Recently I am researching about MONO-ALPHA-ARYLATION; TRANSITION-METAL-FREE; REDUCTIVE ELIMINATION; (NHC)PD(ALLYL)CL NHC; ACETONE; COMPLEXES; HALIDES; AMIDES; ROUTE, Saw an article supported by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under Germany’s Excellence StrategyGerman Research Foundation (DFG) [EXC-2033, 390677874]; European Research CouncilEuropean Research Council (ERC)European Commission [677749]; BMBFFederal Ministry of Education & Research (BMBF); state of NRW (Center of Solvation Science ZEMOS). HPLC of Formula: C7H7Cl. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Hu, XQ; Lichte, D; Rodstein, I; Weber, P; Seitz, AK; Scherpf, T; Gessner, VH; Goossen, LJ. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene
Ylide-functionalized phosphine (YPhos) ligands allow the palladium-catalyzed alpha-arylation of alkyl ketones with aryl chlorides with record setting activity. Using a cyclohexyl-substituted YPhos ligand, a wide range of challenging ketone substrates was efficiently and selectively monoarylated under mild conditions. A newly designed YPhos ligand bearing tert-butyl groups on the coordinating phosphorus atom is already active at room temperature. The synthetic potential was demonstrated by gram-scale reactions and the succinct synthesis of epsilon-caprolactone derivatives.
HPLC of Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Hu, XQ; Lichte, D; Rodstein, I; Weber, P; Seitz, AK; Scherpf, T; Gessner, VH; Goossen, LJ or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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