Jurga, Stefan published the artcileNuclear magnetic relaxation studies in solids, COA of Formula: C3H9ClOS, the publication is Ser. Fiz. (Uniw. im. Adama Mickiewicza Poznaniu) (1980), 58 pp., database is CAplus.
Spin-lattice relaxation times in the laboratory and in the rotating frame are reported for trimethyloxosulfonium fluoride, chloride, bromide and iodide as well as for Me2SO and Me2SO2 over a wide temperature range. A model was developed that makes it possible to analyze the exptl. data on the basis of 4 independent reorientations around 3 3-fold axis and around center of gravity . The following conclusions consistent with the 2nd moment and spin-lattice relaxation results are drawn about reorientational state of cations and mols. The Me group is reorienting about its 3-fold axis at random between 3 equilibrium positions separated by 120° in all the compounds A 3-fold reorientation of all cations around the C3 axis (designed by S → O bond) occurs. There is dynamical inequivalence of Me groups within the Me2SO mol. and trimethyloxosulfonium chloride with 1:2 ratio. There is observed translational diffusion in Me2SO2. The activation energies for C3 and C‘3 reorientations decrease with an increase of an anion ionic radius (with exception of the iodide salt for the last motion).
Ser. Fiz. (Uniw. im. Adama Mickiewicza Poznaniu) published new progress about 5034-06-0. 5034-06-0 belongs to chlorides-buliding-blocks, auxiliary class Salt,Aliphatic hydrocarbon chain, name is trimethyloxosulphonium chloride, and the molecular formula is C3H9ClOS, COA of Formula: C3H9ClOS.
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https://en.wikipedia.org/wiki/Chloride,
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