The chlorination of some N,N-dimethylanilines with 1,3,5-trichloro-1,3,5-triazine-2,4,6(1H,3H,5H)-trione (trichloroisocyanuric acid) was written by Rosevear, Judi;Wilshire, John F. K.. And the article was included in Australian Journal of Chemistry in 1980.Safety of 2-Chloro-N,N-dimethylaniline This article mentions the following:
The reaction of some representative N,N-dimethylanilines and of Fischer’s base (1,3,3-trimethyl-2-methyleneindoline) with trichloroisocyanuric acid in concentrated H2SO4 was investigated. In many cases mixtures of chlorinated products were obtained; these mixtures were examined both by gas-liquid chromatog. and by NMR. The reaction of PhNMe2 with dichloroisocyanuric acid was also studied. Substitution tended to occur ortho to the dimethylamino group. This behavior therefore differs from that reported for the corresponding brominations involving dibromoisocyanuric acid, where meta substitution was observed In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Safety of 2-Chloro-N,N-dimethylaniline).
2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Safety of 2-Chloro-N,N-dimethylaniline
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics