Van Koten, Gerard et al. published their research in Journal of Organic Chemistry in 1977 | CAS: 698-01-1

2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application In Synthesis of 2-Chloro-N,N-dimethylaniline

Group IB organometallic chemistry. 20. The role of mixed organocopper cluster compounds RnR’mCun+m in selective carbon-carbon coupling reactions of 2- and 4-(dimethylamino)phenylcopper with copper arylacetylides was written by Van Koten, Gerard;Ten Hoedt, Richard W. M.;Noltes, Jan G.. And the article was included in Journal of Organic Chemistry in 1977.Application In Synthesis of 2-Chloro-N,N-dimethylaniline This article mentions the following:

The 1:1 interaction of ArnCun (Ar = 2-Me2NC6H4) with CuCCR (R = Ph, 4-MeC6H4, 2,4-xylyl, mesityl, 4-ClC6H4, 4-MeCC6H4, 4-O2NC6H4 in DMF at 125° affords the asym. cross-coupling products ArCCR in almost quant. yield. These reactions involve the intermediate formation of well-defined mixed organocopper cluster species Ar4Cu6(CCR)2. In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Application In Synthesis of 2-Chloro-N,N-dimethylaniline).

2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Application In Synthesis of 2-Chloro-N,N-dimethylaniline

Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics