activated Receptor γ Agonists/Soluble Epoxide Hydrolase Inhibitors》, the research content is summarized as follows. A dual partial PPARγ agonist/sEH inhibitor using a structure-guided approach was designed. Exhaustive structure-activity relationship studies lead to the successful optimization of the designed lead. Crystal structures of one representative compound with both targets revealed potential points for optimization. The optimized compounds exhibited favorable metabolic stability, toxicity, selectivity, and desirable activity in adipocytes and macrophages.

Safety of (4-Chlorophenyl)methanamine, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., 104-86-9.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

Chloride substituents modify the physical properties of organic compounds in several ways. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. SDS of cas: 104-86-9.

Ling, Johanne;Bruneau-Voisine, Antoine;Journot, Guillaume;Evano, Gwilherm research published 《 Copper-Catalyzed Carbonylative Cross-Coupling of Alkyl Iodides and Amines》, the research content is summarized as follows. A general copper-catalyzed carbonylative cross-coupling between amines and alkyl iodides was reported to form amides RC(O)NR¹R² [R = Cy, i-Pr, CH(Et)₂, etc.; R¹ = H, Me, R² = n-hexyl, CH₂Bn, t-Bu, etc.]. Using a simple combination of catalytic amounts of copper(I) chloride and N,N,N’;N”,N”-pentamethyldiethylenetriamine in the presence of sodium hydroxide under carbon monoxide pressure, a broad range of alkyl iodides and amines can be efficiently coupled to the corresponding amides that are obtained in good to excellent yields. Notable features of this process were the first one relying on a base metal catalyst, includeed the availability and low cost of the catalytic system, its successful use with primary, secondary, tertiary alkyl iodides and all classes of amines with no or limited competing nucleophilic substitution without CO incorporation as well as its efficiency with complex alkyl iodides and amines. Mechanistic studies demonstrated that a radical pathway is operative and the key role of CO.

104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., SDS of cas: 104-86-9

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Name: (4-Chlorophenyl)methanamine.

Li, Shuangqing;Wang, Shuangshuang;Li, Juan;Qi, Yue;Wang, Chao;Zong, Lili;Tan, Choon-Hong research published 《 Monocationic Cinchoninium Catalyzed Asymmetric Oxohydroxylation of Enoates》, the research content is summarized as follows. In this paper, asym. oxohydroxylation of α-alkyl enoates RCH=C(R¹)C(O)OR² (R = Me, cyclohexyl, furan-2-yl, etc.; R¹ = Me, prop-2-en-1-yl, prop-2-yn-1-yl, Bn, etc.; RR¹ = -(CH₂)₃-, -(CH₂)₄-; R² = Et, Bn, 2-(4-methoxyphenyl)-2-oxoethyl) with potassium permanganate catalyzed by monocationic quaternary ammonium salts I (R³ = H, Bn, (2-bromo-3,5-di-tert-butylphenyl)methyl, [3,5-bis(3,5-di-tert-butylphenyl)phenyl]methyl, etc.; R⁴ = Br, F, CF₃; R⁵ = F, CF₃, [3,5-bis(trifluoromethyl)phenyl]methyl) derived from cinchona alkaloid is reported. A series of α-hydroxy-β-keto esters RC(O)C(R¹)(OH)C(O)OR² were obtained in up to 96% yield and 98% ee under user-friendly conditions. Synthetic application of oxohydroxylation was demonstrated in the synthesis of key chiral building blocks for thapsigargin and camptothecin synthesis. Control experiments indicated that, compared with tetrabutylammonium, monocationic chiral cinchoninium has a dramatic rate acceleration effect on catalytic permanganate oxidation

Name: (4-Chlorophenyl)methanamine, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., 104-86-9.

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics

The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Application In Synthesis of 104-86-9.

Li, Xia;Zhang, Fulin;Wang, Yuexin;Xiong, Kanghui;Lang, Xianjun research published 《 Extending the 2D conjugated microporous polymers linked by thiazolo[5,4-d]thiazole for green light-driven selective aerobic oxidation of amines》, the research content is summarized as follows. Donor-π-acceptor (D-π-A) type CMPs linked by the electron-deficient thiazolo[5,4-d]thiazole (TzTz, i.e. the acceptor) were designed by extending the donor from benzene to pyrene to broaden the visible light activity. Subsequently, two-dimensional (2D) CMPs, TzTz-CMP-Be and TzTz-CMP-Py, were constructed via a solvothermal process. The more extended π-conjugation and planar pyrene bestow upon TzTz-CMP-Py with broader absorption of visible light and higher efficiency of charge transfer than TzTz-CMP-Be. Significantly, TzTz-CMP-Py outperformed TzTz-CMP-Be in the green light-driven selective aerobic oxidation of amines RCH₂NHR¹ [R = Ph, pyridin-2-yl, thiophen-2-yl, etc.; R¹ = H, t-Bu, Bn, 4-fluorobenzyl, etc.]. Remarkable photocatalytic performance was observed in converting a wealth of primary and secondary amines to corresponding imines RCH=NR¹ with mol. oxygen (O₂) over TzTz-CMP-Py. This work suggests that CMPs can be rationally designed for extensive visible light-driven selective organic transformations.

104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., Application In Synthesis of 104-86-9

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics