Awesome Chemistry Experiments For 1-Chloro-2-methylbenzene

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Computed Properties of C7H7Cl. Recently I am researching about SELECTIVE AEROBIC OXIDATION; METAL-ORGANIC FRAMEWORKS; N-HYDROXYPHTHALIMIDE; ADSORPTION; M-MOF-74; ACID; MN, Saw an article supported by the Natural Science Foundation of Jiangsu Province-Outstanding Youth Foundation [BK20170104]; National Key Research and Development Program of China [2017YFB0307202]; Strategic Pioneer Program on Space Science, Chinese Academy of Sciences [XDA15013100, XDA15013101]; Youth Foundation of Southeast University ChengXian College [z0017]. Published in ACADEMIC PRESS INC ELSEVIER SCIENCE in SAN DIEGO ,Authors: Gu, XY; Huang, C; Xu, ZC; Wu, H; Dong, RL; Liu, R; Chen, J; Zhu, HJ. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene

A series of core-shell Co-MOF-74@Mn-MOF-74 samples with different shell thicknesses were prepared by the seed growth method, which were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), inductively coupled plasma mass spectrometry (ICP-MS), X-ray photoelectron spectroscopy, nitrogen adsorption-desorption and scanning electron microscopy (SEM). The shell thickness of these MOF samples were successfully controlled by adjusting the mass ratio between MnCl2 center dot 4H(2)O and Co-MOF-74. On this basis, these MOFs were applied to the catalytic oxidation of toluene. The results showed that with the growth of Mn-MOF-74 in the outer layer of Co-MOF-74, the oxidative selectivity of the substrate to benzaldehyde was greatly improved for the synergy between the core layer and shell layer. The conversion of toluene was 22.4%, and the selectivity of benzaldehyde was 98.1%. In addition, the catalyst can transform various substituted toluene into the corresponding aldehydes in highly selectivity and still keep good stability after four catalytic cycles. The selectivity of the corresponding aldehyde is generally above 80%.

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Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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