UV irradiation-initiated substitution reaction in isomeric N,N-dimethyl-p-chloroanilines in the presence of oxidizing agents was written by Kul’bitskaya, O. V.;Frolov, A. N.;El’tsov, A. V.. And the article was included in Zhurnal Organicheskoi Khimii in 1979.Category: chlorides-buliding-blocks This article mentions the following:
The sensitized photolysis of 4-ClC6H4NMe2 with NaNO2 gave mainly I and only 1-2% 4-O2NC6H4NMe2 (II); direct irradiation gave no I and up to 60% II. Irradiation of 2- or 3-ClC6H4NMe2 gave isomers of I having the NO2 group para to the NMe2 group. The role of cation radicals in these reactions was discussed. In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Category: chlorides-buliding-blocks).
2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics