Palladium-Catalyzed Benzylic C-H Insertion of 2-Substituted N-Iminopyridinium Ylides was written by Mousseau, James J.;Larivee, Alexandre;Charette, Andre B.. And the article was included in Organic Letters in 2008.Category: chlorides-buliding-blocks This article mentions the following:
Palladium-catalyzed direct benzylic C-H arylation of 2-alkyl substituted N-iminopyridinium ylides to afford the corresponding 2-arylalkyl-N-iminopyridinium ylides, e.g., I, is described. The insertion can be conducted with several electron-poor and electron-rich aryl chlorides in good yields. This work adds to the few examples of sp3 C-H insertions that have been reported so far. In the experiment, the researchers used many compounds, for example, tert-Butyl (4-chlorophenyl)carbamate (cas: 18437-66-6Category: chlorides-buliding-blocks).
tert-Butyl (4-chlorophenyl)carbamate (cas: 18437-66-6) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics