Recently I am researching about C-H BONDS; LIGHT PHOTOREDOX CATALYSIS; HYDROGEN-PRODUCTION; FUNCTIONALIZATION; ARYLATION; PHOTOCHEMISTRY; ALKYLATION; CO2, Saw an article supported by the German Science Foundation (DFG)German Research Foundation (DFG) [KO 1537/18-1]; European Research Council (ERC) under the European Union’s Horizon 2020 Research and Innovation ProgrammeEuropean Research Council (ERC) [741623]. Name: 1-Chloro-2-methylbenzene. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Das, S; Murugesan, K; Rodriguez, GJV; Kaur, J; Barham, JP; Savateev, A; Antonietti, M; Konig, B. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene
Graphitic carbon nitride materials have attracted significant interest in recent years and found applications in diverse light-to-energy conversions such as artificial photosynthesis, CO2 reduction, or degradation of organic pollutants. However, their utilization in synthetic photocatalysis, especially in the direct functionalization of C(sp(3))-H bonds, remains underexplored. Herein, we report mesoporous graphitic carbon nitride (mpg-CN as a heterogeneous organic semiconductor photocatalyst for direct arylation of C(sp(3))-H bonds in combination with nickel catalysis. Our protocol has a broad synthetic scope (>70 examples including late-stage functionalization of drugs and agrochemicals), is operationally simple, and shows high chemo- and regioselectivities. Facile separation and recycling of the mpg-CN catalyst in combination with its low preparation cost, innate photochemical stability, and low toxicity are beneficial features overcoming typical shortcomings of homogeneous photocatalysis. Detailed mechanistic investigations and kinetic studies indicate that an unprecedented energy-transfer process (EnT) from the organic semiconductor to the nickel complex is operating.
Name: 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Das, S; Murugesan, K; Rodriguez, GJV; Kaur, J; Barham, JP; Savateev, A; Antonietti, M; Konig, B or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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