Microwave Assisted Oxidation of Benzyl Halides to Aldehydes and Ketones with 4-Hydroxypyridinium Nitrate Functionalized Silica Gel in Aqueous Media was written by Ghalehbandi, Shermineh sadat;Ghazanfari, Dadkhoda;Ahmadi, Sayed Ali;Sheikhhosseini, Enayatollah. And the article was included in Organic Preparations and Procedures International in 2021.Quality Control of 1-(Chloromethyl)-3-methylbenzene This article mentions the following:
An eco-friendly heterogeneous oxidant based on 4-hydroxypyridinium nitrate functionalized silica gel was prepared for the oxidation of benzyl halides to the corresponding carbonyl compounds R1C(O)R2 [R1 = Ph, 4-FC6H4, 3-MeOC6H4, etc.; R2 = H, Me, Ph]. The oxidant was a stable solid and could be prepared from the reaction of sodium 4-pyridinolate with an acidic activated silica gel which was then reacted with HNO3. In the experiment, the researchers used many compounds, for example, 1-(Chloromethyl)-3-methylbenzene (cas: 620-19-9Quality Control of 1-(Chloromethyl)-3-methylbenzene).
1-(Chloromethyl)-3-methylbenzene (cas: 620-19-9) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Quality Control of 1-(Chloromethyl)-3-methylbenzene
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics