Visible-light-Catalyzed [3 + 1 + 2] Coupling Annulations for the Synthesis of Unsymmetrical Tri-substituted Amino-1,3,5-triazines was written by Guo, Wei;Zhao, Mingming;Du, Chengtang;Zheng, Lvyin;Li, Luo;Chen, Liping;Tao, Kailiang;Tan, Wen;Xie, Zhen;Cai, Liuhuan;Fan, Xiaolin;Zhang, Kai. And the article was included in Journal of Organic Chemistry in 2019.Recommanded Product: 18637-02-0 This article mentions the following:
A visible-light catalyzed [3 + 1 + 2] annulation for the synthesis of unsym. tri-substituted amino-1,3,5-triazines I (R1 = Me, C6H5, 4-FC6H4, etc.; R2 = 4-FC6H4, 4-EtC6H4, 2-ClC6H4, etc.) from amidines, isothiocyanates and 1,1,3,3-tetramethylguanidines has been developed. The method exhibits the advantages of easily available starting materials, insensitive to air and moisture, wide substrate scopes, high step economy, mild, metal- and ligand-free conditions, which has potential applications in the organic, medicinal and material chem. In the experiment, the researchers used many compounds, for example, 2-Chloro-benzamidine hydrochloride (cas: 18637-02-0Recommanded Product: 18637-02-0).
2-Chloro-benzamidine hydrochloride (cas: 18637-02-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Recommanded Product: 18637-02-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics