Iron-Catalyzed C(sp2)-H Bond Functionalization with Organoboron Compounds was written by Shang, Rui;Ilies, Laurean;Asako, Sobi;Nakamura, Eiichi. And the article was included in Journal of the American Chemical Society in 2014.Quality Control of 3-Cyanobenzoyl chloride This article mentions the following:
We report here that an iron-catalyzed directed C-H functionalization reaction allows the coupling of a variety of aromatic, heteroaromatic, and olefinic substrates with alkenyl and aryl boron compounds under mild oxidative conditions. We rationalize these results by the involvement of an organoiron(III) reactive intermediate that is responsible for the C-H bond-activation process. A zinc salt is crucial to promote the transfer of the organic group from the boron atom to the iron(III) atom. Thus, e.g., coupling of (E)-N-(quinolin-8-yl)tiglamide I with (Z)-alkenylboronic acid pinacol ester II (Z/E = 93:7) employing BuLi for conversion to II to the corresponding borate, catalytic Fe(acac)3, ZnBr2.TMEDA, a bidentate phosphine ligand and 1,2-dichloroisobutane oxidant afforded (Z,Z)-diene III (90%; Z,Z/Z,E = 82:18). In the experiment, the researchers used many compounds, for example, 3-Cyanobenzoyl chloride (cas: 1711-11-1Quality Control of 3-Cyanobenzoyl chloride).
3-Cyanobenzoyl chloride (cas: 1711-11-1) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Quality Control of 3-Cyanobenzoyl chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics