Category: 1002-41-1

Toader, Gabriela published the artcileEco-Friendly Peelable Active Nanocomposite Films Designed for Biological and Chemical Warfare Agents Decontamination, Safety of 1,2-Bis(2-chloroethyl)disulfane, the publication is Polymers (Basel, Switzerland) (2021), 13(22), 3999, database is CAplus and MEDLINE.

In the context of imminent threats concerning biol. and chem. warfare agents, the aim of this study was the development of a new method for biol. and chem. decontamination, employing non-toxic, film-forming, water-based biodegradable solutions, using a nano sized reagent together with bentonite as trapping agents for the biol. and chem. contaminants. Bentonite-supported nanoparticles of Cu, TiO₂, and Ag were successfully synthesized and dispersed in a polyvinyl alc. (PVA)/glycerol (GLY) aqueous solution The decontamination effectiveness of the proposed solutions was evaluated by qual. and quant. anal. techniques on various micro-organisms, with sulfur mustard (HD) and di-Me methylphosphonate (DMMP) as contaminants. The results indicate that the peelable active nanocomposite films can be successfully used on contaminated surfaces to neutralize and entrap the hazardous materials and their degradation products. Mech. and thermal characterization of the polymeric films was also performed to validate the decontamination solution′s potential as peelable-film generating materials. The removal efficacy from the contaminated surfaces for the tested micro-organisms varied between 93% and 97%, while for the chem. agent HD, the highest decontamination factor obtained was 90.89%. DMMP was almost completely removed from the contaminated surfaces, and a decontamination factor of 99.97% was obtained.

Polymers (Basel, Switzerland) published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C12H10FeO4, Safety of 1,2-Bis(2-chloroethyl)disulfane.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Labande, Agnes published the artcileRhodium(III) and ruthenium(II) complexes of redox-active, chelating N-heterocyclic carbene/thioether ligands, Product Details of C4H8Cl2S2, the publication is New Journal of Chemistry (2011), 35(10), 2162-2168, database is CAplus.

Half-sandwich rhodium(III) and ruthenium(II) complexes bearing a new redox-active ferrocenyl NHC-thioether ligand have been prepared The synthesis of ferrocenyl thioether-imidazolium salts was carried out via intermediate FcSCH₂CH₂Cl using an improved procedure. Rhodium(III) complex and ruthenium(II) complex were obtained in good yields and were fully characterised by NMR spectroscopy, x-ray diffraction anal. and electrochem. Rhodium(III) complex shows a complex ABCD system by ¹H NMR, which denotes conformational rigidity due to the presence of several bulky groups. Electrochem. anal. by cyclic voltammetry reveals reversible redox behavior about the iron center in both complexes, and indicates electronic communication between iron and rhodium or ruthenium.

New Journal of Chemistry published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C4H8Cl2S2, Product Details of C4H8Cl2S2.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics

Pierson, R. M. published the artcileBis-type modifiers in polymerization. I. Behavior of various disulfides in bulk styrene polymerization, Recommanded Product: 1,2-Bis(2-chloroethyl)disulfane, the publication is Journal of Polymer Science (1955), 221-46, database is CAplus.

Studies were made of the effectiveness in low-conversion bulk styrene polymerizations of the modifiers, bis(2-ethylhexyl) disulfide, dibenzyl disulfide, bis(chlorobenzyl) disulfide, bis[2-(2-pyridyl)ethyl] disulfide, bis(2-chloroethyl)disulfide, bis(2-hydroxyethyl)disulfide, dithiodiacetic acid, esters of bis(2-carboxyethyl)disulfide, bis(2-chloroacetoxyethyl) disulfide, diphenyl disulfide, di-ο-tolyl disulfide, bis(2,6-xylyl) disulfide, bis(2,3,5,6-tetramethylphenyl) disulfide, bis(4-carboxyphenyl) disulfide, bis(4-carbethoxyphenyl) disulfide, bis(4-hydroxymethylphenyl)disulfide, bis(2-chloromethylphenyl) disulfide, bis(2-bromomethylphenyl)disulfide, bis(2-aminophenyl) disulfide, di-2-naphthyl disulfide, di-2-benzothiazolyl disulfide, bis(isopropylxanthogen) disulfide, 4,4′-dithiodimorpholine disulfide, carbonylbis(thioglycolic acid), thiocarbonylbis(thioglycolic acid), and tetraphenylhydrazine. Alkyl disulfides, even when substituted at C’s near the SS bond, had very low transfer constants The transfer constants of aryl disulfides were much higher and could be increased by substitutions, thereby incorporating desired groups into the polymer. They cleave to give one half the mol. to each end of the polymer as was shown by comparing end-group concentrations of styrene polymers containing various types of end groups with polymers modified by thiols containing similar groups.

Journal of Polymer Science published new progress about 1002-41-1. 1002-41-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is 1,2-Bis(2-chloroethyl)disulfane, and the molecular formula is C4H8Cl2S2, Recommanded Product: 1,2-Bis(2-chloroethyl)disulfane.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics