An article Unified Protocol for Fe-Based Catalyzed Biaryl Cross-Couplings between Various Aryl Electrophiles and Aryl Grignard Reagents WOS:000467319600022 published article about ALKYL-HALIDES; IRON CATALYSIS; CHLORIDES; MAGNESIUM; ARYLMAGNESIUM; TOSYLATES; COBALT; LIGAND; ALKYLATIONS; CHARACTER in [Wang, Lei; Wei, Yi-Ming; Zhao, Yan; Duan, Xin-Fang] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China in 2019.0, Cited 76.0. Safety of 1-Chloro-2-methylbenzene. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8
The combination of commonly used FeCl3/SIPr with Ti(OEt)(4)/PhOM enabled a highly general iron- based catalyst system, which could efficiently catalyze the biaryl coupling reaction between various electrophiles (I, Br, Cl, OTs, OCONMe2, OSO2NMe2) and common or functionalized aryl Grignard reagents with high functional group tolerance. Selective couplings of aryl iodides and bromides over the corresponding oxygen-based electrophiles have been achieved, and thus a terphenyl acid intermediate for anidulafungin was conveniently synthesized via an orthogonal coupling strategy.
Safety of 1-Chloro-2-methylbenzene. Bye, fridends, I hope you can learn more about C7H7Cl, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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