Chloromethyl benzoate (cas: 5335-05-7) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of C8H7ClO2
Kinetic study of hydrolysis of benzoates. Part XXVI. Variation of the substituent effect with solvent in alkaline hydrolysis of substituted alkyl benzoates was written by Nummert, Vilve;Piirsalu, Mare;Koppel, Ilmar A.. And the article was included in Collection of Czechoslovak Chemical Communications in 2006.Computed Properties of C8H7ClO2 This article mentions the following:
The second-order rate constants k2 (dm3 mol-1 s-1) for the alk. hydrolysis of substituted alkyl benzoates C6H5CO2R were measured spectrophotometrically in aqueous 0.5 M Bu4NBr at 50 and 25 °C (R = CH3, CH2Cl, CH2CN, CH2C≡CH, CH2C6H5, CH2CH2Cl, CH2CH2OCH3, CH2CH3) and in aqueous 5.3 M NaClO4 at 25 °C (R = CH3, CH2Cl, CH2CN, CH2C≡CH). The dependence of the alkyl substituent effects on different solvent parameters was studied using the following equations:. Δ Log k = c0 + c1σ1 + c2E5B + c3ΔE + c4ΔY + c5ΔP + c6ΔEσ1 + c7ΔYσ1 + c8ΔPσ1. Δ Log k = c0 + c1σ* + c2EsB + c3ΔE + c4ΔY + c5ΔP + c6ΔEσ* + c7ΔYσ* + c8ΔPσ*. Δ Log k = log kR – log kCH3·σ1 and σ* are the Taft inductive and polar substituent constants E, Y and P are the solvent electrophilicity, polarity and polarizability parameters, resp. In the data treatment ΔE = ES – EH2O, ΔY = YS – YH2O, ΔP = PS – PH2O were used. The solvent electrophilicity, E, is the main factor responsible for changes in alkyl substituent effects with medium. When σ1 constants were used, variation of the polar term of alkyl substituents with the solvent electrophilicity E is similar to that observed earlier for meta and para substituents, but twice less when σ* constants were used. The steric term for alkyl substituents was approx. independent of the solvent parameters. In the experiment, the researchers used many compounds, for example, Chloromethyl benzoate (cas: 5335-05-7Computed Properties of C8H7ClO2).
Chloromethyl benzoate (cas: 5335-05-7) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Computed Properties of C8H7ClO2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics