Kinetics and mechanistic approach of N-chlorosaccharin oxidation of some aliphatic aldehydes was written by Khan, M. U.;Verma, J. K.;Nigam, S. K.;Parihar, S. S.;Dwivedi, H. P.. And the article was included in Oxidation Communications in 1998.Application of 14070-51-0 This article mentions the following:
The kinetic studies of N-chlorosaccharin (NCSA) oxidation of acetaldehyde and propionaldehyde have been reported in aqueous acetic acid medium. The reactions follow identical kinetics, being first order in each NCSA, and 1 to 0 order with respect to substrate and [H+]. A pos. effect on the oxidation rate is observed for solvent whereas saccharin exhibited a neg. trend. The ionic strength does not influence the oxidation rate. Various activation parameters have been evaluated. The products of the reactions were identified as the corresponding acids. A suitable scheme of mechanism consistent with the exptl. results has been proposed. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Application of 14070-51-0).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Application of 14070-51-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics