Authors Li, DH; He, XX; Xu, C; Huang, FD; Liu, N; Shen, DS; Liu, FS in AMER CHEMICAL SOC published article about CROSS-COUPLING REACTIONS; SUZUKI-MIYAURA REACTION; HETEROCYCLIC CARBENE COMPLEXES; ORTHO-SUBSTITUTED BIARYLS; ARYLBORONIC ACIDS; ROOM-TEMPERATURE; HIGHLY EFFICIENT; PEPPSI COMPLEXES; NHC COMPLEXES; ARYL BROMIDES in [Li, Dong-Hui; He, Xu-Xian; Xu, Chang; Huang, Fei-Dong; Liu, Ning; Shen, Dong-Sheng; Liu, Feng-Shou] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Zhongshan 528458, Guangdong, Peoples R China in 2019.0, Cited 100.0. Formula: C7H7Cl. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8
A series of palladium N-heterocyclic carbenes (NHCs), complexes C1-C5, bearing dianisole backbones and substituted N-aryl moieties have been synthesized and characterized. The electronic effect as well as the steric environment of the NHC ligands has been assessed. The synthesized palladium complexes were applied for Suzuki-Miyaura cross-coupling reactions under aerobic conditions. The relationship between the catalytic structure and catalytic performance was then extensively investigated. Upon optimizing the reaction conditions, the C4 was found to be highly efficient to catalyze the cross-coupling of (hetero)aryl chlorides with (hetero)arylboronic acids at a 0.1 mol % palladium loading.
Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Li, DH; He, XX; Xu, C; Huang, FD; Liu, N; Shen, DS; Liu, FS or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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