In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Synthesis of (dppe)Pt(μ3-S)2{Ru(N)Me2}2, (dppe)Pt(μ3-S)2{Os(N)(CH2SiMe3)2}2, and Related Heterometallic Complexes, published in 2001-10-29, which mentions a compound: 12266-72-7, mainly applied to platinum palladium nickel silanethiolate complex preparation reaction; sulfido bridged heterobimetallic imino complex preparation reaction; crystal mol structure platinum ruthenium osmium sulfido bridged trimetallic, Category: chlorides-buliding-blocks.
The trimethylsilanethiolate complexes of the platinum triad metals (dppe)M(SSiMe3)2 (M = Ni, Pd, Pt) and (COD)Pt(SSiMe3)2 were prepared by the reaction of NaSSiMe3 with (dppe)MCl2 or (COD)PtI2. These complexes are water-sensitive. New, sulfido-bridged heterobimetallic complexes L2M(μ3-S)2{Ru(N)Me2}2 resulted from the reactions of (dppe)Pt(SSiMe3)2, (COD)Pt(SSiMe3)2, or (dppe)Pd(SSiMe3)2 with [PPh4][Ru(N)Me2Cl2]. The reaction between (dppe)Pt(SSiMe3)2 and [Os(N)(CH2SiMe3)2(NCMe)2][BF4] produced (dppe)Pt(μ3-S)2{Os(N)(CH2SiMe3)2}2. All new compounds have been characterized through spectroscopic techniques and elemental anal. The mol. structures of (dppe)Pt(μ3-S)2{Ru(N)Me2}2 and (dppe)Pt(μ3-S)2{Os(N)(CH2SiMe3)2}2 were determined by single-crystal x-ray diffraction.
In addition to the literature in the link below, there is a lot of literature about this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Category: chlorides-buliding-blocks, illustrating the importance and wide applicability of this compound(12266-72-7).
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics